• Title/Summary/Keyword: extruder

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The Effect of Compatibilizer on the Rheological Properties of Polypropylene/Glass-fiber Composites (폴리프로필렌/유리섬유 복합재료의 유변물성에 미치는 상용화제의 영향)

  • Lee Seung-Hwan;Youn Jae-Ryoun
    • Composites Research
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    • v.19 no.3
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    • pp.15-22
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    • 2006
  • In this study, we prepared glass fiber reinforced polypropylene composites using Brabender twin-screw extruder. Compatibilizer, polypropylene-based maleic anhydride (PP-g-MAH), was used to increase the molecular interaction between polypropylene matrix and glass fiber and to enhance melt processability. We also measured the shear and uniaxial elongational behaviors of glass-fiber reinforced composites in the absence or presence of compatibilizer. The effects of compatibilizer and fiber loading on the viscoelastic behaviors were examined. It was fuund that the PP-g-MAH compatibilizer improved the fluidity and increased the molecular bonding of composite melts in shear flow. Transient elongational viscosity was increased with fiber loadings in uniaxial elongational flow However, it was decreased with increasing elongational rates because of microscale shear flow between fibers.

Production and investigation of 3D printer ABS filaments filled with some rare-earth elements for gamma-ray shielding

  • Batuhan Gultekin;Fatih Bulut;Hatice Yildiz;Hakan Us;Hasan Ogul
    • Nuclear Engineering and Technology
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    • v.55 no.12
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    • pp.4664-4670
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    • 2023
  • Radiation is the main safety issue for almost all nuclear applications, which must be controlled to protect living organisms and the surrounding materials. In this context, radiation shielding materials have been investigated and used in nuclear technologies. The choice of materials depends on the radiation usage area, type, and energy. Polymer materials are preferred in radiation shielding applications due to their superior characteristics such as chemical inertness, resistivity, low weight, flexibility, strength, and low cost. In the presented work, ABS polymer material, which is possibly the most commonly used material in 3D printers, is mixed with Gd2O3 and Er2O3 nanoparticles. ABS filaments containing these rare-earth elements are then produced using a filament extruder. These produced filaments are used in a 3D printer to create shielding samples. Following the production of shielding samples, SEM, EDS, and gamma-ray shielding analyses (including experiments, WinXCOM, GEANT4, and FLUKA) are performed. The results show that 3D printing technology offers significant enhancements in creating homogeneous and well-structured materials that can be effectively used in gamma-ray shielding applications.

Melt viscosity and Morphology of Reactive Blends (Coupling Agent를 이용한 Polyamide 6와 Polyester Elastomer의 반응동반 블랜드)

  • Byung Kyu Kim;Sang Hyun Baek;Lee Keun Yoon
    • The Korean Journal of Rheology
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    • v.11 no.1
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    • pp.50-56
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    • 1999
  • Melt blends of polyamide 6 (PA 6) with polyester elastomer (PEL) were prepared in a corotating twin screw extruder using two types of coupling agent(CA), viz. diglycidyl ether of bisphenol A (DGEBA) and 1,4-phenylene bis(2-oxazoline) (PBO). Notched impact strength of PA 6 as well as PA 6/PEL blends increased with the addition of coupling agent, especially with DGEBA and the maximum impact toughening of the blend was obtained with 0.6%(by mol) DGEBA, where a minimum domain size was observed from SEM. Melt viscosities of the untreated blends were higher than those of base resins at low frequencies. Viscosities of base resins as well as blends increased with the addition of CA, and the effect was much more pronounced with DGEBA, especially for PA 6 and PA 6-rich blends.

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Preparation and Properties of Cellulose Diacetate/$CaCO_3$ Composite (Cellulose Diacetate/$CaCO_3$ 복합체의 제조 및 물성)

  • Lim, Hwan-Kyu;Kye, Hyoung-San;Won, Sung-Ho;Nam, Jae-Do;Lee, Young-Kwan
    • Polymer(Korea)
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    • v.32 no.2
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    • pp.178-182
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    • 2008
  • Cellulose diacetate (CDA) and calcium carbonate ($CaCO_3$) biodegradable composites were prepared by melt mixing in a twin screw extruder and their physical properties were examined. In the melt processing, triacetine and epoxidized soybean oil were added to the composites as a plasticizer and lubricant, respectively. The optimal conditions for the preparation of the biodegradable composites were determined. Acetic acids ($CH_3COOH$) were made by pyrolysis acetyl group ($-OC (O)CH_3$) of CDA and TA in melt processing. Increasing the amount of $CaCO_3$ in the composites resulted in further enhancement of the $CH_3COOH$ absorption effects. The tensile strength and elongation were decreased, and Young's modulus and $T_g$ value increased with increasing amount of $CaCO_3$.

A Study on the Anti-impulsive Strength of the Helmets for a Gas Industry (가스산업용 안전모의 내충격 안전성에 관한 연구)

  • Kim, Chung Kyun;Kim, Tae Whan
    • Journal of the Korean Institute of Gas
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    • v.17 no.6
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    • pp.52-57
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    • 2013
  • In this study, the strain energy density, stress and deformation behaviors have been analyzed as functions of a thickness and a force area of protective helmets with and without an extruder on the top of the shell structure using the finite element method. The strain energy density in which is related to the absorption capacity of an impact energy transfer is one of a key element of the helmet safety. The FEM analyzed results show that when the impulsive force of 4,540N is applied on the top surface of the helmets, the maximum stress is linearly reduced for an increased area of impact forces. But, the maximum strain energy density has been reduced for the increased force area. The reduced strain energy density may increase the impulsive forces transferred to the head and neck of helmet wearers, which may decrease the impact energy absorption safety of the helmets. In thus, it is safer design of the helmet in which has an extruded structure on the summit surface, but the modified helmet may decrease the impact energy absorption capacity.

The Effect of Surface-Modification of Wood Powders by Plasma Treatment of Propylene on the Mechanical Properties of Wood Powder/PP Composites (프로필렌의 플라즈마 처리로 개질된 목분이 복합재료의 기계적 특성에 미치는 영향)

  • Cho, Dong Lyun;Ha, Jong-Rok;Kim, Byung Sun;Yi, Jin Woo
    • Composites Research
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    • v.30 no.2
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    • pp.145-148
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    • 2017
  • Wood powders were surface-modified by plasma-treating propylene to make them compatible with PP matrix in WPC(wood powder composite). The plasma treatment of propylene resulted in the deposition of an ultrathin hydrophobic film which had the chemical structure similar to that of polypropylene. Wood powder and polypropylene were mixed to pellets by twin screw extruder and then 50 wt% wood powder/PP composites were produced by an injection machine. Tensile strength and flexural strength were improved by 7.59% and 12.43% at the maximum respectively. SEM (Scanning Electron Microscopy) observation on the fracture surface revealed that the treatment improved the interfacial bonding and the mechanical properties of the composites.

Thermal and Mechanical Properties of Flame Retardant ABS Nanocomposites Containing Organo-Modified Layered Double Hydoxide (유기변성 LDH를 사용한 난연 ABS 나노복합재료의 열적 및 기계적 물성)

  • Kim, Seog-Jun
    • Elastomers and Composites
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    • v.43 no.4
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    • pp.241-252
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    • 2008
  • ZnAl-LDH(layered double hydroxide) modified with oleic acid(SO-ZnAl LDH) was synthesized and added to the flame retardant ABS compounds containing brominated epoxy resin(BER) and antimony trioxide(${Sb_2}{O_3}$). Flame retardant ABS compounds were manufactured by using a twin-screw co-rotating extruder and subsequently injection molded into several specimen for flame retardancy and mechanical properties. The XRD patterns of ABS nanocomposites showed no peaks. The thermal stability of ABS nanocomposites was enhanced by the addition of SO-ZnAl LDH as shown in TGA results. However, these nanocomposites showed no rating in the UL 94 vertical test at 1.6 mm thickness. Only ABS nanocomposites with additional BER more than 1.5 wt% showed UL 94 V0 rating. Notched Izod impact strength, tensile modulus, and elongation at break of flame retardant ABS nanocomposites increased with the proportion of So-ZnAl LDH whereas their melt index decreased.

Recycling of PC/ABS Blend Used in Instrument Panel of Automotive (자동차 Instrument Panel에 사용된 PC/ABS계의 재활용)

  • Lee, Chang Hyung;Jung, In Kwon;Lee, Yong Moo;Oak, Sung Hyun;Choi, Hyeong Ki
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.118-123
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    • 1999
  • The recycle of the polycarbonate(PC)/acrylonitrile-butadiene-styrene(ABS) separated from the instrument panel (In-Panel) of the automotive was investigated. The small amount of polyurethane(PU) foam contained in the separated PC/ABS decreased the mechanical properties of the recycled PC/ABS. However, it is found that the PU foam formed the dispered phase of small particles at high temperature ($260^{\circ}C$) under high shear of the twin extruder, whereas it formed the big particles at low extrusion temperature ($220^{\circ}C$). The mechanical properties of the recycled PC/ABS extruded at high temperature was better than those at low temperature, which enabled the recycled PC/ABS seperated from In-Panel to be applied to the radiator grille without the addition of the compatibilizers or virgin PC/ABS. This was ascribed to the smaller particle sizes of the PU foam formed at high extrusion temperature under high shear.

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Analysis of the Thermal/Mechanical Energy in Food Extrusion Process (식품 압출성형공정의 열 및 기계에너지 분석)

  • Chung, Moon-Young;Lee, Seung-Ju
    • Korean Journal of Food Science and Technology
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    • v.29 no.1
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    • pp.65-71
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    • 1997
  • The energy supplied by motor of extruder, being known mostly to be dissipated as heat, was classified into two kinds of energy: a thermal energy by heat dissipation and a purely mechanical energy. The thermal energy was defined as a energy in terms of temperature rise and the mechanical energy as the motor energy minus the heat dissipated energy. A method to derive the thermal energy and the relative mechanical energy (the mechanical energy calculated regarding the mechanical energy at the lowest screw speed as zero) under the condition of constant barrel temperature was developed by which an extrusion case was analyzed. When extruding com grits with moisture $(27{\sim}37%)$ at low barrel temperature $({\leq}80^{\circ}C)$, the thermal energy slightly increased with increase in the moisture content, whereas the relative mechanical energy increased to a great extent. When increasing the screw speed, the thermal energy was nearly kept constant, whereas the relative mechanical energy largely varied. It is concluded that as the moisture content increases, the role of the mechanical energy becomes more effective than the heat energy dissipated from the motor energy.

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Preparation and Characterization of Low Density Polyethylene (LDPE) and Flower-like Zinc Oxide (FZnO) Composite Films (저밀도폴리에틸렌(LDPE)/꽃 모양 산화아연(FZnO) 복합필름의 제조 및 물성 분석)

  • Kim, Insoo;Lee, Hojun;Kim, Dowan;Seo, Jongchul
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.22 no.3
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    • pp.85-93
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    • 2016
  • Flower-like zinc oxide (FZnO) was successfully synthesized via a sonochemical process. The chemical structure, morphology, and antimicrobial properties of as- prepared FZnO were investigated. Additionally, pure LDPE and five different LDPE/FZnO composite films were prepared with different FZnO content by using a twin screw extruder. According to the FTIR and SEM analyses, there exists weak interfacial interaction between LDPE and FZnO. Compared with pure LDPE, the LDPE/FZnO composite films showed UV barrier and enhanced antimicrobial activity against Escherichia coli (E. coli) as a Gram-negative micro-organism and Staphylococcus aureus (S. aureus) as a Gram-positive micro-organism. To enhance the interfacial interaction and good dispersion of FZnO into the LDPE matrix, and resultantly to such as UV barrier and antimicrobial properties of LDPE/FZnO composite films as the packaging materials, further efforts are required.