• Title/Summary/Keyword: fast curing

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Fast Switching of Vertically Aligned Liquid Crystals by Low-Temperature Curing of the Polymer Structure

  • Park, Byung Wok;Oh, Seung-Won;Kim, Jung-Wook;Yoon, Tae-Hoon
    • Journal of the Optical Society of Korea
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    • v.18 no.4
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    • pp.395-400
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    • 2014
  • We proposed a method for fast turn-off switching of a vertically-aligned liquid crystal cell by low-temperature curing of the polymer structure. We confirmed that the turn-off times of the fabricated cells were reduced significantly as the curing temperature was lowered to $-20^{\circ}C$. We accounted for the effect of low-temperature curing on the turn-off time by using a mathematical model and by observing images obtained via scanning electron microscopy. We also confirmed that low-temperature curing is more effective in reducing the response time when the device is operated at a low temperature.

A Study on the Hardening Characteristics of Ground Injection Grout under Various Curing Conditions (다양한 양생조건에서 지반주입 그라우트의 경화특성에 대한 연구)

  • Heo, Hyungseok;Park, Innjoon
    • Journal of the Korean GEO-environmental Society
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    • v.21 no.11
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    • pp.11-20
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    • 2020
  • For water barrier and reinforcing grout in soft ground, the verification of durability was conducted over the initial and long-term ages under various curing conditions. The grout was made of water glass system, fast-hardening mineral (FHM) system, and acrylic polymer system. There were three types of curing conditions that were tab water curing, artificial seawater curing, and atmospheric curing. And the various tests were performed for each sample by age, uniaxial compressive strength, length change, and weight change. As artificial seawater, MgCl2 and MgSO4 aqueous solutions were prepared and used, respectively. As the test results, the fast-hardening mineral system and acrylic polymer system were cured stably without significant change in durability in tap water and artificial sea water, whereas water glass system showed a very rapid drop in durability under artificial sea water conditions compared to tap water. In atmospheric curing conditions, durability is lowered compared to water curing in all cases, and in particular, the weight loss in the FHM system and water glass system is about 62% and 60%, respectively, resulting in a significant decrease in durability.

Pot Life Assessment and Mechanical Property of Fast Curing Polyurethane Developed with Eco-friendly Pre-polymer

  • Joseph, Jessy;Moon, Junho;Kong, Tae Woong;Kim, Dong Ho;Oh, Jeong Seok
    • Elastomers and Composites
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    • v.55 no.1
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    • pp.13-19
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    • 2020
  • 4,4'-Methylenebis(2-chlorobenzenamine) (MOCA)-free fast curing polyurethanes were prepared. In this study, the processibility of a fast curing polyurethane system was characterized by assessing the pot life. The obtained pot life of the polyurethane was 6-8 s, indicating that this prepolymer-curative system is appropriate for ribbon flow casting. The influence of the NCO index on the viscosity and mechanical properties was evaluated. The viscosity, tensile strength, tear strength, and hardness of the as-prepared polyurethanes showed an increasing trend, with an increase in the NCO index, whereas the elongation at break increased initially and then decreased with an increase in the NCO index. The gel fraction and crosslink density showed a direct correlation with the NCO index, which substantiated the improved mechanical properties at the higher NCO index. The coefficients of friction and abrasion deteriorated with an increase in the NCO index.

Study on the Improvement of Epoxy Property for Aluminum Conductor Composite Core (복합재료 중심인장선용 에폭시 물성 개선 연구)

  • Heo, Seok-Bong;Kang, Junyoung;Youn, Young-Gil;Goh, Munju;Kim, Nam Hoon
    • Composites Research
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    • v.32 no.6
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    • pp.349-354
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    • 2019
  • The Aluminum conductor composite core consists of fast-curing thermosetting epoxy used as reinforcements and carbon fiber and glass fiber used as matrix. In this study, we have investigated fast curing epoxy cured products used for composite core(Aluminum Conductor Composite Core, ACCC). Tetrafunctional epoxy(PA 806) was used as a multifunctional epoxy, along with two kinds of curing agents, MNAn(5-Methyl-5-norbornene-2,3-dicarboxylic anhydride) and HHPA(Hexahydrophthalic Anhydride), to make an epoxy cured product and their properties were evaluated. Optimum conditions are confirmed by varying the content of curing accelerator in the selected epoxy and curing agent.

A Study on Preparation of Fast Cure and Low Density SMC (속경화·저비중 SMC 제조에 관한 연구)

  • Kim, Eun Kyoung;Lee, Youngchul;Hwang, Seok-Ho
    • Applied Chemistry for Engineering
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    • v.7 no.3
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    • pp.511-517
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    • 1996
  • In this research, we studied curing and filler systems for preparation of fast cure SMC and low-density SMC, respectivly. Two curing systems were evaluated for fast cure SMC formulation. One is a mixed initiator system and the other is an activator system. For low-density SMC, glass micro-baloon(GMB) was used as a filler. Various SMC formulations were cured in an appropriate way, and their curing behavior and physical/mechanical properties were characterized. Curing rates were increased with increasing quantity of mixed initiator and activator, but mechanical properties were not affected. As the quantities of GMB increased, density and mechanical properties were decreased.

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Thermoinitiated Cationic Polymerization of Epoxy Resin by Sulfonium Salts for Latent Curing (Sulfonium 염에 의한 Epoxy 수지의 잠재성 경화형 열 개시 양이온 중합반응)

  • Kim, Sun Hee;Shin, Min Jae;Shin, Jae Sup
    • Journal of Adhesion and Interface
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    • v.13 no.2
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    • pp.53-57
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    • 2012
  • A latent curing system was necessary for the anisotropic conducting film (ACF), and a fast reaction system was also necessary to fast production. In this study, the benzylsulfonium salts were synthesized and were used as latent curing initiators for epoxy resin. These benzylsulfonium compounds exhibited a long shelf life with epoxy resin. The curing behaviors of an epoxy resin with these sulfonium salts were investigated using differential scanning calorimetry (DSC), and the curing times were determined at $150^{\circ}C$ using an indentation method.

Properties of Prepacked Concrete Using Super Early Hardening Mortar (초속경성 모르타르를 주입한 프리팩트 콘크리트의 물성 평가)

  • Yang Seung Kyu;Jeong Yon Shik;Um Tai Sun;Lee Jong Ryul
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.651-654
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    • 2005
  • Fast-setting cement is usually used for emergency repair construction of roads, bridges, buildings and so on. In this study, we tried to develop fast-setting ultra early strength mortar for prepacked concrete and evaluated the properties of fresh and hardened concrete with it. The flowability of the mortar was high enough to be easily poured into coarse aggregates. It showed high early strength development which can make it possible to use newly constructed structures within $3\~4$ hours regardless of curing conditions such as curing temperature and curing environment. And it also showed good resistance to drying shrinkage and chemical attack.

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Tuning Exothermic Curing Reaction of Hydrogenated Bisphenol A Epoxy Resins for Stone Conservation (석조문화재 보존.복원에 적용될 에폭시 수지의 경화 시 반응열 제어 및 안정성 향상 연구)

  • Choi, Yong-Seok;Park, You-Jin;Kang, Yong-Soo;Won, Jong-Ok;Kim, Jeong-Jin;Kim, Sa-Dug
    • Journal of Conservation Science
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    • v.28 no.2
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    • pp.131-139
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    • 2012
  • The exothermic cure kinetics of epoxy resin was controlled by hardener containing fast and slow curing agents. The epoxy risen comprises hydrogenated bisphenol A-based epoxide (HBA), fast curing agent (FH) and slow curing agent poly(propyleneglycol)bis(2-aminopropylether) (SH). Talc was used as an inorganic additive. In the process of curing, cure kinetics along with temperature was monitored by differential scanning calorimeter (DSC) and thermocouple to show that the temperature increase was well controlled by adjusting the hardener mixture. Additionally, bending and tensile strengths of the epoxy/talc composites were also measured to be lower and higher with the amount of the talc inorganic additive, respectively. It is thus concluded that the increase in the temperature during exothermic curing reaction and mechanical properties of epoxy resins are tuned by optimizing hardener mixture for successful stone conservation.

Grouting diffusion mechanism in an oblique crack in rock masses considering temporal and spatial variation of viscosity of fast-curing grouts

  • Huang, Shuling;Pei, Qitao;Ding, Xiuli;Zhang, Yuting;Liu, Dengxue;He, Jun;Bian, Kang
    • Geomechanics and Engineering
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    • v.23 no.2
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    • pp.151-163
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    • 2020
  • Grouting method is an effective way of reinforcing cracked rock masses and plugging water gushing. Current grouting diffusion models are generally developed for horizontal cracks, which is contradictory to the fact that the crack generally occurs in rock masses with irregular spatial distribution characteristics in real underground environments. To solve this problem, this study selected a cement-sodium silicate slurry (C-S slurry) generally used in engineering as a fast-curing grouting material and regarded the C-S slurry as a Bingham fluid with time-varying viscosity for analysis. Based on the theory of fluid mechanics, and by simultaneously considering the deadweight of slurry and characteristics of non-uniform spatial distribution of viscosity of fast-curing grouts, a theoretical model of slurry diffusion in an oblique crack in rock masses at constant grouting rate was established. Moreover, the viscosity and pressure distribution equations in the slurry diffusion zone were deduced, thus quantifying the relationship between grouting pressure, grouting time, and slurry diffusion distance. On this basis, by using a 3-d finite element program in multi-field coupled software Comsol, the numerical simulation results were compared with theoretical calculation values, further verifying the effectiveness of the theoretical model. In addition, through the analysis of two engineering case studies, the theoretical calculations and measured slurry diffusion radius were compared, to evaluate the application effects of the model in engineering practice. Finally, by using the established theoretical model, the influence of cracking in rock masses on the diffusion characteristics of slurry was analysed. The results demonstrate that the inclination angle of the crack in rock masses and azimuth angle of slurry diffusion affect slurry diffusion characteristics. More attention should be paid to the actual grouting process. The results can provide references for determining grouting parameters of fast-curing grouts in engineering practice.

Properties of Light Weight Foamed Concrete According to Curing Condition (양생조건에 따른 경량기포콘크리트의 특성)

  • Shin, Sang-Chul;Choi, Ji-Ho;Hong, Sung-Rog;Kim, Ji-Ho;Jeong, Ji-Yong;Kim, Jin-Man
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.237-239
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    • 2011
  • This study was performed to investigate the influence of curing temperature on the properties of light weight foamed concrete, manufactured on-site construction according to the various experimental factor such as temperature of material, curing temperature in air(5, 10, 20℃), curing time in air(5, 10, 15hour), and target density of hardened state(0.8, 1.2t/㎥). As a result, the influence of the curing temperature on various properties of foamed concrete is greater than curing time. When increasing temperature and time in air curing, progress of hydration is fast and compressive strength is increasing more and more. However, when considering the productivity, minimum curing time is required 15hours at 5℃, 10hours at 10℃, and 5hours at 20℃. If this condition is not required, there is some crack due to volume expansion on the surface of light weight foamed concrete.

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