• Title/Summary/Keyword: excess water

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An Evaluation on the Combustion Characteristics of Heavy Oil-Water Emulsions (중질유-물 유화연료의 연소특성 평가)

  • Lee, Yong-Il
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.12
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    • pp.1722-1728
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    • 2002
  • Most researches regarding emulsified fuel were in the areas of emulsifier, emulsified fuel manufacturing and emulsified fuel droplet combustion, but there were little papers published regarding emulsified fuel combustion and boiler efficiency in an industrial boiler. The main purpose of this study is to clarify whether improvements in the boiler efficiency and the reduction of pollutants such as CO, NOx, SOx and smoke exist or not when emulsified fuels are combusted in the commercial boiler. Main experimental parameters were water content in heavy oil , excess $O_2$, and boiler load. The fuels used in this experiment were 0.5 B-C, and 5 kinds of 0.5 B-C/water emulsified fuels. The combustion characteristics of heavy oil and its emulsions with water were investigated in an industrial boiler. The combustion stability was monitored and exhaust gases such as CO, NOx, SOx and smoke were measured with excess $O_2$ and combustion load. In case of emulsified fuel combustion, flame stability was poor and boiler efficiency was lowered by 1.6~5.7%, but emission levels of CO and smoke were improved.

Development of Molecular Dynamics Model for Water Electrolysis Ionomer (수전해용 이오노머 분자동역학 모델 개발)

  • Kang, Hoseong;Park, Chi Hoon;Lee, Chang Hyun
    • Membrane Journal
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    • v.30 no.6
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    • pp.433-442
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    • 2020
  • In this study, in order to build a molecular dynamics simulation model of ionomer for water electrolysis, an ionomer model that reflects the characteristics of a water electrolysis system in which excess water molecules exist was compared to an ionomer built according to the conventional simulation method of the fuel cells membrane. The final ionomer MD models have a strong phase separation and water channel that is one of the important characteristics of the perfluorinated ionomer, and are stable and water-insoluble under excessive water and high temperature conditions. In the ionomer MD models built in this study, the excess water molecules decrease an ion conductivity due to the dilution of ions, but increase a hydrogen diffusivity. Therefore, it is necessary to design the molecular structure of ionomers for water electrolysis in experimental studies as well as molecular dynamics studies according to the characteristics of the water electrolysis system reported in this study.

Influence of Penetration Rate on Piezocone Penetration Test (변형율 속도가 콘관입시험에 미치는 영향)

  • Kim, Dae-kyu
    • Proceedings of the Korean Geotechical Society Conference
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    • 2000.02a
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    • pp.59-70
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    • 2000
  • 본 연구에서는 콘관입속도가 콘관입시험 결과에 미치는 영향을 연구하기 위하여 LSU/CALCHAS(Louisiana State University Calibration Chamber System)를 이용한 미니 Piezocone의 관입시험이 수행되었으며 그 결과를 비교 분석하였다. 10회의 미니 Piezocone 관입시험이 Ko 조건에서 수행되었으며 33% kaolin, 67% sand mixture가 시료로 사용되었고, 콘관입속도 0.3, 0.6cm/sec, U1(filter element at the cone tip), U2(filter element above the cone base), OCR=1, 10 의 조건이 다양하게 적용되었다. 시험결과 Cone Resistance, Excess Pore Water Pressure, Sleeve Friction 은 U1, U2 두 종류의 콘에 대해서 모두 관입속도가 커짐에 따라 증가하였으나 OCR의 증가에 따라서는 감소하였으며 U1의 Excess Pore Water Pressure가 U2 경우보다 크게 측정되었다.

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An Estimation of Smear Zone Induced by Vertical Drain Construction Based on the Laboratory Model test (실내모형실험을 통한 연직배수재 타설에 의한 스미어존의 평가)

  • Kim, Hong-Taek;Han, Yeon-Jin;Kim, Seong-Wook;Hwang, Jeong-Soon
    • 한국방재학회:학술대회논문집
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    • 2007.02a
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    • pp.279-282
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    • 2007
  • When ground disturbance takes place due to vertical drain construction through mandrel penetration, that affects excess pore water pressure dissipation time because of soft clay coefficient of permeability decreasing. Eventually, consolidation time is influenced. In this research, we measure process of excess pore water pressure dissipation before and after each other different shape's mandrel penetration through model test, and calculates range of smear zone, coefficient of permeability and horizontal coefficient of consolidation after model test. Using of test result, we grasp a degree of drainage ability drop resulting from vertical drain construction.

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A Study on the Liquefaction Resistance of Anisotropic Sample under Real Earthquake Loading (이방 구속 조건에서 실지진 하중을 이용한 액상화 저항강도 특성 분석)

  • Lee, Chae-Jin;Jeong, Sang-Seom;Kim, Soo-Il
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.09a
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    • pp.1188-1191
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    • 2009
  • In this study, cyclic triaxial tests were performed with the samples which were anisotropically consolidated using irregular earthquake loading to consider in-situ condition and seismic wave. The consolidation pressure ratio(K) was changed from 0.5 to 1.0. The Ofunato and Hachinohe wave are applied as irregular earthquake loading and liquefaction resistance strength was estimated from excess pore water pressure(EPWP) ratio. As results of the cyclic triaxial tests, buildup of EPWP ratio increased as K value increased. It shows, that the isotropically consolidated sands is more susceptible to liquefaction than anisotropically consolidated sands under equal conditions such as confining pressure and dynamic loading.

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Preparation of High Purity Alumina by Alkoxide Process (Aluminum Isopropoxide의 가수분해법에 의한 고순도 $\alpha$-Al2O3의 제조)

  • 백행남;이명기;곽중협;서태수
    • Journal of the Korean Ceramic Society
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    • v.26 no.3
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    • pp.445-451
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    • 1989
  • Hydrolysis of aluminum isopropoxide with excess water in the presence of excess isopropyl alcohol resulted in the formation of boehmite in independence of temperature of hydrolysis and aging. Stoichiometric and substoichiometric amount of water hydrolyzed aluminum isopropoxide to pseudo-boehmite and amorphous one, respectively. $\alpha$-Al2O3 with 0.3${\mu}{\textrm}{m}$ in median size was produced by calcination of boehmite, bseudo-boehmite and amorphous boehmite at 125$0^{\circ}C$, 120$0^{\circ}C$, and 115$0^{\circ}C$ for one hour, respectively. Singnificant reduction in particle size was found during transition from $\theta$-Al2O3 to $\alpha$-Al2O3. $\alpha$-Al2O3 produced in this study was relatively uniform spherical and its purity was found to be over 99.9%.

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Static Dielectric Constant and Relaxation Time for the Binary Mixture of Water, Ethanol, N. N-Dimethylformamide, Dimethylsulphoxide, and N, M-Dimethylacetamide with 20Hethoxyethanol

  • Ajay Chaudgari;N. M. More;S. C. Mehrotra
    • Bulletin of the Korean Chemical Society
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    • v.22 no.4
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    • pp.357-361
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    • 2001
  • Frequency spectra of the complex permittivity of 2-methoxyethanol (2-ME) with water, ethanol, dimethylsulphoxide (DMSO), N,N-dimethylformamide (DMF) and N,N-dimethylacatamide (DMA) have been determined over the frequency range of 10 MHz to 20 GHz at 25 $^{\circ}C$, using the Time domain reflectometry method, for 11 concentrations for each system. The static dielectric constant, dielectric constant at microwave frequency, relaxation time, excess dielectric parameters, and Kirkwood correlation factor have been determined. The relaxation in these systems within the frequency range can be described by a single relaxation time constant, using the Debye model. The parameters show a systematic change with the concentration.

피에조 콘 소산시험을 이용한 압밀계수 추정시 이론해의 선택 및 현장지반의 압밀도 평가

  • 이승래;김영상
    • Proceedings of the Korean Geotechical Society Conference
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    • 1998.04a
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    • pp.37-46
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    • 1998
  • Several researchers have developed a number of theoretical time factors to determine the coefficient of consolidation by biezocone excess pore water dissipation test in soft clay deposits. However, depending on the assumptions and analytical techniques, the estimated coefficient of consolidation could be in a considerably wide range even for a specific degree of consolidation. These solutions are obtained from an initial excess porewater pressure distribution which can be determined from. either the cavity expansion theory or the strain path method. The 야ssipation of the initial excess porelvater pressure has been usally simulated by means of linear-uncoupled consolidation analysis and then the dissipation curve is normalized by the initial excess porewater pressure for easy use. However. since there is no guidelines or rules on which method gives the best solution for obtaining the coefficient of consolidation from the dissipation curve, the final selection was only based on engineer's extrience and Judgements. Thus, such an arbitrary selection might be inappropriate for a specific site to characterize the consolidation behavior. In this paper, we reviewed various theoretical time factors and, based on this consideration, we mentioned needs for researches in selecting a specific solution that is compatible for Korean clays. Also we listed some source of errors that can be encountered in the procedure of dissipation analysis.

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Comparison of 1-g and Centrifuge Model Tests on Liquefied Sand Grounds (액상화 지반에 대한 1-g 모형실험과 원심모형실험의 비교 연구)

  • Kim, Sung-Ryul;Hwang, Jae-Ik;Ko, Hon-Yim;Kim, Myoung-Mo
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 2006.03a
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    • pp.97-104
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    • 2006
  • The centrifuge and 1-g shaking table tests were performed simultaneously to compare the dynamic behaviors of loose sands of same geotechnical properties. The prototype soils were 10 m thick liquefiable loose sands. The geometric scaling factors were 20 for 1-g and 40 for centrifuge tests. The excess pore pressure, surface settlement, and acceleration in the soil were measured at the same locations in the 1-g and centrifuge tests. The total excess pore pressure from development to dissipation was measured. In the centrifuge test, viscous fluid was used as the pore water to eliminate the time scaling difference between dynamic time and dissipation time. In the 1-g tests, the steady state concept was applied to determine the unit weight of the model soil, and two different time scaling factors were applied for the dynamic time and the dissipationtime. It is concluded that the 1-g tests can simulate the excess pore pressure of the prototype soil if the permeability of the model soil is small enough to prevent dissipation of excess pore pressure during shaking and the dissipation time scaling factor is properly determined.

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Health risk assessment for radon of groundwater in Korea

  • Kim, Yeshin;Kim, Jinyong;Park, Hoasung;Park, Soungeun;Dongchun Shin
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2003.10a
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    • pp.170-170
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    • 2003
  • An initial study has been conducted with Korea Institute of Geoscience and Mineral resources and National Institute of Environment Research to evaluate the distribution of radon levels and their risk levels of groundwater in Korea. Probability distribution of 616 samples was log-normal one with 1,867pCi/L as arithmetic value, 920pCi/L as median and 40,010pCi/L as maximum during iou. years(1999-2002). In addition, 10% of total samples are in excess of 4,000pCi/L, 20% in excess of 2,700pCi/L, and 30% in excess of 1,700pCi/L, and 15 samples exceeds 10,000pCi/L. Total samples are grouped into 10 areas and 5 rocks unit, and difference of concentrations among areas and rocks are statistically significant(respectively, p<0.0001). The highest area is Daejeon located in ogcheon metamorphic rocks and granitic rocks, and most of all sites with high concentration sites are located in granitic rocks. The lowest area is Jeju located in volcanic rocks. We have estimated excess cancer risks of radon based on these data. To estimate risks, first of all, use patterns of groundwater are categorized with 6 groups: for drinking, household, farming, washing cars, raising stock, and others. We considered risk only for drinking water and household water because radon is rapidly dispersed before it of other use reach human respiratory organs. We select 565 samples for risk analysis, and applied unit risk which is 6.6210-7 per pCi/L to be recommended by NAS committee. Unit risk was derived from considering radon ingestion and radon inhalation from water use. When estimating risk, we analyzed PDF of concentration and represented risk as 50 and 95 percentile values to consider uncertainty with Monte-Carlo simulation. It results in 10-4 level of their excess cancer risk and in 10-2 level in some areas with high concentration of radon. It must be monitor periodically and take adequate actions in these risky sites. We recommend that it needs to take more survey and finally set guideline for radon regulation in groundwater.

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