• Title/Summary/Keyword: filler size effect

Search Result 96, Processing Time 0.028 seconds

Effect of Filler on the Physical Properties of Silicone Rubber Impression Material (실리콘 고무인상재의 물성에 미치는 충전제의 영향)

  • Chung, Kyung-Ho;Kang, Seung-Kyung
    • Elastomers and Composites
    • /
    • v.41 no.3
    • /
    • pp.157-163
    • /
    • 2006
  • In this study, the wettability and mechanical properties of silicone rubber impression material were studied by using precipitated silica and fumed silica with different particle size and polarity (hydrophilic/hydrophobic). Curing time of impression material depended on the particle size of fumed silica. The curing time delayed about 9 minutes by using A300, which was the fumed silica with the smallest particle size among the silica used in this study. Wettability of rubber impression material improved with the introduction oi hydrophobic fumed silica(R972). Also, the optimum flow and mechanical properties could be obtained by using blended silica with the 90: 10 ratio of precipitated and fumed silica.

Effect of Aging Time of AlO(OH) Gel Precipitated by Hydrolysis of Aluminum Sulfate on Crystal Growth of the Flaky α-Al2O3 (황산알루미늄의 가수분해에 의해 석출된 AlO(OH) 겔의 숙성시간이 판상 α-Al2O3의 결정성장에 미치는 영향)

  • Choe, Dong-Uk;Park, Byung-Ki;Suh, Jeong-Kwon;Lee, Jung-Min
    • Journal of the Korean Ceramic Society
    • /
    • v.43 no.9 s.292
    • /
    • pp.575-581
    • /
    • 2006
  • To precipitate the complex gel of flux and aluminum hydroxides gel, aqueous solution of the mixture of $Na_2CO_3\;and\;Na_2PO_4{\cdot}12H_2O$ was added with stirring in aqueous solution of the mixture of $Al_2(SO_4)_3{\cdot}14{\sim}18H_2O,\;Na_2SO_4$, and then the complex gel was aged in $0{\sim}30h\;at\;90^{\circ}C$. As aging time passed, the aluminum hydroxides was grown into the acicular AlO(OH) gel. Also, aging time had an effect on physical properties of the AlO(OH) gel and on crystal growth of the flaky ${\alpha}-Al_2O_3$ prepared by molten-salt precipitation. In this study, the complex gel was crystallized in temperature range of $400{\sim}1,200^{\circ}C$ after drying at $110^{\circ}C$, and then it was investigated to effect of aging time on precipitation temperature, size, thickness, morphology and particle size distribution of the flaky ${\alpha}-Al_2O_3$ crystal. As aging time passed, the flaky a${\alpha}-Al_2O_3$ crystal showed a tendency toward an increase in size and thickness as result from an increase in BET surface area and pore volume of the acicular AlO(OH) gel.

Effect of Cationic Starch and MFC Addition on the Flocculation Behaviour of GCC (양이온성 전분과 MFC 투입이 GCC의 응집거동에 미치는 영향)

  • Yong, Seong Moon;Lee, Yong Kyu;Won, Jong Myoung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.48 no.1
    • /
    • pp.82-92
    • /
    • 2016
  • The reduction of carbon dioxide emission is hot issue in the world because we are confronted with serious global warming and climate change. As a part of carbon dioxide reduction efforts, various approaches for increasing filler loading have been carried out in order to decrease the energy consumption in papermaking processes. Effects of the pretreatment of GCC with cationic starch and MFC on the flocculation behaviour of GCC were investigated in this study. Pretreatment of GCC with cationic starch caused the change of electric charge of suspension and flocculation behaviour of GCC. Largest flocculation size was obtained near the isoelectric point in the case of cationic starch treatment. When MFC (30 times grinded) was added after preflocculation of GCC with cationic starch, the flocculation size was increased, but largest flocculation size was obtained at -150 mV of electric charge of suspension in this study. However the addition of highly grinded MFC (60 times grinded) caused smaller flocculation size of GCC than those of MFC (30 times grinded). When GCC and MFC were mixed first, and then cationic starch was added, the characteristics of MFC and the change of electric charge which could be brought by cationic starch did not affect the flocculation size of GCC at all. The flocculation size obtained by the combination of cationic starch and MFC was smaller than those of cationic starch. These results show that flocculation behaviour could be controlled by the change of electric charge of suspension and the combination methods of cationic starch and MFC.

Filler-Elastomer Interactions. 3. Microstructures and Mechanical Interfacial Properties of Anodized Carbon Black/Rubber Composites

  • Park, Soo-Jin;Kim, Jeong-Soon;Lee, Jae-Rock
    • Carbon letters
    • /
    • v.1 no.3_4
    • /
    • pp.138-142
    • /
    • 2001
  • The effect of electrochemical surface treatments in KOH chemical solution on microstructures of carbon blacks was investigated in terms of surface functional values and XRD measurements. And their mechanical interfacial properties of the carbon blacks/rubber composites were studied by the composite tearing energy ($G_{IIIC}$). It was found that the development of basic-surface functional groups lead to the significant physical changes of carbon blacks, such as, decrease of the interlayer spacing ($d_{002}$), increase of the crystalline size along c-axis ($L_c$), and increase of degree of crystalline (${\chi}_c$). This treatment is possibly suitable for carbon blacks to be incorporated in a hydrocarbon rubber matrix, resulting in improving the hardness and tearing energy of the resulting composites.

  • PDF

Effective Noise Suppression in Edge Region Using Modified Wiener Filter (수정된 Wiener 필터를 사용한 에지 영역에서의 효과적인 잡음 제거)

  • Song Young-Chul
    • The Transactions of the Korean Institute of Electrical Engineers D
    • /
    • v.52 no.3
    • /
    • pp.173-180
    • /
    • 2003
  • The modified Wiener filtering method is proposed for effective noise suppression in edge region of images corrupted by additive white gaussian noise. Although the pixels classified as a edge region in the conventional Wiener filter have lots of noise components, the conventional Wiener filler cannot remove noise effectively due to the preserving of edges. To reduce noise well in edge region, we modify filter coefficients of the conventional Wiener filter The modified filter coefficients increase in noise suppression effect In edge region, while they preserve edges for strong edge region. From simulation $(256{\time}256$ size, 256 graylevel images) filtered images by the proposed method show much improved subjective image quality with some improved peak signal-to-noise ratio compared to those by the conventional Wiener filtering.

Modification of GCC with Poly-DADMAC and PSS with Different Molecular Weights and its Effect on the Paper Properties (Poly-DADMAC과 PSS의 분자량을 달리한 중질탄산칼슘의 개질과 종이 물성에 미치는 영향)

  • Ahn, Jungeon;Lee, Jegon;Lee, Hye Yoon;Youn, Hye Jung;Lee, Hak Lae
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.44 no.5
    • /
    • pp.21-31
    • /
    • 2012
  • In this study, we modified the surface of ground calcium carbonate (GCC) with polyelectrolytes with different molecular weight using Layer-by-Layer (LbL) multilayering technique and investigated its effect on the paper properties. Polydiallydimethylammonium chloride (poly-DADMAC) and poly sodium 4-styrene sulfonate (PSS) which have different molecular weights were used for LbL multilayering. Zeta potential and particle size of the LbL modified GCC were measured. After preparation of handsheets, their structural and mechanical properties were evaluated. The zeta potential and average particle size of the modified GCC were affected by the molecular weight of anionic polyelectrolyte (PSS). The zeta potential was higher and the particle size was smaller when GCC was treated by PSS with high molecular weight compared to the case with low molecular weight of PSS. The tensile and internal bond strength of the handsheets was increased with an increase in the number of layers on GCC particles, but the molecular weight of polyelectrolyte did not significantly affect the paper strength.

Effect of the Holding Temperature and Vacuum Pressure for the Open Cell Mg Alloy Foams

  • Yue, Xue-Zheng;Hur, Bo-Young
    • Korean Journal of Materials Research
    • /
    • v.22 no.6
    • /
    • pp.309-315
    • /
    • 2012
  • Metal foam has many excellent properties, such as light weight, incombustibility, good thermal insulation, sound absorption, energy absorption, and environmental friendliness. It has two types of macrostructure, a closed-cell foam with sealed pores and an open-cell foam with open pores. The open-cell foam has a complex macrostructure consisting of an interconnected network. It can be exploited as a degradable biomaterial and a heat exchanger material. In this paper, open cell Mg alloy foams have been produced by infiltrating molten Mg alloy into porous pre-forms, where granules facilitate porous material. The granules have suitable strength and excellent thermal stability. They are also inexpensive and easily move out from open-cell foamed Mg-Al alloy materials. When the melt casting process used an inert gas, the molten magnesium igniting is resolved easily. The effects of the preheating temperature of the filler particle mould, negative pressure, and granule size on the fluidity of the open cell Mg alloy foam were investigated. With the increased infiltration pressure, preheat temperature and granule sizes during casting process, the molten AZ31 alloy was high fluidity. The optimum casting temperature, preheating temperature of the filler particle mould, and negative pressure were $750^{\circ}C$, $400-500^{\circ}C$, and 5000-6000 Pa, respectively, At these conditions the AZ31 alloy had good fluidity and castability with the longest infiltration length, fewer defects, and a uniform pore structure.

Effect of Particle Size of the Filler on the Thermal Properties of the Sealing Glass for Solid Oxide Fuel Cells (필러의 입자크기가 고체전해질 연료전지용 밀봉유리의 열적 특성에 미치는 영향)

  • Cho, Min-Young;Moon, Ji-Woong;Lee, Mi-Jae;Choi, Byong-Hyun;Park, Sun-Min;Hwang, Hae-Jin;Choi, Heon-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2007.11a
    • /
    • pp.305-305
    • /
    • 2007
  • SOFC용 밀봉유리$({\sim}10.0{\times}10^{-7}/K)$의 열팽창 계수를 SUS430$({\sim}12.0{\times}10^{-7}/K)$ 인터커넥터에 매칭 시키기 위하여 모유리에 비하여 열팽창계수가 큰 $CaTiO_3\;({\sim}13.5{\times}10^{-7}/K)$ 입자를 필러로서 첨가하였다. 필러입자의 첨가량이 증가함에 따라 밀봉재의 열팽창 계수가 증가하고, 동일 함량의 필러를 첨가하는 경우 필러 입자의 크기가 작을 수록 밀봉재의 연화점 상승 폭이 커서 SUS430 기판과의 접합 상태가 불량해짐을 관찰하였다. 필 테스트, 접합시험, 미세구조 분석 등을 통하여 필러 입자 크기가 증가 할 수록 SUS430과의 접합이 가능한 범위 내에서 보다 많은 양의 필러를 첨가하는 것이 가능하기 때문에 열팽창 계수 제어가 용이하다는 것을 확인 할 수 있었다.

  • PDF

Fabrication, characterization, simulation and experimental studies of the ordinary concrete reinforced with micro and nano lead oxide particles against gamma radiation

  • Mokhtari, K.;Kheradmand Saadi, M.;Ahmadpanahi, H.;Jahanfarnia, Gh.
    • Nuclear Engineering and Technology
    • /
    • v.53 no.9
    • /
    • pp.3051-3057
    • /
    • 2021
  • The concrete is considered as an important radiation shielding material employed widely in nuclear reactors, particle accelerators, laboratory hot cells and other different radiation sources. The present research is dedicated to the shielding properties study of the ordinary concrete reinforced with different weight fractions of lead oxide micro/nano particles. Lead oxide particles were fabricated by chemical synthesis method and their properties including the average size, morphological structure, functional groups and thermal properties were characterized by XRD, FESEM-EDS, FTIR and TGA analysis. The gamma ray mass attenuation coefficient of concrete composites has been calculated and measured by means of the Monte Carlo simulation and experimental methods. The simulation process was based on the use of MCNP Monte Carlo code where the mass attenuation coefficient (μ/ρ) has been calculated as a function of different particle sizes and filler weight fractions. The simulation results showed that the employment of the lead oxide filler particles enhances the mass attenuation coefficient of the ordinary concrete, drastically. On the other hand, there are approximately no differences between micro and nano sized particles. The mass attenuation coefficient was increased by increasing the weight fraction of nanoparticles. However, a semi-saturation effect was observed at concentrations more than 10 wt%. The experimental process was based on the fabrication of concrete slabs filled by different weight fractions of nano lead oxide particles. The mass attenuation coefficients of these slabs were determined at different gamma ray energies using 22Na, 137Cs and 60Co sources and NaI (Tl) scintillation detector. The experimental results showed that the HVL parameter of the ordinary concrete reinforced with 5 wt% of nano PbO particles was reduced by 64% at 511 keV and 48% at 1332 keV. Reasonable agreement was obtained between simulation and experimental results and showed that the employment of nano PbO particles is more efficient at low gamma energies up to 1Mev. The proposed concrete is less toxic and could be prepared in block form instead of toxic lead blocks.

Study of Humidity Sensing Properties Related to Metal Content of Aerosol Deposited Ceramic/Metal Composite Films (에어로졸 증착한 세라믹/금속 복합막의 금속 함량에 따른 습도 감지 특성 연구)

  • Kim, Ik-Soo;Koo, Sang-Mo;Park, Chulhwan;Shin, Weon Ho;Lee, Dong-Won;Oh, Jong-Min
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.34 no.5
    • /
    • pp.314-320
    • /
    • 2021
  • Controlling ambient humid condition through high performance humidity sensors has become important for various fields, including industrial process, food storage, and the preservation of historic remains. Although aerosol deposited humidity sensors using ceramic BaTiO3 (BT) material have been widely studied because of their longtime stability, there remain critical disadvantages, such as low sensitivity, low linearity, and slow response/recovery time in case of the sensors fabricated at room temperature. To achieve superior humidity sensing properties even at room temperature condition, BT-Cu composite films utilizing aerosol deposition (AD) process have been proposed based on the percolation theory. The BT-Cu composite films showed gradually improved sensing properties until the Cu concentration reached 15 wt% in the composite film. However, the excessive Cu (above 30 wt%) containing BT-Cu composite films showed a rapid decrease of the sensing properties. The results of observed surface morphology of the AD fabricated composite films, to figure out the metal filler effect, showed correlation between surface topography as well as size and the amount of open pores according to the metal filler content. Overall, it is very important not only dielectric constant of the humidity sensing films but also microstructures, because they affect either the variation range of capacitance by ambient humidity or adsorption/desorption of ambient humidity onto/from the humidity sensing films.