• Title/Summary/Keyword: exposed specimen

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Evaluation of the Effect of High Temperature on the Interface Characteristics between Solid Oxide Fuel Cell and Ag Paste (고온열처리가 고체산화물연료전지의 전극과 Ag 페이스트의 계면에 미치는 특성 평가)

  • Jeon, Sang Koo;Nahm, Seung Hoon;Kwon, Oh Heon
    • Journal of the Korean Society of Safety
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    • v.30 no.1
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    • pp.21-27
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    • 2015
  • In this study, interfacial characteristics between SOFC and Ag paste as current collector was estimated in the high temperature environment. The Ag paste was used to connect the unit cell of SOFC strongly with interconnector and provide the electrical conductivity between them. To confirm electrical conductivity, Ag paste was treated in the furnace at $800^{\circ}C$ for 48 hours. The sheet resistance of Ag paste was measured to compare the resistance values before and after the heat treatment. Also, the four-point bending test was performed to measure the interfacial adhesion. The unit cell of SOFC and $SiO_2$ wafer were diced and then attached by Ag paste. The $SiO_2$ wafer had the center notch to initiate a crack from the tip of the notch. The modified stereomicroscope combined with the CCD camera and system for measuring the length was used to observe the fracture behavior. To compare the characteristics before heat treatment and after heat treatment, the specimen was exposed in the furnace at $800^{\circ}C$ for 48 hours and then the interfacial adhesion was evaluated. Finally, the interfacial adhesion energy quantitatively increases $1.78{\pm}0.07J/m^2$ to $4.9{\pm}0.87J/m^2$ between the cathode and Ag paste and also increase $2.9{\pm}0.47J/m^2$ to $5.12{\pm}1.01J/m^2$ between the anode and Ag paste through the high temperature. Therefore, it is expected that Ag paste as current collector was appropriate for improving the structural stability in the stacked SOFC system if the electrical conductivity was more increased.

Acute Testis Toxicity of Bisphenol A Diglycidyl Ether in Sprague-Dawley Rats

  • Yang, Yun-Jung;Lee, Shin-Young;Kim, Kyung-Yong;Hong, Yeon-Pyo
    • Journal of Preventive Medicine and Public Health
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    • v.43 no.2
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    • pp.131-137
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    • 2010
  • Objectives: Bisphenol A diglycidyl ether (BADGE) is a liquid compound obtained by condensation of two molecules of epichlorohydrin with one molecule of bisphenol A. General and reproductive toxicity with BADGE has been reported higher than 1000 mg/kg/day. This study was performed to show the effects of acute exposure to BADGE below 1000 mg/kg/day on the testis in adult male rats. Methods: BADGE was administered by gastric lavage in a single dose of 500, 750, 1000, and 2000 mg/kg/day in 8-week old male SPF Sprague-Dawley rats. The right testis was processed for light microscopic analysis. The left testis was homogenized and spermatids were counted to determine the daily sperm production and daily abnormal sperm production. The sperm count, sperm motility, and incidence of abnormal sperm were estimated in the epididymis. In testicular sections, the seminiferous tubules were observed for qualitative changes. The progression of spermatogenesis was arbitrarily classified as full-matured, maturing, and immature. The specimen slide was observed at 3 points and 10 seminiferous tubules were evaluated at each point. Results: The male rats exposed to single oral dose of BADGE at 750, 1000, and 2000 mg/kg/day were significantly increased the number of immature and maturing sperm on the testis. There were no significant differences with respect to sperm head count, sperm motility, and sperm abnormality in the BADGE treatment groups. Conclusions: These results suggest that single oral exposure of BADGE 750 mg/kg/day can affect adult male testis development.

An Experimental Study on Structural Behaviour of Asymmetric H Beam Slim floor under Load Condition in Fire (내화 피복된 비대칭 H형강을 적용한 슬림플로어 보의 재하가열조건 화재거동에 관한 실험적 연구)

  • Kim, Hyung-Jun;Kim, Hyung-Jun;Min, Byung-Youl;Lee, Jae-Sung;Park, Soo-Yong
    • Fire Science and Engineering
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    • v.25 no.1
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    • pp.63-71
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    • 2011
  • When it comes to slim floor using asymmetric H-beam, it was designed that the steel member is embedded in concrete with relatively low thermal conductivity so as to minimize the deterioration of rigidity of steel member in fire. But given the bottom flange of asymmetric H-beam is directly exposed to the fire, the measure of applying the fireproof coating to improve the fire rate performance of slim floor beam was sought. The test was aimed at comparing the fireproof performance by adjusting the load ratio of 0.4 and 0.3, and The test was carried out to identify the 3-hour fire performance by reinforcing the beam as well as applying the fireproof coat, In the wake of comparing the specimen depending on variation of load ratio, lowering load ratio by 0.1 resulted in difference of 12 minutes and deflection was 39 mm. It was able to improve 12 minutes by reinforcing the beam and up to 102.4 mm in deflection.

Effects of Relative Humidity and Temperature on the Transport of Chloride in the Concrete

  • Nam Jin-Gak;Hartt William H.;Kim Ki-Joon
    • Journal of the Korea Concrete Institute
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    • v.17 no.5 s.89
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    • pp.821-828
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    • 2005
  • To investigate the role of RH and temperature on the transport of chloride in the concrete, two groups of specimens were configured. For both groups, mix design was based on w/c=0.45, $400kg/m^3$ cement, $794kg/m^3$ fine aggregate and $858kg/m^3$ coarse aggregate. After specimen fabrication these were exposed to four different RH (35, 55, 75 and $95\%$ RH) and temperature (0, 20, 30 and $40^{\circ}C$) conditions. After 3 and 6 months $15\%$ NaCl exposure 5mm cores were taken. These cores were sliced and individual cores were ground to powder. In addition, to evaluate the effect of temperature on the chloride binding some powder samples were leached in the each of four temperature chambers. Chloride titration fur these was performed using FDOT acid titration method. Based upon the resultant data conclusions were reached regarding that 1) effective diffusion coefficient, $D_e$, increased with increasing exposure RH, suggesting that the size and number of water paths increased with elevated moisture content in the specimens, 2) $D_e$ increased with increasing temperature in the range of 0 to $40^{\circ}C$ possibly by elevated thermal activation of chloride ions and reduced chloride binding at higher temperature, 3) water soluble chloride concentration, $[Cl^-]_s$, increased with increasing temperature, and 4) chloride concentration profile for initially dry concrete specimens was higher than for the initially wet ones indicating pronounced capillary suction (sorption) occurred for the dry concrete specimens.

Flexural Performance Evaluation of HPFRCC Using Hybrid PVA Fibers (하이브리드 PVA 섬유를 이용한 HPFRCC의 휨 성능 평가)

  • Kim, Young-Woo;Min, Kyung-Hwan;Yang, Jun-Mo;Yoon, Young-Soo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.753-756
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    • 2008
  • HPFRCC (High-Performance Fiber Reinforced Cementitious Composites), which is relatively more ductile and has the characteristic of high toughness with high fiber volume fractions, can be used in structures subjected to extreme loads and exposed to durability problems. In the case of using PVA(polyvinyl alcohol) fibers, it is noted by former studies that around 2% fiber volume fractions contributes to the most effective performance at HPFRCC. In this study, therefore, compressive and flexural tests were implemented to evaluate the compressive and flexural capacities of HPFRCC while the total fiber volume fractions was fixed at 2% and two different PVA fibers were used with variable fiber volume fractions to control the micro-crack and macro-crack with short and long fibers, respectively. Moreover, specimens reinforced with steel and PVA fiber simultaneously were also tested to estimate their behavior and finally find out the optimized mixture. In the result of these experiments, the specimen consists of 1.6% short fibers (REC 15) and 0.4% long fiber (RF4000) outperformed other specimens. When a little steel fibers added to the mixture with 2% PVA fibers, the flexural capacity was increased, however, when high steel fiber volume fractions applied, the flexural capacity was decreased.

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Characteristics of Silane Treated Graphene Filled Nanocomposites Exposed to Low Earth Orbit Space Environment (저궤도 우주환경하의 실란처리된 그래핀 첨가 나노 복합재료의 물성특성)

  • Noh, Jae-Young;Jin, Seung-Bo;Kim, Chun-Gon
    • Composites Research
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    • v.28 no.3
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    • pp.130-135
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    • 2015
  • This study investigates the property of graphene filled polymer nanocomposites in LEO(Low Earth orbit) environment conditions. In order to improve compatibility with polymer matrices and resistance of carbon material against AO(Atomic oxygen) attack, silanization of graphene oxide with organosilane was carried out. The corresponding moieties were characterized through X-ray photoelectron spectroscopy (XPS). Graphene oxide filled nanocomposites were prepared using solution based processing methods. The sets of specimen series were tested in an accelerated LEO simulated space environment facility. Graphene oxide and silane treated graphene oxide reinforced nanocomposites were compared with neat epoxy. The comparison revealed that the silane treated graphene filled polymer composite shows inherent resistance against atomic oxygen attack while the lack of silane treatment resulted in a reduction in performance.

A Study on the 43$0^{\circ}C$ Degradation Behavior of Cast Stainless Steel(CF8M) (III) - Evaluation of Elastic-Plastic Fracture Toughness - (주조 스테인리스강 CF8M의 43$0^{\circ}C$ 열화거동에 관한 연구 (III) - 탄소성 파괴인성 평가 -)

  • Gwon, Jae-Do;In, Jae-Hyeon;Park, Jung-Cheol;Choe, Seong-Jong;Park, Yun-Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.10 s.181
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    • pp.2405-2412
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    • 2000
  • A cast stainless steel may experience an embrittlement when it is exposed to approximately 30$0^{\circ}C$ for long period. In the present investigation, The three classes of the thermally aged CF8M specimie n are prepared using an artificially accelerated aging method. Namely, after the specimen are held for 300, 1800 and 3600hrs. at 43$0^{\circ}C$ respectively, the specimens are quenched in water to room temperature. Load versus load line displacement curves and J-R curves are obtained using the unloading compliance method. $J_{IC}$ values are obtained following ASTM E 813-87 and ASTM E 813-81 methods. In addition to these methods, JIC values are obtained using SZW(stretch zone width) method described in JSME S 001-1981. The results of the unloading compliance method are $J_Q$=485.7 kJ/m$^2$ for virgin material, $J_{IC}$ of the degraded materials associated with 300, 1800 and 3600hrs are obtained 369.25 kJ/m$^2$, 311.02 kJ/m$^2$, 276.7 kJ/m$^2$, respectively. The results of SZW method are similar to those of the unloading compliance method. Through the elastic-plastic fracture toughness test, it is found that the value of $J_{IC}$ is decreased with increasing of the aging time. The results obtained through the investigation can provide reference data for a leak before break(LBB) of reactor coolant system of nuclear power plants.

A Study on the Fire Resistance Performance of Wood Framed Lightweight Wall which Including a Middle Lintel (중인방을 포함한 목골조 경량벽체의 내화성능에 관한 연구)

  • Yeo, In-Hwan;Cho, Bum-Yean;Min, Byung-Yeol;Yoon, Myung-O
    • Fire Science and Engineering
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    • v.25 no.3
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    • pp.91-98
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    • 2011
  • This study is about fire resistance performance of wood framed lightweight wall including a middle lintel as a traditional wall form in Korea. The target wall is non-loadbearing system which constructed with $38{\times}89$ mm ($2"{\times}4"$) wood frame and fireproof gypsum board covering, including a middle lintel made of $150{\times}150$ mm section glue-laminated timber. As a test results, all specimens have showed fire resistant performance over 90 minutes and tests were maintained until flame occuring on Specimen-l, 2, 3 at 91 min, 97 min and 98 min respectively. Fire resistance of the heat side gypsum board was 45 minutes and charring rate of middle lintel was equivalant with that of usual timber. The wood stud inside wall system showed relatively quick combution characteristic when exposed to high temperature with no temperature rising delaying time caused by moisture evaporation because of the dehydration preceded during the early period of fire side gypsum board resist to heat.

Occurrence of Post-larvae and Juveniles of Laeops kitaharae (Bothidae, Pleuronectiformes) in Korea (한국산 흰비늘가자미의 후기 자어와 치어 출현)

  • Youn, Chang-Ho;Huh, Sung-Hoi;Kim, Ik-Soo
    • Korean Journal of Ichthyology
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    • v.10 no.2
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    • pp.200-206
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    • 1998
  • Several specimens belonging to the family Bothidae were collected by trawls in Kwangyang Bay and off Kadeok Island in March 1996 and June 1998. These specimens were confirmed to be the post-larvae and juveniles of Laeops kitaharae (Smith and Pope, 1906) that have not been reported in Korea. According to the Amaoka's criterion (1972), four specimens belong to the middle metamorphic post-larval stage, one specimen to the late metamorphic post-larval stage, and two specimens to the juvenile stage. The middle metamorphic post-larval stage can be distinguished from the late metamorphic post-larval stage by the characters such as a notch between foreside of the dorsal fin and dorsal region of the right eye, and greatly elongated second spine of the dorsal fin. In the juvenile stage, the intestine was not externally exposed. However, the early metamorphic post-larval stage was not occurred in this study.

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In Vitro Study Of Salivary Bacterial Adherence On e-PTFE Membrane According To Periodontal Status. (치주조직 상태에 따른 e-PTFE막 부착에 관한 연구)

  • Ju, Jae-Ig;Chung, Hyun-Ju
    • Journal of Periodontal and Implant Science
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    • v.26 no.1
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    • pp.117-132
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    • 1996
  • The purpose of this study was to evaluate the bacterial adherence on e-PTFE membrane immersed in whole saliva from subjects with different periodontal status. Experiment involved 3 subject groups: 5 persons with healthy periodontium(probing depth below 3mm and no signs of gingival inflammation including bleeding on probing), 10 patients with gingivitis(probing depth below 3mm and apparent signs of gingival inflammation), and 10 patients with advanced periodontitis(probing depth over 7mm and apparent signs of gingival inflammation). Each disease group was included before and after scaling and root planing treatment. After obtaining whole saliva from each subject, e-PTFE membrane(Gore-Tex periodontal membrane : $GTPM^{(R)}$, W.L. Gore & Associates, Flagstaff, USA) specimens were immersed at room temperature in the saliva aliqouts for 1, 3, 7 days. The weight between pre - and post - immersion in saliva was measured with the analytical balance and the difference was recorded. The specimens were processed for SEM observation. The bacterial adherence on the membrane specimens was evaluated using the scanning electron microscope images. The obtained results were as follows : 1. There was no difference in the weight of bacteria adherent to e-PTFE membrane specimens according to the periodontal status and the immersion periods. 2. As the exposure time to saliva increased, the bacterial adherence to the membrane specimen significantly increased in all groups(P<0.005). 3. As the severity of periodontal disease increased, the bacterial adherence to the membrane specimens significantly increased(p<0.001). 4. After scaling and root planing, the bacterial adherence to the membrane specimens significantly decreased in gingivitis and periodontitis patient group(P<0.001). These results suggest that bacterial contamination on exposed barrier membrane surface be reduced through improvement of periodontal status and oral health environment before and after GTR procedure for the successful outcome.

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