• Title/Summary/Keyword: f-structure

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Variation of Band Gap Energy upon Structural Distortion for Nb-containing Oxyfluorides (Nb를 포함하는 불소산화물에서 구조적 뒤틀림에 따른 에너지 띠 간격의 변화)

  • Kim, Hyun-Jun;Kim, Seung-Joo
    • Journal of the Korean Chemical Society
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    • v.51 no.3
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    • pp.265-269
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    • 2007
  • A comparative study on crystal structures and UV-visible diffuse reflectance spectra for Nb-containing oxyfluorides was performed to probe the relationship between energy band gap and local structure. The oxyfluorides, RbSrNb2O6F, RbCaNb2O6F and RbNb2O5F are commonly composed of the corner-sharing NbO5F octahedra as structural building units. The average Nb-O(F)-Nb bond angles, which can be a measure of the structural distortion, are 158.6° for RbSrNb2O6F, 149.6° for RbCaNb2O6F and 139.5° for RbNb2O5F. As the bond angle decreases, the band gap increases: 3.48eV for RbSrNb2O6F, 3.75eV for RbCaNb2O6F and 4.03 eV for RbNb2O5F. This experimental result implies that the band gap can be controlled with a range of 0.6 eV through a variation of local structure for the Nb-containing oxyfluorides.

Dynamic Earth Pressure on Embedded Structure

  • Sadiq, Shamsher;Park, Duhee
    • Journal of the Korean GEO-environmental Society
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    • v.20 no.9
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    • pp.13-19
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    • 2019
  • Dynamic earth pressure is considered an important parameter in the design of embedded structures. In current engineering design simplified methods developed either for yielding or non-yielding structures are utilized to predict resultant dynamic pressure. The applicability of these equations to embedded structures have not yet been reported. In this study we perform a suite of equivalent linear time history analysis for a range of embedded structure configurations. Numerically calculated dynamic pressure is shown to depend on the flexibility ratio (F), aspect ratio (L/H) of the embedded structure, and ground motion. Increase in L/H and intensity increases the magnitude of dynamic pressure. An increase in F decreases the dynamic pressure. Overall, the trends highlight the need for development of new method that accounts for F and L/H to calculate the dynamic pressure for the performance-based design of embedded structures.

GENERIC LIGHTLIKE SUBMANIFOLDS OF AN INDEFINITE TRANS-SASAKIAN MANIFOLD WITH AN (ℓ, m)-TYPE METRIC CONNECTION

  • Jin, Dae Ho
    • Communications of the Korean Mathematical Society
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    • v.34 no.2
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    • pp.615-632
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    • 2019
  • We study generic lightlike submanifolds M of an indefinite trans-Sasakian manifold ${\bar{M}}$ or an indefinite generalized Sasakian space form ${\bar{M}}(f_1,f_2,f_3)$ endowed with an $({\ell},m)$-type metric connection subject such that the structure vector field ${\zeta}$ of ${\bar{M}}$ is tangent to M.

A Study On Structure Change of Binding Actin and Moysin On The Contracting Muscle Membrane (수축중인 근육막에서 actin과 myosin 결합의 구조변화에 관한 연구)

  • Kim, Duck-Sool;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.3
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    • pp.380-387
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    • 2008
  • The effects of the applied stretch and MgADP binding on the structure of the actin and myosin cross-bridges in rabbit fibers in the rigor state have been investigatedwith improved resolution by x-ray diffraction using synchrotron radiation. To clarify the structure of the ATP hydrolysis intermediates formed by actin and myosin cross-bridges,the effects of various phosphate analogs in the of MgADP on the structure of the thin and thick filaments in glycerinated rabbit muscle fibers in the rigor state investigated by x-ray diffraction with a short exposure time using synchrotron radiation. These results strongly suggest that when MgADP and phosphate analogs such as metallofluorides(BeF3 and AlF4)and vanadate(VO4(Vi)) were added the rigor fibers in the presence of the ATP-depletion backup system, the intensities of the actin-based layer lines were markedly weakened. We found that the intensity of the 14.5 nm-based meridional reflections increase by 20-50% when phosphate analogs such as metallofluorides(BeF3 and AlF4) and vanadate(VO4(Vi)) was added to the rigor muscle.

Molecular and Crystal Structure of' Metalaxyl, $C_{15}H_{21}NO_4$ (Metalaxyl, $C_{15}H_{21}NO_4$의 분자 및 결정구조)

  • Keun Il Park;Young Kie Kim;Sung Il Cho;Man Hyung Yoo
    • Korean Journal of Crystallography
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    • v.13 no.3_4
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    • pp.148-151
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    • 2002
  • The molecular and crystal structure of metalaxyl C/sub15/H/sub21/NO₄, was determined by single crystal x-ray diffraction study. Crystallographic data for, title compound P2₁/c, a=7.849(4) Å, b=13.081(5) Å, c=15.100(3) Å, β=101.8(2)°, V= 1517.6(3) ų, Z=4. The molecular. Structure model was solved by direct method and refined by full-matrix least- squares. The final reliable factor, R, is 0.067 for 1694 independent reflections (F/sub o//sup 2/>4σ(F/sub o//sup 2/)). The molecular structure of title compound shows an intramolecular hydrogen bond: Cl2-Hl2A…O1.

ON CONTACT SLANT SUB MANIFOLD OF L × f F

  • Sohn, Won-Ho
    • Communications of the Korean Mathematical Society
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    • v.19 no.1
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    • pp.129-134
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    • 2004
  • It is well known that the warped product $L\;{\times}\;{_f}\;F$ of a line L and a Kaehler manifold F is an almost contact Riemannian manifold which is characterized by some tensor equations appeared in (1.7) and (1.8). In this paper we determine contact slant submanifolds tangent to the structure vector field of $L\;{\times}\;{_f}\;F$.

ON THE RICCI CURVATURE OF SUBMANIFOLDS IN THE WARPED PRODUCT L × f F

  • Kim, Young-Mi;Pak, Jin-Suk
    • Journal of the Korean Mathematical Society
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    • v.39 no.5
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    • pp.693-708
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    • 2002
  • The warped product L$\times$$_{f}$ F of a line L and a Kaehler manifold F is a typical example of Kenmotsu manifold. In this paper we determine submanifolds of L$\times$$_{f}$ F which are tangent to the structure vector field and satisfy certain conditions concerning with Ricci curvature and mean curvature.ure.

A study on branch type Inverted-F structure antenna with dual-band operation (듀얼밴드를 갖는 브랜치타입 인버티드 F구조 안테나에 관한 연구)

  • Park, Seong-Il;Ji, Yu-Kang
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.12 no.1
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    • pp.39-45
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    • 2008
  • In this parer a branch type inverted-F structure antenna with dual-band is proposed. The proposed antenna has a size of about $70mm{\times}35mm{\times}0.8mm$ with a total mobile phone PCB for support and patch of about $12mm{\times}8mm{\times}0.8mm$. This antenna is designed to operate of frequency 2.45GHz and 5.8GHz, Bandwidth at each other frequency is satisfied $83MHz{\sim}100MHz$ in frequencies. Also, The designed and fabricated dual-band antenna for 2.45GHz, 5.8GHz have a gain between 2.0dBi and -1.0dBi at all bands.

Analysis of Plastic Hinge of Pile-Bent Structure with Varying Pile Diameters (단일형 현장타설말뚝의 소성힌지를 고려한 최적설계법 제안)

  • Ahn, Sang-Yong;Jeong, Sang-Seom;Kim, Jae-Young
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.09a
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    • pp.349-356
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    • 2010
  • In this study, a new design method of pile bent structure considering plastic hinge was proposed on the basis of the beam-column model. Based on the analysis results, it is found that the positioning of plastic hinge on the pile bent structure was influenced by nonlinear behavior of material and p-$\Delta$ effect. Moreover, concrete cracking began to occur at the joint section between the pile and column in case of pile bent structure with different cross-sections. The plastic hinge can be developed on the pile bent structure when large displacement was occurred, and pile bent structures can be maintained well only if it is developed on the column part. Therefore, in this study, the optimized cross-section ratio between column and pile was analyzed to induce the plastic hinge at the joint section between the pile and column. Based on this, the optimized diameter ratio of pile and column can be obtained below the inflection point of the bi-linear curve depending on the relations between column-pile diameter ratio($D_c/D_p$) and normalized lateral cracking load ratio($F/F_{Dc=Dp}$). And through this study, it is founded that in-depth limit($L_{As}$=0.4%) normalized by the pile length($L_P$) are proportionally decreased as the pile length($L_P/D_P$) increases up to $L_P/D_P$=17.5, and beyond that in-depth limit converges to a constant value. Finally, it is found that the proposed limit depth by taking into account the minimum concrete-steel ratio would be more economical design of the pile bent structure.

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Fabrication and Characterization of ${LiMn_2}{O_4}$ Cathode for Lithium Rechargeable Battery by R.F.Magnetron Sputtering (R.F. Magnetron Sputtering을 이용한 리튬이차전지 정극용 ${LiMn_2}{O_4}$의 제조 및 특성)

  • 우태욱;손영국
    • Journal of the Korean Ceramic Society
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    • v.37 no.6
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    • pp.552-558
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    • 2000
  • LiMn2O4 thin fiolm cathodes for Li-ion secondary battery were fabricated by r.f. magnetron sputtering technique. As-deposited films were amorphous. A spinel structure could not be obtained LiMn2O4 films by in-situ thermal annealing. After post thermal annealing over $700^{\circ}C$ in oxygen atmosphere, LiMn2O4 films prepared above 100 W r.f. power could be crystallized into a spinel structure. The electrochemical property of the LiMn2O4 film cathodes was tested in a Li/1 M LiClO4 in PC/LiMn2O4 cell. From cyclic voltammetry at scan rate of 2mV/sec of 2.5~4.5V, LiMn2O4 electrode prepared by post annealing at 75$0^{\circ}C$ showed good initial capacity. LiMn2O4 electrode prepared by post annealing at 80$0^{\circ}C$ showed the best crycling performance.

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