• Journal of Conservation Science
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• v.26 no.3
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• pp.269-276
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• 2010

This study aims to extract manufacturing techniques by analysing metallurgical characteristics of the cast-iron pot from Bubjusa, examining corrosion status and microstructure with a optical microscope, SEM-EDS, micro vickers hardness tester and XRD. The microstructure analysis has presented that ferrite and partial portion of pearlite exist within the corroded outer layer. The analysis of the inner layer revealed that there is pearlite and graphite of feather shape. The one of the middle layer, which is placed between outer and inner layer, showed that corrosion has been heavily developed. Micro vickers hardness values range from 217Hv to 698Hv in constituent layers and such values lie within the ranges of the ancient iron relics. The result of EDS analysis for each microstructure presented that the outer layer has been more decarbonized than the inner layer. XRD analysis of iron corrosion compound revealed that Goethite and Hematite had been produced from the corrosive process of iron. The study concludes that the large iron pot was made by casting technique, and microstructure of inner layer had a gray cast iron. Outer layer has been decarbonized through repetitive process of heating and cooling. This results can be used as fundamental data for comparative study to reveal manufacturing techniques of large cast-iron pot.

• Korean Journal of Materials Research
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• v.2 no.6
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• pp.452-460
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• 1992

Effects of the microalloyed elements, temperatures and cooling rates on the strength and toughness of the medium carbon microalloyed hot forging steels obtained by air cooling(A.C.) method and the low carbon microalloyed forging steels by direct quenching(D.Q.) method were investigated. Combined additions of V+Nb produced the optimum combination of strength and toughness with ferrite-pearlite structure of the medium carbon steel by the A.C. method. 831MPa in UTS and 52.1J in toughness were obtained for 0.40c+0.12V+0.07Nb. It was martensite structure for the low carbon steel by the D.Q. method. The highest UTS and toughness obtained by Mo additions were 855MPa and 108j by 0.12C+0.10V+0.03Nb+1.13Mo respectively. Especially, the toughness of the low carbon steel was twice better than that of the medium carbon steel. 110$0^{\circ}C$was more appropriate than 120$0^{\circ}C$ for the reheating and forging temperature and 1.$2^{\circ}C$ /s was the best cooling rate from the viewpoint of the strength and toughness. Multiple regression analysis was used to quantify the influence of the microalloyed elements, temperatures and cooling rates on the strength, toughness, austenite grain size, and the pearlite interlamellar spacing.

• Journal of the Mineralogical Society of Korea
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• v.20 no.4
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• pp.231-245
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• 2007

The forged iron axe of the middle 3rd Century found in the No. 2 wood-framed tomb from the Hwangseongdong site, Gyeongju is rectangular on the plane level. The iron axe shines in met-allic luster, which is light grey with pale creamy tint. The result of X-ray diffraction analysis shows that the axe consists of magnetite and geothite, which can explain why the composition and texture of the original ore has been kept intact. There are fine-grained quartz, calcite, mica, magnetite, amphibole, unknown tungsten minerals, pyroxene and olivine inside the axe. Those must be the impurities that they failed to remove in the thermal treatment process. Generally, the iron axe consists mainly of pearlite texture coexisting ferrite and cementite, and show high carbon contents with homogeneous distribution. It can be interpreted the axe was carburized after the material was made to resemble pure iron. The decarbonization work didn't go well along the process marks. Crude ores of the iron axe are possible utilized by magnetite from the Ulsan mine on the basis of the occurrences and inclusions. It's estimated that the original ore was bloom produced in low-temperature reduction and formed around in $727^{\circ}C$, which is eutetic temperature.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.5
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• pp.252-261
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• 2017

This study examined the effect of heat treatment on the microstructure and mechanical properties of J55 line pipe steel. The experiments were carried out at under the following various conditions: austenization temperature($880^{\circ}C$, $910^{\circ}C$, $940^{\circ}C$), cooling methods(water quenching, oil quenching) and tempering temperature(none, $550^{\circ}C$, $650^{\circ}C$). The phase diagram and CCT curve were simulated based on the chemical composition of J55 steel to predict the microstructures. In the results, A1, A3 temperature decreased. As the austenization temperature increased, existing austenite grains grew exponentially which seriously degraded their mechanical properties. Various microstructures, including martensite, bainite, ferrite, and pearlite, developed in accordance with the heat treatments and were closely correlated with hardness, tensile strength and toughness. Martensite was formed after water quenching, but bainite and ferrite appeared after oil quenching. FeC precipitation formed and coarsened during tempering, which improved their toughness.

• Journal of Korea Foundry Society
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• v.43 no.6
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• pp.279-285
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• 2023

In order to predict the mechanical properties of ductile cast iron heat treated in an intercritical temperature range, samples machined from cast iron with a tensile strength of 450 MPa were heat-treated at various intercritical temperatures and air-cooled, after which a microstructural analysis and Brinell hardness test were conducted. As the heat treatment temperature was increased in the intercritical temperature range, the ferrite fraction in the ductile cast iron decreased and the pearlite fraction increased, whereas the nodularity and nodule count did not change considerably from the corresponding values in the as-cast condition. The Brinell hardness values of the heat-treated ductile cast iron increased gradually as the heat treatment temperature was increased. Based on the measured alloy composition, the fraction of each stable phase and the hardness model from the literature, the hardness of the ductile cast iron heat treated in the intercritical temperature range was calculated, showing values very similar to the measured hardness data. In order to check whether it is possible to predict the hardness of heat-treated ductile cast iron by using the phase fraction obtained from thermodynamic calculations, the volumes of graphite, ferrite, and austenite in the alloy were calculated for each temperature condition. Those volume fractions were then converted into areas of each phase for hardness prediction of the heat-treated ductile cast iron. The hardness values of the cast iron samples based on thermodynamic calculations and on the hardness prediction model were similar within an error range up to 27 compared to the measured hardness data.

• Corrosion Science and Technology
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• v.14 no.2
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• pp.47-53
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• 2015

Recently, the bending process is greatly applied to fabricate the pipe line. Bending process can reduce welding joints and then decrease the number of inspection. Thus, the maintenance cost will be reduced. Induction heat bending process is composed of bending deformation by repeated local heat and cooling. By this thermal process, corrosion properties and microstructure can be affected. This work focused on the effect of induction heating bending process on the properties of ASME SA106 Gr. C low carbon steel pipes. Microstructure analysis, hardness measurements, and immersion corrosion test were performed for base metal and bended area including extrados, intrados, crown up, and down parts. Microstructure was analyzed using an optical microscope and SEM. Hardness was measured using a Rockwell B scale. Induction heat bending process has influenced upon the size and distribution of ferrite and pearlite phases which were transformed into finer structure than those of base metal. Even though the fine microstructure, every bent area showed a little lower hardness than that of base metal. It is considered that softening by the bending process may be arisen. Except of I2, intrados area, the others showed a similar corrosion rate to that of base metal. But even relatively high rate of intrados area was very low and acceptable. Therefore, it is judged that induction heat bending process didn't affect boric acid corrosion behaviour of carbon steel.

• 보존과학연구
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• s.22
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• pp.115-132
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• 2001

No. 3 Tomb of Bogam-ri, in Naju City, Chollanam-do Province, was a site excavated and inspected from 1996 to 1998 and had a various grave forms, including jar-coffins, stone-chambers and stone-cists. Although most of the metal artifacts excavated from it were severely corroded, we could implement microstructure investigation by collecting samples from the iron axes, iron coffin-nails and iron clamps in which the metal parts were remained. The metal structures were inspected by using metallographic microscope and SEM, and fine components analysis was implemented by ICP. To examine the hardness differences in accordance with the structure distribution, we measured the hardness by structures with Vickers hardness testing machine. As a result of the metal structure inspection, most of them were pure iron, ferrite, and also pearlite, cementite and widmannstaten structures were displayed. We could confirm carbonization was formed on the surface of the iron axes-B, iron coffin-nails-B, and iron clamps-A. There was no carbonization in the rest of the artifacts, and it is not certain that whether the carbonized parts were peeled off through extreme corrosion or they were not carbonized when they were made. In the particular part of a blade, the quality of the material was strengthened through processing. Due to the processing re-grain was caused and fine grain particles were formed. As a result of the ICP component analysis, there were no addition atoms because pure irons were used as materials. In the mean time, No. 17 jar-coffin where the iron axes-A are excavated, is chronologically ordered as from the late-fourth century to the mid-fifth century, and No. 1 and No. 2 stone chambers, where the rest of the artifacts were excavated, as the early-sixth century. It was difficult to relate the periodic differences with the manufacture technique artifacts which we inspected because there were no distinct characteristics of the manufacture technique of the metal structures and it is impossible to conclude the artifacts and sites are at the same period although their periods are different.

• Journal of the Korean Society for Heat Treatment
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• v.26 no.2
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• pp.59-65
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• 2013

The microstructures and hardness distributions of a large-sized high strength H-sectional steel with both V and Nb were systematically examined. The outer surface of the flange part was composed of martensite and bainite due to faster cooling, and had a high hardness value of approximately 310 Hv. However, the amounts of ferrite and pearlite increased and the hardness decreased with increasing the distance from the outer surface at the flange part, except the inner surface. High hardness value of about 290 Hv was measured at the upper surface of the web part having martensite and bainite. The hardness drastically decreased with increasing the web thickness, and then greatly rose again at the lower surface due to bainite formation caused by fast air cooling. The hardness of the flange part was higher than that of the web part due to the larger amount of low-temperature transformed phases, except for the lower surface of the web part. Nb-rich precipitates of 30 to 50 nm and V-rich precipitates less than 20 nm were observed at both flange and web parts. However, the particle size was smaller at the flange part than the web part, resulting in the higher strength of the flange part.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.6 no.1
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• pp.50-56
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• 2010

Fatigue has been known as a major degradation mechanism of ASME class 1 components in nuclear power plants. Fatigue damage could be accelerated by combined interaction of several loads and environmental factors. However, the environmental effect is not explicitly addressed in the ASME S-N curve which is based on air at room temperature. Therefore many studies have been performed to understand the environmental effects on fatigue behavior of materials used in nuclear power plants. As a part of efforts, we performed low cycle fatigue tests under various environmental conditions and analyzed the environmental effects on the fatigue life of SA508 Gr. 1a low alloy steel by comparing with higuchi's model. Test results show that the fatigue life depends on water temperature, dissolved oxygen and strain rate. But strain rate over 0.4%/s has little effect on the fatigue life. To find the cause of different fatigue life with ANL's and higuchi's model, another test performed with different heat numbered and heat treated materials of SA508 Gr. 1a. On a metallurgical point of view, the material with bainite microstructure shows much longer fatigue life than that with ferrite/pearlite microstructure. And the characteristics of crack propagation as different microstructure seem to be the main cause of different fatigue life.

• Korean Journal of Materials Research
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• v.29 no.12
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• pp.781-789
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• 2019

The prediction of Jominy hardness curves and the effect of alloying elements on the hardenability of boron steels (19 different steels) are investigated using multiple regression analysis. To evaluate the hardenability of boron steels, Jominy end quenching tests are performed. Regardless of the alloy type, lath martensite structure is observed at the quenching end, and ferrite and pearlite structures are detected in the core. Some bainite microstructure also appears in areas where hardness is sharply reduced. Through multiple regression analysis method, the average multiplying factor (regression coefficient) for each alloying element is derived. As a result, B is found to be 6308.6, C is 71.5, Si is 59.4, Mn is 25.5, Ti is 13.8, and Cr is 24.5. The valid concentration ranges of the main alloying elements are 19 ppm < B < 28 ppm, 0.17 < C < 0.27 wt%, 0.19 < Si < 0.30 wt%, 0.75 < Mn < 1.15 wt%, 0.15 < Cr < 0.82 wt%, and 3 < N < 7 ppm. It is possible to predict changes of hardenability and hardness curves based on the above method. In the validation results of the multiple regression analysis, it is confirmed that the measured hardness values are within the error range of the predicted curves, regardless of alloy type.