• Title/Summary/Keyword: fine particle concentration

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A Study on the PVA Particle Manufacturing for Polymerization Type Fine Toner (중합형 미세토너 합성을 위한 PVA입자 제조에 관한 연구)

  • 전재우;우화령;이난형;류원석;김삼수
    • Textile Coloration and Finishing
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    • v.15 no.6
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    • pp.8-17
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    • 2003
  • In order to investigate the possibility of PVA particle as toner, PVA/PVAc particle was manufactured. Fine spherical PVAc particle with emulsifier SDS(sodium Dodecyl Sulfate) and initiator V-50(2,2'- azo bis(2-amidinopropane) dihydrochloride) was manufactured by emulsion polymerization. And then, the PVAc was carried with surface saponification. PVA/PVAc skin core structured particle was obtained under optimum saponification condition. PVA skin side in manufactured PVA/PVAc particles was dyed with 1:2 metal complex type C. I. Acid Yellow 235 and then the dyed PVA particles were observed with a optical microscope. Under given polymerization condition such as SDS concentration, $1.62\times{10}^{-2} \;mol/lH_2O$, V-50 concetration, $3.7\times{10}^{-3}\;mol/lH_2O$ and temperature $50^\circ{C}$ , the high molecular weight of PVAc with Pn 13,900 and PVA with Pn 3,400 was produced. The particle distribution of obtained PVAc microspheres was appeared highly at 60 and $100\mu{m}$, respectively.

A study on the Manufacture of the CuO Powder from Copper Chloride Solution by Spray Pyrolysis Process (분무열분해법에 의한 구리염화물 용액으로부터 CuO 분말 제조에 관한 연구)

  • Yu, Jae-Geun;Park, Hui-Beom
    • Korean Journal of Materials Research
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    • v.12 no.1
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    • pp.58-67
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    • 2002
  • In this study copper chloride(CuCl$_2$) solution was used as raw material to produce the fine copper oxide powder which has less than 1 $\mu\textrm{m}$ average particle size and has uniform particle size distribution by spray pyrolysis process. In the present study, the effects of reaction temperature, the injection speed of solution and air, the nozzle tip size and the concentration of raw material solution on the properties of produced powder were studied. The structure of the powder became much more compact with increasing the reaction temperature regardless of copper concentration of the raw material solution. The particle size of the powder increased accordingly with increasing the reaction temperature in case of 30 g/$\ell$ copper concentration of the solution. The particle size of the powder increased accordingly, and the surface structure of the powder became more porous with increasing the copper concentration of the raw material solution. When copper concentration in raw material solution was more than 100 g/$\ell$, all produced powder was CuCl regardless of reaction temperatures. When copper concentration in solution was below 30 g/$\ell$ and reaction temperature was higher than 90$0^{\circ}C$, CuO was the main phase. The surface of the powder tended to become porous with increasing the injection speed of solution. Particle size was increased and the surface of the powder showed severely disrupted state with increasing the nozzle tip size. The particle size was decreased and the particle size distribution was more uniform with increasing the air pressure through the nozzle.

Y-TZP Fine Powder Preparation by Ultrasonic Spray Pyrolysis (초음파 분무 열분해법에 의한 Y-TZP 미립자의 합성)

  • 이정형;김복희;최의석;황재석
    • Journal of the Korean Ceramic Society
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    • v.30 no.4
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    • pp.325-331
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    • 1993
  • Aqueous solutions of metallic salts, ZrO(NO3)2.2H2O and Y(NO3)3.5H2O were used as raw materials to synthesize crystalline submicron spherical powders of Zr0.94Y0.06O1.97 with tetragonal crystal phase. Each aqueous solution was mixed on the magnetic stirrer to homogenize for 12 hours. The concentration of the mixed solutionwas changed from 0.01mol/$\ell$ to 0.1mol/$\ell$ calculated as the concentration of Zr0.94Y0.06O1.97. Ultrafine droplets of starting mixed solution were sprayed by the ultrasonic vibrator and carried into the furnace kept at 55$0^{\circ}C$, $650^{\circ}C$, 75$0^{\circ}C$ and 85$0^{\circ}C$ using carrier gas of air (10$\ell$/min) and pyrolysed to form Y-TZP fine powders. The results of this exeriment were as follows. 1) Synthesized powders were nonagglomerated and spherical type. 2) Particle size distribution was narrow between 0.1${\mu}{\textrm}{m}$ and 1${\mu}{\textrm}{m}$. 3) Forming reaction Y-TZP was finished above synthetic temperature 75$0^{\circ}C$. 4) As the synthetic temperature rised from 55$0^{\circ}C$ to 85$0^{\circ}C$, the mean particle size decreased from 0.35${\mu}{\textrm}{m}$ to 0.22${\mu}{\textrm}{m}$ in the concentration of starting solution with 0.02mol/$\ell$. 5) At 75$0^{\circ}C$ of synthetic temperature, the concentration changes of starting solution from 0.01mol/$\ell$ to 0.1mol/$\ell$ increased the mean particle size from 0.24${\mu}{\textrm}{m}$ to 0.38${\mu}{\textrm}{m}$. 6) Chemical compositions of each synthesized particle were homogeneous nearly.

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A Study on the Size Distribution and Chemical Component of Suspended Particulate during the Period of Sandy Dust Phenomena (黃砂現象時 粉塵의 粒度分布와 化學組成에 關한 硏究)

  • Lee, Min-Hee;Han, Eui-Jung;Shin, Chan-Ki;Han, Jin-Suk
    • Journal of Korean Society for Atmospheric Environment
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    • v.4 no.2
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    • pp.57-66
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    • 1988
  • Sandy dust phenomena was observed from April 19 to 23, 1988 in Seoul and suspended particulate was collected by Andersen air sampler during this period. The samples were analyzed for 16 components $(SO_n^{2-}, NO_3^-, Cl^-, PO_4^{3-}, NH_4^+, F^-, Al, Fe, K, Cu, Mn, Na, Pb, Mg, Ca, Cd)$. The conclusions are as follwes: 1. Total suspended particulate concentation during the period of sandy dust phenomena was 489 $\mug/m^3$ (ordinary times: 140-125 $mug/m^3$) 2. The water - soluble ion component concentration of suspended particulate during the period of sandy dust phenomena was few and the metal concentration of that was more than that of ordinary times. 3. The cumulative frequency distribution of suspended particulates in logarithmic diagram did not show similar to normal log distribution during the period of sandy dust phenomena. 4. $SO_4^{2-}, NO_3^-, Cl^-, and PO_4^{3-}$ was onsided to coarse particle, and $NH_4^+$ and F to fine particle in the size distribution of water - soluble ion components during the period of sandy dust phenomena. 5. Metal concentration was high and Al, Fe, Cu, Mn, Na, Mg, and Ca was onsided to coarse particle, and K, Pb, and Cd to fine particle in the size distribution of metal components. 6. During the period of sandy dust phenomena the quantity of respirable particle (< 1 $\mum$) was about 3 times and that of metal components were about 2 - 11 times than that of ordinary times. 7. The concentrations of $NO_3^-, Cl^-, NH_4^+$ at ordinary times were 1.1 - 4 time than that of the period of sandy dust phenomena.

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The Properties of Roadway Particles from the Interaction between the Tire and the Road Pavement (실제 도로 주행과정에서 타이어와 도로의 마찰에 의해서 발생하는 미세입자의 특성연구)

  • Lee, Seok-Hwan;Kim, Hong-Suk;Park, Jun-Hyuk;Cho, Gyu-Baek
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.2
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    • pp.131-141
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    • 2012
  • A large fraction of urban $PM_{10}$ concentrations is due to non-exhaust traffic emissions including road dust, tire wear particles, and brake lining particles. Although potential health and environmental impacts associated with tire wear debris have increased, few environmentally and biologically relevant studies of actual tire wear debris have been conducted. Tire wear particles (TWP) are released from the tire tread as a result of the interaction between the tire and the pavement. Roadway particles (RP), meanwhile, are particles on roads composed of a mixture of elements from tires, pavements, fuels, brakes, and environmental dust. The main objective of present study is to identify the contribution of tires to the generation of RP and to assess the potential environmental and health impacts of this contribution. First, a mobile measurement system was constructed and used to measure the RP on asphalt roads according to vehicle speed. The equipment of the mobile system provides $PM_{10}$ concentrations by Dusttrak DRX and number density & size distribution measurements of fine and ultra-fine particles by a fast mobility particle sizer (FMPS) and an aerosol particle sizer (APS). When traveling on an asphalt road at constant speed, there is a clear tendency for $PM_{10}$ concentration to increase slightly in accordance with an increase in the vehicle speed. It was also found that considerable brake wear particles and particles from tire/road interface were generated by rapid deceleration of the vehicle. As a result, the $PM_{10}$ concentration and particle number of ultra-fine particles were measured to be very high.

Applicability of hiding-exposure effect to suspension simulation of fine sand bed (가는 모래의 부유 모의시 차폐효과 고려의 영향)

  • Byun, Jisun;Son, Minwoo
    • Journal of Korea Water Resources Association
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    • v.54 no.8
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    • pp.607-616
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    • 2021
  • The purpose of this study is to simulate the transport of nonuniform sediment considering the hiding-exposure effect numerically. In order to calculate the transport of multi-disperse suspended sediment mixtures, the set of advection-diffusion equations for each particle class is solved. The applicability of the numerical model is examined by comparing the simulation results with experimental data. In this study, we calculate the vertical distribution of total concentration of sediment particles using two approaches: (1) by considering the mixture as represented by a single size; and (2) by combining the concentration of the sediment corresponding to several particle size classes; From the simulation results, it is shown that both approaches calculate reasonable results due to the narrow range of size distribution. Under the condition of nonuniform sediment, the critical shear stress of the sediment particle is influenced by the size-selective entrainment, i.e., hiding-exposure effect. It is shown in this study that the effect of hiding-exposure effect on the erosion rates of fine sand is negligibly small.

Visualization of the Comparison between Airborne Dust Concentration Data of Indoor Rooms on a Building Model (실내 공간별 미세먼지농도 비교 데이터의 시각화)

  • Lee, Sangik;Lee, Jin-Kook
    • Journal of the Korean housing association
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    • v.26 no.4
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    • pp.55-62
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    • 2015
  • The international concern on the inhalable fine dust is continuing to increase. In addition to the toxic properties of the fine dust itself, it can be more dangerous than other environmental factors since the dust pollution is hard to be detected by human sense. Although the information on outdoor air condition can be acquired easily, the indoor dust concentration is another problem because the indoor air condition is influenced by the architectural environment and human activity. It means occupants may be exposed to indoor dust pollution over a long period without being aware. Therefore the indoor dust concentration should be measured separately and visualized as an intuitive information. By visualizing, the indoor dust concentration in each space can be recognized practically in compare with the degree of pollution in adjacent spaces. Besides the visualization outcome can be used as base data for related research such as an analysis of the relation between indoor dust concentration and architectural environment. Meanwhile, with the development of network and micro sensing devices, it became possible to collect wide range of indoor environment data. In this regards, this paper suggests a system for visualization of indoor dust concentration and demonstrates it on an actual space.

Characteristics of Inorganic Components in Fine Particles Collected at Chunchon during the Springtime Yellow Sand Occurrence Period in 2002 (춘천에서 2002년 봄철 황사 발생기간 동안에 채취된 미세분진 중 무기성분의 특성)

  • 김희갑;정경미;김동진;이종태
    • Environmental Analysis Health and Toxicology
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    • v.17 no.4
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    • pp.333-339
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    • 2002
  • Yellow sand (YS) storms were observed about ten times in the Korean peninsula during March and April in 2002. Twenty four hour fine particle (PM$\_$2.5/) samples were collected onto the 47 mm Teflon - coated quartz filters over 9 days during and after the events using the MiniVol Portable Air Sampler at a flow rate of 5 liters per minute. The highest PM$\_$2.5/ concentration measured during the YS period was 289 $\mu\textrm{g}$/㎥, which is 13 times higher than the lowest of the values for the samples collected during the non-yellow sand period. The filter samples were analyzed for inorganic ions using the IC, AAS and Autoanalyzer, and for metals using the ICP-MS. The results showed that the concentrations of some inorganic ions (e.g., Ca$\^$2+/ and SO$_4$$\^$2-/) and metals (e.g., Fe, Mn) of soil origin were elevated during the yellow sand events.

Dispersion Modeling of Fine Carbon Fibers in Atmospheric Boundary Layer (대기경계층에서 미세 섬유 확산 모델링)

  • Kim, Seog-Cheol;Hwang, Jun-Sik;Lee, Sang-Kil
    • Journal of the Korea Institute of Military Science and Technology
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    • v.11 no.3
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    • pp.169-175
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    • 2008
  • A fine carbon fibers dispersion model is implemented to calculate the scattering range and ground level concentration of carbon fibers emitted at certain altitudes of atmospheric boundary layer. This carbon fibers dispersion model was composed by coupling a commonly used atmospheric dispersion model and an atmospheric boundary layer model. The atmospheric boundary layer model, applying the Monin-Obukov Similarity Rule obtained from measurement input data at ground level, was used to create the atmospheric boundary layer structure. In the atmospheric dispersion model, the Lagrangian Particle Model and the Markov Process were applied to calculate the trajectory of scattered carbon fibers relative to gravity and aerodynamic force, as well as carbon fibers specification.

Synethisis of fine BSCCO precursor powder by spray pyrolysis (분무 열분해에 의한 미세 BSCCO 전구체 분말의 합성)

  • 김성환;유재무;고재웅;김영국;박성창
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.10a
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    • pp.99-102
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    • 2003
  • Many researches on synthesis process for BSCCO precursor powders have been developed for high J$_{c}$ BSCCO-2223/Ag tape. Spray pyrolysis method for fabrication of precursor powder has many advantages, such as high purity, fine particle size of BSCCO precursor powder. Fine, spherical powders were prepared by ultrasonic spray pyrolysis from the aqueous solution of metal nitrates. BSCCO precursor powders were synthesized with 0.1 M concentration and heat treatment conditions. Average particle size for spray pyrolysis powders was 1.5 ~ 3 ${\mu}{\textrm}{m}$. BSCCO -2223/Ag tape was prepared by PIT method and followed by various sintering conditions. The critical current density of BSCCO-2223/Ag tape sintered in low oxygen partial pressure was ~ 23 kAcm$^{-2}$.

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