• Polymer(Korea)
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• v.29 no.2
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• pp.177-182
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• 2005

Montmorillonite (MMT) modified with siloxane diamine was reacted with a reactant obtained from 4,4'-diphenyl methane diisocyanate (MDI) and polyester type polyol, $Nippollan4010(\bar{M}_n2000)$. Finally, polyurethane (PU)/MMT composites were prepared by using 1,4-butane diol as a chain extender in $25\;wt\%$ solution of N,N-dimethyl acetamide (DMAc). It was expected that these nanocomposites had superior exfoliation property to that of MMT dispersed polyurethanes produced by simple mixing due to insertion of siloxane main chain to the silicate interlayer of MMT. Extent of reaction and formation of final products were analysed by using FT-IR spectroscopy. Dispersion into the PU and intercalation of MMT were identified by applying X-ray diffraction (XRD) and transmission electron microscopy (TEM). Tensile data were acquired by universal test machine (UTM). Thermal stability and variation of surface energy were characterized by thermal gravimetric analysis (TGA) method and measurement of contact angle on the synthesized composites, respectively. As the results the organo-MMT modified with siloxane diamine in the PU composites has an intercalated structure relatively well-expanded rather than a completely exfoliated structure. The tensile strengths and the moduli for the PU/organo-MMT composites were drastically enhanced in comparison to those of $PU/Na^+-MMT$ composites.

• Journal of the Korea Concrete Institute
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• v.17 no.1 s.85
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• pp.19-25
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• 2005

Recycling of waste materials in the construction Industry is a useful method that can cope with an environment restriction of every country. In this study, synthetic lightweight aggregates are manufactured with recycled plastic and fly ash with 12 percent carbon. Nominal maximum-size aggregates of 9.5 mm were produced with fly ash contents of 0, 35, and $80\%$ by the total mass of the aggregate. An expanded clay lightweight aggregate and a normal-weight aggregate were used as comparison. Gradation, density, and absorption capacity are reported for the aggregates. Five batches of concrete were made with the different coarse aggregate types. Mechanical properties of the concrete were determined including density, compressive strength, elastic modulus, splitting tensile strength, fracture toughness, and fracture energy. Salt-scaling resistance, a concrete durability property, was also examined. Compressive and tensile strengths were lower for the synthetic aggregates; however, comparable fracture properties were obtained. Relatively low compressive modulus of elasticity was found for concretes with the synthetic lightweight aggregate, although high ductility was also obtained. As nv ash content of the synthetic lightweight aggregate increased, all properties of the concrete were improved. Excellent salt-scaling resistance was obtained with the synthetic lightweight aggregate containing 80 percent fly ash.

• Korean Journal of Agricultural Science
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• v.25 no.2
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• pp.271-277
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• 1998

This study was performed to evaluate the stress-strain properties of surlightweight polymer concrete using synthetic lightweight aggregates. The following conclusions were drawn; 1. The dynamic modulus of elasticity was in the range of $1.514{\times}10^5{\sim}1.916{\times}10^5kgf/cm^2$, which was approximately 48~96% of that of the normal cement concrete. It was showed larger with the decrease of synthetic lightweight fine aggregate. 2. The static modulus of elasticity was in the range of $2.552{\times}10^4{\sim}4.386{\times}10^4kgf/cm^2$, which was showed lower compared to that of the normal cement concrete. The poisson's number of surlightweight polymer concrete was less than that of the normal cement concrete. 3. The stress-strain curves of surlightweight polymer concrete were showed smaller with the increase of expanded clay.

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.4
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• pp.498-505
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• 2020

Aggregate occupies about 70-85% of the concrete volume and is an important factor in reducing the drying shrinkage of concrete. However, when constructing high-rise buildings, it acts as a problem due to the high load of natural aggregates. If the load becomes large during the construction of a high-rise building, creep may occur and the ground may be eroded. Material costs increase and there are financial problems. In order to reduce the load on concrete, we are working to reduce the weight of aggregates. However, artificial lightweight aggregates affect the interface between the aggregate and the paste due to its higher absorption rate and lower adhesion strength than natural aggregates, affecting the overall strength of concrete. Therefore, in this study, in order to grasp the interface between natural aggregate and lightweight aggregate by type, we adopted a method of measuring electrical resistance using an EIS measuring device, which is a non-destructive test, and lightweight bone. The change in the state of the interface was tested on the outside of the material through a blast furnace slag coating. As a result of the experiment, it was confirmed that the electric resistance was about 90% lower than that in the air-dried state through the electrolyte immersion, and the electric resistance differs depending on the type of aggregate and the presence or absence of coating. As a result of the experiment, the difference in compressive strength depending on the type of aggregate and the presence or absence of coating was shown, and the difference in impedance value and phase angle for each type of lightweight aggregate was shown.

• Journal of the Korean Geotechnical Society
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• v.37 no.11
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• pp.83-92
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• 2021

In this study, effective porosity measurement, electron microscope (SEM) observation, X-ray diffraction analysis (XRD), slaking, swelling, and unconfined compression strength according to water immersion were analyzed to evaluate the properties of mudstone with high porosity in Pohang. As a result of the test for 16 square samples (5 cm), the effective porosity was 14.67% on average, higher than porosity of general mudstone, and electron microscope observation confirmed that the porosity was actually high. As a result of X-ray diffraction analysis, the swelling clay mineral content was 2.3~4.1%, which was lower than the results of previous studies in Pohang. The slake durability index was 37.73~87.73%, showing low to medium durability, which was lower than the results of previous studies. It was confirmed that the swelling property rapidly expanded to 1.79~1.82% of maximum swelling strain in the major axis direction for 30 minutes. As the properties of decreasing the unconfined compression strength according to water immersion, the samples rapidly weathered after 10 minutes of water immersion, and the strength decreased. It was confirmed that the results of previous studies related to mudstone in Pohang were different. This is judged to be due to the high porosity of mudstone in study.

• Journal of The Geomorphological Association of Korea
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• v.18 no.4
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• pp.223-233
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• 2011

The aims of this study is about distribution characteristics of tidal coastal landforms, and that changing process in the Hampyeung Bay, which has a semi-enclosed bay like basin shape without inflow of stream, the mouth of open sea is narrow and forms with wide ends toward inland sea. The source of deposits are moved materials by tidal currents and from coastal slopes. Main landform elements of study area consist of tidal flat, tidal channels, intertidal sand bar, sea cliffs, and sea terrace. Tidal flats is classified with mud flat and mixed flat by grain size composition. Mud flats have developed at the shoreline area that tidal flat is closed to the continuity of gentle slope, and mixed flat developed at the foot of the sea cliffs and sea terraces. Quaternary deposits were identified in the coastal materials sedimented by the sea-level change. According to the analysis of grain size composition during last ten years, sands and silt has increased 2% and 6% respectively, clay has been decreased by 9%. The concaved tidal flats are colonized by salt plants. Areal changes of salt plants expanded near four times from 2.4km² at the year 2001 to 9.3km² at the year 2009. During the same periods, mean grain size became coarser from 6.5φ to 4.5φ at the salt plants area.