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Development of Click Chemistry in Polymerization and Applications of Click Polymer

  • Karim, Md. Anwarul
    • 고무기술
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    • 제13권1호
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    • pp.1-9
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    • 2012
  • Click chemistry had enjoyed a wealthy decade after it was introduced by K.B.Sharpless and his co-worker on 2001. Since there is no optimized method for synthesis of click polymer, therefore, this paper introduced three click reaction methods such as catalyst, non-catalyst and azide-end capping for fluorene-based functional click polymers. The obtained polymers have reasonable molecular weight with narrow PDI. The polymers are thermally stable and almost emitted blue light emission. The synthesized fluorene-based functional click polymers were characterized to compare the effect of click reaction methods on polymer electro-optical properties as well as device performance on quasi-solid-state dye sensitized solar cells (DSSCs) applications. The DSSCs with configuration of $SnO_2:F/TiO_2/N719$ dye/quasi-solid-state electrolyte/Pt devices were fabricated using these click polymers as a solid-state electrolyte components. Among the devices, the catalyzed click polymer composed device exhibited a high power conversion efficiency of 4.62% under AM 1.5G illumination ($100mW/cm^2$).These click polymers are promising materials in device application and $Cu^I$-catalyst 1, 3-dipolar cycloaddition click reaction is an efficient synthetic methodology.

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인체에서 분리된 Lactobacillus acidophilus가 생산하는 박테리오신의 선별과 정제 (Screening and Partial Purification of Bacteriocins by Strains of Lactobacillus acidophilus Isolated from Human Origin)

  • 김세헌;김영교
    • Journal of Dairy Science and Biotechnology
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    • 제15권1호
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    • pp.21-26
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    • 1997
  • Lactobacillus acidophilus 223, 606, and NCFM-F among 21 isolated from fecal contents of humans demonstrated inhibitory activity attributed to bacteriocin(s). The bacteriocin(s) were heat stable and nondialyzable proteinous compounds and exhibited narrow inhibitory spectra of activity. Neither hydrogen peroxide nor pH were responsible for inhibitory action. All of the producer strains were resistant to their own bacteriocin(s). The bacteriocin(s) were purified by ammonium sulfate precipitation, gel chromatography and ion exchange chromatography for further characterization. The bacteriocin(s) of human origin exhibited similar characteristics.

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생체신호계측을 위한 체내 이식형 무선송수신 시스템 개발 (Development of a transcutaneous system for implantable bio-signal measurement)

  • 이승하
    • 센서학회지
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    • 제17권1호
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    • pp.23-28
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    • 2008
  • In order to measure bio-signals, it is desirable to build a fully implantable system which connects directly to neural pathways or body tissue. A design scheme for fully implementable measurement system is proposed in this paper. Consisting of an implanted module and an external system, the proposed scheme delivers power and data between the two modules. The external module sends power via inductive link using a simple H-bridge type oscillator. Also, the implanted module sends measured data to the external system utilizing R/F communication technique at a frequency of ISM band. A stable communication and operation is achieved as the two types of channels are separated. Implemented in a compact size enough to be implanted in human body, the system exhibits good performance in experimental studies.

포항지역 지열수의 수리지구화학적 특성

  • 고동찬;염병우;하규철;송윤호
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
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    • pp.453-454
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    • 2004
  • Hydrogeochemical and isotopic characteristics were investigated for groundwater of Tertiary basin in southeastern part of Korea where deep drilling is in progress for geothermal investigation. According to geology, aquifer was distinguished as alluvial, tertiary sedimentary bedrock (bedrock groundwater), and fractured volcanic rock (deep groundwater). Groundwater of each aquifer is distinctively separated in Eh-pH conditions and concentrations of Cl, F, B and HCO$_3$. Deep groundwater has very low level 3H and 14C whereas alluvial groundwater has those of recent precipitation level. However one of deep groundwater show mixed characteristics in terms of hydrochemistry which indicates effect of pumping. Deep groundwater have temperature of 38 to 43$^{\circ}C$ whereas bedrock and alluvial groundwater have temperature less than 2$0^{\circ}C$. Fractured basement rock aquifer has different hydrogeologicalsetting from bedrock and alluvial aquifer considering hydrogeochemical and isotopic characteristics, and temperature.

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보울 피이더에서 신경 회로망을 이용한 부품 자세 인식에 관한 연구 (A neural network method for recognition of part orientation in a bowl feeder)

  • 임태균;김종형;조형석;김성권
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1990년도 한국자동제어학술회의논문집(국내학술편); KOEX, Seoul; 26-27 Oct. 1990
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    • pp.275-280
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    • 1990
  • A neural network method is applied for recognizing the orientation o f individual parts being fed from a bowl feeder. The system is designed in such a way that a part can be discriminated and sorting according to every possible stable orientation without implementing any a mechanical tooling. The operation of the bowl feeder is based on a 2D image obtained from an array of fiber optic sensor located on the feeder track. The acquired binary image of a moving and vibrating part is used as input to a neural network which, in turn, determines t he orientation of the part. The main task of the neural network, here is to synthesize the appropriate internal discriminant functions for the part orientation using the part features. A series of the experiments reveals several promising points on performance. Since the operation of the feeder is highly programmable, it is well suited for feeding and sorting small parts prior to small batch assembly work.

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3차원 자계분포해석을 이용한 고온초전도동기모터에서의 Ag/Bi-2223 Tape 및 Flux Damper의 특성해석 (The Characteristic Analysis of the Ag/Bi-2223 Tape and the Flux damper in GTS Synchronous Motor through 3-Dimensional Magnetic Field Analysis Using F.E.M)

  • 송명곤;윤용수;이상진;고태국
    • 한국초전도저온공학회:학술대회논문집
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    • 한국초전도저온공학회 2000년도 KIASC Conference 2000 / 2000년도 학술대회 논문집
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    • pp.170-172
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    • 2000
  • This paper deals with the characteristic analysis of the flux damper with respect to the load, and the stability of Ag/Bi-2223 tapes in a high-Tc superconducting (HTS) synchronous motor. To find out the magnetic field distribution in a detailed model of the actual motor, the experimentally measured currents of the armature and the field windings are used as input parameters. The simulation results show that the flux damper shields the time varying field up to 10%, reduces armature reactance during the motor operation and during load changes, improving the stable motor operation. And it was observed that the flux damper generates loss by means of leakage flux, but this is not significant and it doesn't degrade the performance of the TS synchronous motor.

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Characterization of Graphene Oxide Suspension for Fluorescence Quenching in DNA-Diagnostics

  • Kapitonov, A.N.;Alexandrov, G.N.;Vasileva, F.D.;Smagulova, S.A.;Timofeev, V.B.;Maksimova, N.R.;Kuznetsov, A.A.
    • 한국재료학회지
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    • 제26권1호
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    • pp.1-7
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    • 2016
  • The graphene oxides (GOs) were tested as a fluorescent quencher in the field of DNA-diagnostics. The various suspensions of GO nanoplates were prepared by changing the synthesis conditions. The suspensions were stable for at least 6 weeks by differing degrees of functionalization of various oxygen-containing groups of atoms. Depending on the properties of GO nanoplates, their fluorescent quenching abilities, which were determined by the amount of the tagged immobilized oligonucleotide, were also changed. GO suspension synthesized at $75^{\circ}C$ of reaction mixture showed the fluorescent quenching of 16.39 nmol/mg, which would be a potential substitution of molecular fluorescent quencher in test-systems for DNA-diagnostics.

전류오차 신호를 이용한 간단한 MPPT제어기 설계에 관한 연구 (A Study on Design of the simple MPPT controller using current error signal)

  • 강주성;고강훈;최광주;홍두성;이현우
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2006년도 전력전자학술대회 논문집
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    • pp.222-224
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    • 2006
  • To improve the drawback of LCMPPT(Limit Cycle Maximum Power Point Tracking) controller of the existing two power conversion stages, an advanced MPPT scheme of single power conversion stage is proposed in this paper. This topology is faster on the control speed by means of current control method and the system configuration is simpler. The Authors produce a battery charger by using a cost effective one-chip processor (PIC16F877A) and evaluate another application on the basis of simulation. As a result, the proposed new LCMPPT algorithm is confirmed to be stable and useful.

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고중량 지지 가능한 이족보행로봇의 개발 (Development of Biped Walking Robot Capable of Supporting Heavy Weight)

  • 최형식;이상준;오주환;강영환
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2006년도 춘계학술대회 논문집
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    • pp.63-64
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    • 2006
  • In this paper, design modification was performed to improve the structure of ex-developed 12 D.O.F Biped walking robot, KUBIR-1 similar with human beings. The motion of KUBIR-1 was slow and had a limited walking space. Hence I designed an improved BWR named KUBIR-2 with 12 degree of freedom. KUBIR-2 was designed to solve the following problems of KUBIR-1. First, KUBIR-2 was more simply designed in the four-bar-link mechanism, and its weight was reduced. Second, it had the built-in controller and motor driver. Third, walking velocity of KUBIR-2 was increased by improvement of speed and motion joint angle range. In addition to these, we modified the structure of the foot for more stable walking.

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틸트 구동형 엑추에이터의 개발 (Development of 3-Axis Actuator for Active Tilt Compensation)

  • 이강녕;박세준;이동주;박노철;조원익;박영필
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2003년도 추계학술대회논문집
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    • pp.226-233
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    • 2003
  • There are many researches going on to develop the information storage devices using Blue-ray disc and DVD as a demand for high-density information storage devices is highly increasing. This high-density information storage device requires a short-wave laser and objective lens of high numerical aperture set in fer its operation. And, that brings out rapid decrease of tilt tolerance. Therefore, it is necessary that an actuator should control tilt motions to get a stable signal. In this paper, a new mathematical form of 3-D.O.F coupled model is formulated and magnetic circuit in constraints is most effectively designed with the use of the moving coil type actuator in higher sensitivity. Further, this paper presents a tilt coil whose rotational center point is put on that of the lens through the variation of tilt coil and proposes a 3-axis actuator with high sensitivity improved in its dynamic property through its structure analysis.

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