• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 1999.10c
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• pp.283-288
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• 1999

This study is performed to evaluate slump , air content, compressive strength and length change ratio of non-shrinkage high strength ocncrete is achieved by 10% expansive additive contained. The length change ration of non-shrinkage high strength concrete which is in water curing, shows 0.055% expansion in 10% expansive additive contained concrete and 0.308 expansion in 20% expansion additive contained concrete when it is curing 28 days.

• International Journal of Concrete Structures and Materials
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• v.18 no.2E
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• pp.73-77
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• 2006

This paper shows a study of the efficiency of expansive additive and shrinkage reducing admixture in controlling restrained shrinkage cracking of high performance concrete at early age. Free autogenous shrinkage test of $100{\times}100{\times}400mm$ concrete specimens and simulated completely-restrained test with VRTM(variable restraint testing machine) were performed. Creep and autogenous shrinkage of high-performance concrete with and without expansive additive and shrinkage reducing admixture were investigated by experiments that provided data on free autogenous shrinkage and restrained shrinkage. The results showed that the addition of expansive additive and shrinkage reducing admixture effectively reduced autogenous shrinkage and tensile stress in the restrained conditions. Also, it was found that the shrinkage stress was relaxed by 90% in high-performance concrete with and without expansive additive and shrinkage reducing admixtures at early age.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.11a
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• pp.683-686
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• 2004

In recent years, some attention was particularly given to cracking sensitivity of high performance concrete. It has been argued and demonstrated experimentally that such concrete undergoes autogenous shrinkage due to self-desiccation at early age, and, as a result, internal tensile stress may develop, leading to micro cracking and macro cracking. One possible method to reduce cracking due to autogenous shrinkage is the addition of expansive additive. Tests conducted by many researches have shown the beneficial effects of addition of expansive additive for reducing the risk of shrinkage-introduced cracking. However, the research on hydration model of expansion additive has been hardly researched up to now. This paper presents a study of the hydration model of Ettringite-Gypsum type expansive additive. Result of comparing forecast values with experiment value, proposed model is shown to expressible of hydration of expansive additive.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.18 no.1
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• pp.5-9
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• 2008

Cordierite has a very low thermal expansion coefficient, but has problem that it has a weak mechanical strength and is apt to be attacked by acid such as sulfur for using as a diesel particulate filter support. The physical properties of $ZrTiO_4$ modified with $SiO_2,\;Al_2O_3$, MoOx, $Cr_2O_3\;and\;Nb_2O_5$ were investigated with XRD, SEM, UTM and thermal expansion, etc. in this paper. $ZrTiO_4$ powder was synthesized as a monoclinic structure with processes that starting materials of $TiO_2\;and\;ZrO_2$ were mixed with ball mill and calcined above $1240^{\circ}C$ for 3 hr. Additive modified $ZrTiO_4$ specimens for flexural strength and thermal expansion measurement were obtained by mixing $ZrTiO_4$ powder with additives, pressing and firing at $1300^{\circ}C$ for 3 hr. The porosity of additive modified $ZrTiO_4$ decreased monotonically with increasing additive content by 5 wt% regardless of additive types and saturated for further increase of additive by 10wt. The flexural strength of $Al_2O_3$ (5, 10 wt%) modified $ZrTiO_4$ shows a large increase, but that of other additives modified $ZrTiO_4$ decreased. The thermal expansion coefficient of additive modified $ZrTiO_4$ except $Nb_2O_5$ decreased continuously with the content of additive. In particular, the lowest thermal expansion coefficient of $ZrTiO_4$ was obtained for the additive of $SiO_2$.

• Journal of Power System Engineering
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• v.18 no.6
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• pp.126-132
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• 2014

The P-T characteristics of mixed refrigerant in thermostatic expansion valve sensing bulb were studied using R-134a and R-410A refrigerant. The characteristics of mixed refrigerant were investigated according to pressure variation and the variation of composition ratio of R-134A and R-410A in the temperature range of $-15^{\circ}C{\sim}15^{\circ}C$. The Thermodynamic characteristic values of the mixed refrigerants were identified using the characteristic value analysis program of mixed refrigerant(Refrop v9.0, NIST). The P-T characteristics in the case of the mixing ratio of 90:10 for R-410A and R-134A were the same result as R-22. And the physical properties showed similar results with R-22. The Maximum operating pressure(MOP) of mixed refrigerant showed a tendency to decrease with decreasing the mixing ratio of additive gases($N_2$ or He) gases. The characteristics in the case of the mixing ratio of 80:1 for mixed refrigerant and additive gases were the similar result as Reference refrigerant.(R-22 MOP, Sporlan company) In addition $N_2$ and He, both showed the same results. It was able to confirm that a MOP on the thermostatic expansion valve sensing bulb can be maintained by adjusting the mixing ratio of mixed refrigerant gases and additive gases.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2008.11a
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• pp.117-120
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• 2008

The Purpose of this is properties of CFT filled with expansion concrete. CFT(concrete filled steel tube) is the structure that circle shape steel column filled with concrete. 3 kinds of expansive additives and variation of replacement rate. we changed expansive additive from 0%, 10%, 20%, 30% of ratio of addition rate are selected for this experiment. Merits of CFT are concrete internal force rising influenced by steel shape restriction, reinforcing the local buckling, excellent resistance to transformation. Generally, High rise building using CFT utilize the high strength and fluidity concrete for packing the tube inside. As the result a steel tube charged expensive concrete has stiffness 1.5times more than a steel tube not charged concrete. Increase of resisting power about compressive stress by binding expansion of expansive concrete affects strength increase and softness.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.789-792
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• 2005

Development of high-strength concrete and improved durability has brought new opportunities to the construction industry. However, some attention was given to characteristics of such concrete, in particular with respect to their cracking sensitivity. It has been argued and demonstrated experimentally that a low water/cement ratio concrete undergoes shrinkage due to self-desiccation. This so-called autogenous shrinkage cracking is a major concern for concrete durability. One possible method to reduce cracking due to autogenous shrinkage is the addition of expansive additive. Tests conducted by many researches have shown the beneficial effects of addition of expansive for reducing the risk of shrinkage-introduced cracking. This paper aimed at forecasting deformation of high strength cement paste with expansive additive for early age.

• Journal of the Korean Ceramic Society
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• v.30 no.5
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• pp.381-388
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• 1993

Due to the anisotropy of thermal expansion, LAS system which has low thermal expansion property is hard to obtain a dense sintered body. Therefore, the thermal expansion coefficient and the mechanical strength were decreased. In this study, mullite, which has good mechanical properties in high temperature and comparatively low thmeral expansion coefficient, was taken as a additive in LAS system. And then, sintering, thermal, and mechanical properties were investigated. The results are follows; When mullite is added in eucryptite composition (Li2O.Al2O3.2SiO2) of LAS system, the creation of liquid phase results in the densification of sintered body and the specimen sintered at 136$0^{\circ}C$ for 2 hours shows optimum sintering condition. With the addition of mullite in eucryptite composition, mechanical strength is increased by the control of grain growth. Especially, flexual strength of EM0 specimen was about double value than the basic composition. Thermal expansion coefficients of EM0 and EM15 specimens sintered at 136$0^{\circ}C$ were -8.23$\times$10-6/$^{\circ}C$ and -4.90$\times$10-6/$^{\circ}C$ in the temperature range of RT.~80$0^{\circ}C$. As the mullite content are increased, negative thermal expansion ratios are decreased.

• Geomechanics and Engineering
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• v.6 no.2
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• pp.139-151
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• 2014

Mudstone is a very common rock that, when in contact with water, can exhibit considerable volume change and breakdown. This behavior of mudstone is frequently encountered in geotechnical engineering and has a considerable influence on infrastructure stability. This is particularly important in the present work, which focuses on mitigating the harmful properties of mudstone. The samples studied are of Permian Age mudstone from Shandong Province, China. Modification tests using organic silicone additive material were carried out. The mechanisms of physical properties modification of mudstone were comparatively studied using corresponding test methods, and the modification mechanism of organic silicone additive material acting on mudstone was analyzed. The following conclusions were drawn. The surface texture and characters of mudstone changed dramatically, surface character turns from hydrophilic to hydrophobic after organic silicone additive material modification. The changes in the surface character indicate a reduction in the water sensitivity of mudstone. After modification, the shape of porosity and fracture of mudstone changed unremarkable, and the total and free expansion ratios decreased obviously, whereas the strength increased markedly.

• Journal of Electrochemical Science and Technology
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• v.12 no.1
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• pp.67-73
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• 2021

Nickel-rich lithium nickel-cobalt-manganese oxides (NCM) are viewed as promising cathode materials for lithium-ion batteries (LIBs); however, their poor cycling performance at high temperature is a critical hurdle preventing expansion of their applications. We propose the use of a functional electrolyte additive, triphenyl phosphate (TPPa), which can form an effective cathode-electrolyte interphase (CEI) layer on the surface of Ni-rich NCM cathode material by electrochemical reactions. Linear sweep voltammetry confirms that the TPPa additive is electrochemically oxidized at around 4.83 V (vs. Li/Li+) and it participates in the formation of a CEI layer on the surface of NCM811 cathode material. During high temperature cycling, TPPa greatly improves the cycling performance of NCM811 cathode material, as a cell cycled with TPPa-containing electrolyte exhibits a retention (133.7 mA h g-1) of 63.5%, while a cell cycled with standard electrolyte shows poor cycling retention (51.3%, 108.3 mA h g-1). Further systematic analyses on recovered NCM811 cathodes demonstrate the effectiveness of the TPPa-based CEI layer in the cell, as electrolyte decomposition is suppressed in the cell cycled with TPPa-containing electrolyte. This confirms that TPPa is effective at increasing the surface stability of NCM811 cathode material because the TPPa-initiated POx-based CEI layer prevents electrolyte decomposition in the cell even at high temperatures.