• Title/Summary/Keyword: fine dispersion

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Preparation of Au fine particle dispersed $TiO_2$ film by sol-gel and photoreduction process

  • Hyun, Buh-Sng;Kim, Byeong-Il;Kang, Won-Ho
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.09a
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    • pp.103-111
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    • 1998
  • Au fine particle dispersed TiO2 film was prepared on silica glass substrate by sol-gel dip and firing process. The films were fabricated from the system of titanium tetraisoproxie-EtOh-HCl_H2O-hydrogen tetrachloroaurate(III) tetrahydrate. The conditions for the formation of the clear solution and dissolving high concentration of Au compound were examined. And a photoreduction process was adopted to control the size of gold metal particles. Phase evolution of matrix TiO2 and variation of Au particle with UV irradiation were investigated by XRDA, SEM, TEM and UV-visible spectrophotometer. And the effect of CPCl(Cetylpyridinium chloride monohydrate) as a dispersion agent was evaluated.

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Compaction of Ultra-fine WC Powder by High-Speed Centrifugal Compaction Process

  • Suzuki, Hiroyuki Y.;Kadono, Yuichi;Kuroki, Hidenori
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.24-25
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    • 2006
  • High-Speed Centrifugal Compaction Process is one of slip-using compacting method originally developed for processing of oxide ceramics. In this study, we apply the HCP to ultra-fine (0.1 micron) WC powder. Organic liquid of heptane was chosen as dispersing media to avoid possible oxidation of WC. The mixing apparatus was a key to obtain dense compacts. Only the slips mixed by high energy planetary ball mill were packed up to 55% by the HCP, and sintered to almost full density at 1673 K without any sintering aids. This sintered compact marked Vickers hardness of Hv 2750 at maximum.

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The Evaluation of Thermal Properties for W-Cu Composite Sintered from Mechanically Alloyed Powders (기계적 합금화한 W-Cu 복합분말 소결체의 열물성 평가)

  • 오낭렴;김대건;석명진;김영환;김영도;문인형
    • Journal of Powder Materials
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    • v.7 no.3
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    • pp.154-160
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    • 2000
  • In order to enhance sinterability of W-Cu composites used for heat sink materials, mechanical alloying process where both homogeneous mixing of component powders and fine dispersion of minor phase can be easily attained was employed. Nanostructured W-Cu powders prepared by mechanical alloying showed W grain size ranged of 20-50 nm and were able to be efficiently sintered owing to the fine particle size as well as uniform distribution of Cu phase. The thermal properties such as electrical resistivity, coefficient of thermal expansion and thermal conductivity were evaluated as functions of temperature and Cu content. It was found that the coefficient of thermal expansion could be controlled by changing Cu content. The measured electrical resistivities and thermal diffusivities were also varied with Cu content. The thermal conductivities calculated from the values of resistivities and diffusivities showed similar tendency as a function of temperatures. However, this is in contradiction with thermal conductivities of pure W and Cu which decrease with increasing temperature.

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Influence of Carburizing on the Mechanical Properties of Martensitic Stainless Steel (마르텐사이트계 스테인레스강의 기계적 성질에 미치는 침탄처리의 영향)

  • Kim, In-Bae;Park, Se-Yoon;Lee, Chang-Ho
    • Journal of the Korean institute of surface engineering
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    • v.17 no.1
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    • pp.7-13
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    • 1984
  • Carburizing of a 12%Cr steel containing 0.6%Si was performed at 950$^{\circ}C$ for various times, and the microstructure, hardness and the water characteristics of the carburized chromium steel were examined. The results obtained in this study are as follows: 1. Carbide-dispersed layer (CD layer) with fine dispersion of $Cr_7C_3$ in martensite matrix was formed by carburizing. The radius and amount of the carbides in the surface region of CD layer were about 0.3${\mu}m$ and 35% by volume, respectively. 2. Chromium steel carburized and quench-tempered showed better wear resistance and hardness than ordinary high chromium tool steel. It is concluded from these results that fine dispered carbides are very effective in improving wear resistance and hardness.

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A New Hybrid Method for Flow-Dominated Transport

  • Lee, Jung-Lyul
    • Proceedings of the Korean Society of Coastal and Ocean Engineers Conference
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    • 1997.10a
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    • pp.110-115
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    • 1997
  • Recently, since one of the most important societal problems facing us today is the growing incidence of the contamination of coastal sea from variety of sources, several distinct numerical improvements have been made and applying the transport models to flow-dominated transport area. Application of Eulerian numerical models to the solution of sharp-front problems often results in oscillations, phase errors, peak depression, and/or numerical dispersion, unless very fine temporal and spatial steps are adopted. (omitted)

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Magnetic Separation for Water Treatment

  • Lee, Sang-Heon;Choi, Yong
    • Proceedings of the KIEE Conference
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    • 2008.10a
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    • pp.115-116
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    • 2008
  • YBCO materials in the form of large single crystals without weak link probleum is necessary. A refreshment and uniform distribution of the Y211 particles in the YECO were achived by sintering the Ag doped samples. The $em{\backslash}nhancement$ of the critical current density was ascribable to a fine dispersion of the YBCO particles, a low porasity and the persence of Ag particles. In $addir{\backslash}tion$, we have designed and manufactured large YBCO single domain with levitation force.

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Development of Ceramic Superconductor Bulk for Electric Energy resonance (초전도 화합물 세라믹 벌크 개발)

  • Lee, Sang-Heon;Choi, Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.42-43
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    • 2008
  • The numerous application of ceramic superconducting bulk such as magnetic levitation train flywheel energy, levitation transpormation, magnetic bulk magnet etc. To obtain YBaCuO materials in the form of large single crystals are necessary. A refreshment and uniform distributon of the superconducting particle in the sample. The enhancement of the critical density was ascribe to a fine dispersion of the superconducting particle.

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The Characteristics of Poly(acrylamide)-SiOx Nanoparticles Prepared by Graft-polymerizaton (그라프트 중합에 의해 만들어진 폴리아크릴아마이드-실리카 나노 입자의 특성)

  • Min, Jun Ho;Min, Seong Kee
    • Applied Chemistry for Engineering
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    • v.21 no.1
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    • pp.34-39
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    • 2010
  • Methacryloxypropyltrimethoxysilane (MPTMS) was used for the surface modification of silica nanoparticles in the toluene dispersion system for 8 h (MPSN). Then, methacryloxypropyl-modified silica nanoparticles were successfully prepared by solutioun polymerization in the ethanol solution at $60^{\circ}C$ for 14 h with adding AIBN initiator. The modification of ultra-fine particles (SiOx-PAA nanospheres) was investigated via EA, XPS, FTIR, TGA, SEM and TEM. The mean diameter of the bare silica nanoparticles, MPSN and SiOx-PAA monodisperse nanoparticles was about 25, 30 and 35 nm, respectively.

Flow Characteristics of Fine Particles for Separated Device Shapes (분리장치의 형상에 따른 미립자 유동특성)

  • Hwang, Seon Kyeong;Lee, Seoung Soo;Jung, Hyo Sang
    • Journal of the Korean Society for Precision Engineering
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    • v.30 no.5
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    • pp.544-551
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    • 2013
  • Recently high speed mixer, which is mixing, grinding, dispersion for liquid-liquid material, has been widely used several industries such as food, cosmetics, pharmaceuticals, fine chemicals, electronic material. This high speed mixer has a core element part called particle separation device. Particle separation device, which makes mixed liquid and liquid material using shear forces from a rotor and a stator, is a decisive factor in the distributed parts. In this study, we examined the velocity distribution of the two models of particle separation device using computation fluid dynamics, so that we were able to see the difference of the velocity distribution according to the shape. Also, by experiment, we observed that the use of rotor-screen type is deemed more suitable in case of accurately considering the effect of improving of the dispersibility through the circulation of the future.

Study on Magnetic Property Enhancement of Metal Powders for Magnetic Tape by Using Ultrasonic Dispersion (자기테이프용 Metal Powder의 초음파 분산에 의한 자기적 특성 향상에 관한 연구)

  • Kim, Chang-Gon;Choe, Hyeon-Seung;Jang, Hak-Jin;Yun, Seok-Yeong;Kim, Tae-Ok
    • Korean Journal of Materials Research
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    • v.11 no.11
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    • pp.972-977
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    • 2001
  • It was investigated the effect of ultrasonic treatment on magnetic property of ultra fine magnetic Fe powders ($\alpha$-Fe) for magnetic tape. The properties were characterized with vibrating sample magnetometer (VSM), particle size analyzer (PSA) and scanning electron microscope (SEM). At 4hours ultrasonic treatment of 70 kHz, magnetic properties such as squareness ratio (S.Q. : 0.8868), orientation ratio (O.R. : 2.45) and switching field distribution (S.F. D. : 0.394) before taping were relatively enhanced. Cumulative particle size distribution of less than 5$\mu\textrm{m}$ fine powder was above 90% below 1 hour leaving time after ultrasonic treatment and it was supposed that ultrasonic treatment prevent aggregation. The magnetic values of S.Q. and S.F.D. of tape manufactured at 70 kHz and 4hour ultrasonic treatment were improved from 0.7747, 0.3818 to 0.8037, 0.3706, respectively. Electro-magnetic property used as in-output signal characteristic was improved, which showed that ultrasonic treatment developed the magnetic properties.

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