• Journal of the Society of Disaster Information
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• v.13 no.1
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• pp.35-42
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• 2017

In this study, to quantitatively evaluate the strength characteristics of the inflatable liquid used for the recovery of soft ground or partial settlement, the inflatable liquids were prepared by dividing the inflatable capacity and the strength characteristics were analyzed according to the conditions. The experimental group was divided into two groups: relatively high expansion group and low expansion group. The specimens were prepared by controlling the volume of 10 ~ 30% of the maximum expansion volume, and the strength of the specimens were evaluated. The compressive strength of the high expansion group and low expansion group was about 2.1 times.

• Polymer(Korea)
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• v.24 no.2
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• pp.149-158
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• 2000

Oil-absorptive expanded polyurethane (EPU) was prepared with a lypophilic polyol, polypropyleneglycol (PPG) as the soft segment, and toluenediisocyanate (TDI) and $H_2O$ as the hard segment. PPGs haying various average molecular weights ((equation omitted) : 1000, 2000, 3000) were employed to investigate that the soft segment content was consequent on the oil-absorptivity and the mechanical properties of the EPUs. As (equation omitted) of PPG was decreased from 3000 to 1000, the oil-absorptivity and the tensile strength of the EPUs increased from 1460 to 3010% and from 0.26 to 0.55 $kg_{f}$ /$cm^2$ respectively. As the hard segment content ratio, ${\gamma}$ ([NCO]/[OH]) was increased from 1.0 to 1.2, the tensile strength of the EPUs increased from 0.56 to 0.95 $kg_{f}$ /$cm^2$, due to the formation of allophanate and/or biuret bondings. However, as the surfactant (S-A) content was increased from 1.0 to 2.5 pbw, the oil-absorptivity was decreased from 3634 to 3312%, due to the formation of closed cell structures.

• Proceedings of the Korea Concrete Institute Conference
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• 1996.10a
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• pp.253-259
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• 1996

The purpose of this study is to investigate the fundamental properties of polyurethan concrete. Polyurethane must be expanded by means of a blowing agent during polymerization. Chemical blowing is caused by the reaction water with isocyanate. Binder system for polyurethane concrete is based on polyol and isocyanate with catalyst, surfactant, and methyl chloride. Polyurethane concretes are prepared with various grading of aggregate, and tested for compressive, flexural strengths, flow test, foaming multiple proportion, working life, condition of surface, distirbution of aggregate. From the test results, the foaming of polyurethane concretes are affceted by amount and grading of aggregate. Workability increases with raising amount of methy chloride and working life reduced according to amount of catalyst. The mix proportion of B with methyl chloride of 1% and catalyst of 0.1g for polyurethane concrete is recommended in consideration of strengths, condition of surface and balance between cost and performance.

• Journal of the Korean Electrochemical Society
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• v.12 no.2
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• pp.181-188
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• 2009

Pt catalyst was adsorbed on Carbon nanofiber (CNF) by modified polyol method after acid treatment of the carbon support with $HNO_3$ and $H_{2}SO_{4}$. As the time for acid treatment increases, more oxygen functional groups on carbon surface were produced which improve the loading amount and dispersion of Pt catalyst on carbon supports. In order to inspect the effect of CNF acid treatment time on electrochemical corrosion, constant potential of 1.4 V was applied to a single cell for 30 min and the amount of $CO_2$ emitted was monitored with on-line mass spectrometry. According to the results of our experiment, more $CO_2$ was produced with Pt/ oxidized-CNF catalyst in compared to that with unoxidized-CNF. Increasing acid treatment time also induces the more $CO_2$ emission. Besides, performance degradation after corrosion test expanded with severer carbon corrosion. From the observed results, it can be concluded that the acid treatment of CNF is beneficial to catalyst loading, but it also is a significant factor declining the fuel cell durability by accelerating electrochemical oxidation of carbon support.

• Polymer(Korea)
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• v.29 no.2
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• pp.177-182
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• 2005

Montmorillonite (MMT) modified with siloxane diamine was reacted with a reactant obtained from 4,4'-diphenyl methane diisocyanate (MDI) and polyester type polyol, $Nippollan4010(\bar{M}_n2000)$. Finally, polyurethane (PU)/MMT composites were prepared by using 1,4-butane diol as a chain extender in $25\;wt\%$ solution of N,N-dimethyl acetamide (DMAc). It was expected that these nanocomposites had superior exfoliation property to that of MMT dispersed polyurethanes produced by simple mixing due to insertion of siloxane main chain to the silicate interlayer of MMT. Extent of reaction and formation of final products were analysed by using FT-IR spectroscopy. Dispersion into the PU and intercalation of MMT were identified by applying X-ray diffraction (XRD) and transmission electron microscopy (TEM). Tensile data were acquired by universal test machine (UTM). Thermal stability and variation of surface energy were characterized by thermal gravimetric analysis (TGA) method and measurement of contact angle on the synthesized composites, respectively. As the results the organo-MMT modified with siloxane diamine in the PU composites has an intercalated structure relatively well-expanded rather than a completely exfoliated structure. The tensile strengths and the moduli for the PU/organo-MMT composites were drastically enhanced in comparison to those of $PU/Na^+-MMT$ composites.