• 한국염색가공학회지
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• 제12권1호
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• pp.44-51
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• 2000

The conventional one bath exhaust dyeing system of nylon]/cotton blends with acid dye/direct dye involves a lot of neutral salt which affect dyeability of acid dyes. Because of conventional one bath exhaust dyeing system of nylonl/cotton blends with acid dye/direct dye needs acid dyes adjusted at a neutral liquor, suitable acid dye is limited. To improve dyeing property of nylon/cotton blends, cotton component was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. This study was carried out to investigate dyeing possibilities of nylon/cationized cotton blends with acid dye/direct dye in a non-neutral salt dyebath by one bath two step method. The concentration of direct dye was 1.0%, 0.7%, 0.3%o.w.f. respectively at a non, 1%, 3%owf of reserving agent for being almost equal color strength between nylon and 3% cationized cotton when nylon/3% cationized cotton blends was dyed with acid dye/direct dye at concentration of acid dye(1%o.w.f.) by one bath two step method.

• 한국염색가공학회지
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• 제7권2호
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• pp.1-8
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• 1995

Polymer cationic agent was prepared by the initial polymerization of epichlorohydrin followed by amination with diethyl-amine. Cotton fibre treated with the polymer (6∼8% o.w.f.) is highly cationic and exhibit increased substantivity for anionic dyes. The modified substrate could be dyed with direct dyes without salt or a little salt from dye bath. The increased concentration of cationic agents resulted in an increase the colour yield. Futhermore, treated cotton has an electropositive surface charge. Adsorption of direct dye can be attributed to both van der waals force and electrostatic attraction.

• 한국염색가공학회지
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• 제15권5호
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• pp.327-332
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• 2003

In this study, the polyurethane microcapsules for non-aqueous dyeing containing iron oxide and disperse dyes were prepared by in-situ polymerization method using hexamethylene diisocyanate(HDI) with ethylene glycol(EG). And the size, shape, and particle size distribution of microcapsules prepared were investigated. The size and shape of microcapsule were observed by optical microscope and scanning elecron microscope. The particle size distribution was analyzed by particle size analyzer. The microcapsule size and its distribution were largely effected by the existance of surface active agent in the system. When a surfactant did not exist in the system, the size distribution of microcapsules prepared was much uneven. By adding a surfactant, this phenomenon was disappeared. And the size of microcapsule was also effeced by the hydrophobicity of core material(disperse dye). It was considered due to the difference of dispersity of core materials. And the size of microcapsule prepared was inversely proportional to the stirring speed.

• 한국염색가공학회지
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• 제22권1호
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• pp.61-70
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• 2010

This effects of drawing conditions on the physical properties of the drawn worsted yarns were investigated. The drawn worsted yarns were made on the yarn drawing system with various drawing conditions such as concentration of reducing agent, draw ratio, setting time of drawn yarn and concentration of oxidizing agent. The dry and wet shrinkage, irregularity(CV%), thin and thick part, hairiness and abrasion resistance of these various specimens were measured and discussed in terms of various drawing conditions.

• 한국염색가공학회지
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• 제23권2호
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• pp.100-106
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• 2011

UV-curable water-repellent finish was carried out to impart one-side repellency to the PET fabrics using a formulation of a UV-active fluorocarbon agent and a water soluble photoinitiator. The aqueous formulation was padded on the PET fabrics and it was subsequently UV-cured. The unirradiated side of the cured fabrics was made to wetteable to water by the prolonged UV/ozone irradiation. The influence of photoinitiator concentration, agent concentration and UV energy for photodegradation on the performance of the finished fabrics were investigated. The difference in the functional property of front and back sides was examined by measuring water repellency at each side of the treated fabrics, which resulted in four rating difference between two-side. The UV-cured and photodegraded PET surfaces were characterized by ATR, ESCA and FE-SEM.

• 한국염색가공학회지
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• 제23권2호
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• pp.107-117
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• 2011

Polyurethane (PU) was synthesized by one-shot process and the PU nanofiber was prepared by electrospinning. In this study, electrospun PU multi-membranes were prepared with various coating thickness ratio of base resin to top resin, where the base resin contains melamine curing agent and acid catalyst and the top resin contains water-repellent agent of fluoro-carbon compounds. The PU nanofiber multi-membranes were analyzed by field-emission scanning electron microscopy, differential scanning calorimeter, breathability, tensile strenth, air permeability and water resistance. The results showed that the PU multi-membrane provided excellent waterproof and moisture permeability.

• 한국염색가공학회지
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• 제11권3호
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• pp.23-31
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• 1999

In order to investigate the detergency of the mixture of compact detergent and bleaching agent to fabric stained with a coffee and a red wine, respectively, and a japanese wet stained fabrics, to evaluation of detergency was studied under various washing conditions. In order to study the effect of alkaline agent addition on the detergency, the soda ash was added in the compact detergent system. The results are as follows : In a low temperature washing condition, the alkalinity of washing liquor effected more the removal of the composite stained fabrics than that of oilic stained fabrics. For the colored stained fabric such as red wine stained sample, the influence of the repeated washing treatment on the detergency was not significant factor. On the other hand, the influence of the repeated washing treatment for the coffee stained and japanese wet stained fabric on the detergency was gradually increased.

• 한국염색가공학회지
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• 제9권6호
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• pp.79-86
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• 1997

The microcapsule for thermochromism is based on the polymerization reaction between epoxy resin and amine curing agent. The preparation process of microcapsule is based on dissolving or dispersing a hydrophobic core materials[one-dye-black(OBD), bis-phenol A(BPA), cetyl alcohol] in an aqueous solution of gelatin, epoxy resin and isophorondiamine(IPDA) ; the gelatin and IPDA used as a dispersion stabilizer and an hardening agent, respectively. The structures of epoxy resin and microcapsule materials have been analyzed by FT-IR and UV/Vis spectra. The mean diameter and size distribution of microcapsule are 1.46~1.75${\mu}{\textrm}{m}$ and 1.42, respectively. The DSC thermograms of microcapsules indicated 2 kinds of endothermic peaks at 47 and 322$^{\circ}C$. This is possibly corresponding to the melting peak of core material and wall meterial. These microcapsules are applied to the fabric by printing. Complex finished fabric showed a good wear resistance on rubbing test and the print pattern to the cotton fabric showed a reversible thermochromism ; ${\mu}_{max}$ are 580 nm below 4$0^{\circ}C$ and 276.5nm above 4$0^{\circ}C$ in ethanol/water(2/8), respectively.

• 한국염색가공학회지
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• 제10권3호
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• pp.1-9
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• 1998

The dyeing properties of modified wool were examined with a series of acid, reactive and cationic dyes. Cationic agent and sulphamic acid were applied to wool fabric for dye assist and resist effect. Wool pretreated with cationic agent showed better uptake of acid and reactive dyes than did untreated wool. On the other hand, the dyeing behavior of wool pretreated with sulphamic acid was found as follows : Acid dyes were poorly resisted with a hydrophobic mechanism but acid dyes were strongly resisted with a hydrophilic mechanism. Reactive dyes were also found to be effectively resisted. Sulphamic acid introduces sulphonate group into wool's structure, it has increased better uptake of cationic dyes than untreated wool. The degree of differential uptake depends on the level of pretreatment and produces a variety of tone-on-tone and multicolor effect in piece dyeing.

• 한국염색가공학회지
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• 제2권1호
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• pp.31-36
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• 1990

산화제를 함유한 셀룰로우스 아세테이트 필름을 피롤 증기 속에 노출시킴으로써 전도성 셀룰로우스/폴리피롤 복합체 필름을 합성하고 폴리피롤의 형성을 IR 및 전자현미경을 사용하여 확인했다. 복합체 내에 존재하는 폴리피롤의 형태는 사용한 산화제의 종류에 따라 다르게 나타났다. 산화제로 사용한 몇 가지 금속염화물 중에서 염화제 2철이 높은 전도도를 가지는 복합체를 합성하는데 가장 효과적이며 50중량 퍼센트의 염화제 2철을 첨가해서 제조한 복합체 필름의 전기전도도는 $10^{-2}S/cm$에 달한다.