• Bulletin of the Korean Chemical Society
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• 제33권5호
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• pp.1686-1692
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• 2012

Densities (${\rho}$), Viscosities (${\eta}$) and ultrasonic speeds (u) of pure acetophenone (AP), propiophenone (PP), $p$-methyl acetophenone ($p$-MeAP), $p$-chloroacetophenone ($p$-ClAP) and those of their binary mixtures with $N$-ethyl aniline ($N$-EA) as a common component, were measured at 303.15 K over the entire composition range. These experimental data were used to calculate the excess volume $V^E$, deviation in ultrasonic speeds ${\Delta}u$, isentropic compressibility $K_s$, intermolecular free length $L_f$, acoustic impedance Z, deviations in isentropic compressibility ${\Delta}K_s$, deviation in viscosity ${\Delta}{\eta}$ and excess Gibbs free energy of activation of viscous flow ($G^{*E}$) at all mole fractions of $N$-ethyl aniline. These parameters, especially excess functions, are found to be quite sensitive towards the intermolecular interactions between component molecules. Theoretical values of viscosity of the binary mixtures were calculated using different empirical relations and theories. The relative merits of these relations and theories were discussed. The experimental results were correlated by using the polynomial proposed by Redlich-Kister equation.

• 천문학회보
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• 제40권1호
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• pp.48.2-48.2
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• 2015

van Dokkum and Conroy revisited the strong Na I lines at $8200{\AA}$ found in some giant elliptical galaxies and interpreted it as evidence for bottom-heavy initial mass function. Jeong et al. later found a lot of galaxies showing strong Na D doublet absorption line at $5900{\AA}$ (Na D excess objects; a.k.a. NEOs) and showed that their origins can be different for different types of galaxies. While the excess in Na D seems related with interstellar medium in late-type galaxies, smooth-looking early-type NEOs suggest no compelling sign of ISM contributions. To test this finding, we measured doppler shift in the Na D line. We hypothesized that ISM is more likely to show blueshift due to outflow caused by either star formation or AGN activities. In order to measure the doppler shift, we tried both Gaussian and Voigt functions to fit each galaxy spectrum near the Na D line. We found that Voigt profiles reproduce the shapes of the Na D lines markedly better. Many of late-type NEOs clearly show blueshift in their Na D lines, which is consistent with the former interpretation that the Na D excess found in them is related with star formation-caused gas outflow. On the contrary, early-type NEOs do not show any notable doppler component, which is also consistent with the interpretation of Jeong et al. that the Na D excess in early-type NEOs is likely not related with ISM activities but purely stellar in origin.

• 전자공학회논문지T
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• 제36T권3호
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• pp.7-12
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• 1999

본 논문은 (1-x-y)PMN-yPT-xST세라믹스의 유전 및 변위특성을 ST의 양에 따라 조사하였다. ST의 성분은 1∼ 6㏖%이내로 변화시켰고 과잉 MgO에 따른 조성변화에 따라 결과를 조사하였다. ST의 성분의 증가에 따라 유전상수는 5㏖%인 조성에서 최대값을 나타내었다. 큐리온도는 ST의 성분이 증가함에 따라 선형적으로 감소하였다. 항전계와 잔류분극은 l㏖%인 조성에서 최대값을 나타내었다. 과잉 MgO의 효과에 따라 유전상수는 0.8PMN-0.12PT-0.04ST조성에서 MgO를 3㏖%까지 과잉 첨가함에 따라 증가하였으나 변위특성은 감소함을 나타내었다.

• 대한화학회지
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• 제29권4호
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• pp.341-347
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• 1985

금속이온이 생체내에서 생체성분과 금속착물을 형성하는 것이 여러가지 생물학적 작용의 첫단계로 인정되고 있다. 본 연구에서 금속이온의 착물형성에 중요한 인자로서 과잉편극세기가 순수한 친자성 척도가 됨을 알았으며, 또한 과잉편극세기가 금속착물의 생성상수와 관련된 Irving-Williams계열을 설명할 수 있었다. 실험적으로 발암성이 밝혀진 금속이온의 과잉편극세기의 값이 0.22이상이었으며 나아가서 과잉편극세기의 값이 0.22이상인 금속이온은 발암성을 가질 수 있을 것으로 예측된다. 따라서 이 양을 금속이온의 화학발암성의 척도로 채택할 것을 제안한다.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2006년도 추계 학술발표회
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• pp.312-333
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• 2006

This paper presents the results of an analysis of the excess porewater pressure distribution due to piezocone penetration in overconsolidated clays. From piezocone test results for moderately and heavily overconsolidated clays, it was observed that the excess porewater pressure increases monotonically from the piezocone surface to the outer boundary of the shear zone and then decreases logarithmically to the outer boundary of the plastic zone. It was also found that the size of the shear zone decreases from approximately 2.2 to 1.5 times the cone radius with increasing OCR, while the plastic radius is about 11 times the piezocone radius, regardless of the OCR. The equation developed in this study based on the modified Cam clay model and the cylindrical cavity expansion theory, which take into consideration the effects of the strain rate and stress anisotropy, provide a good prediction of the initial porewater pressure at the piezocone location. The method of predicting the spatial distribution of excess porewater pressure proposed in this study is based on a linearly increasing ${\Delta}u_{shear}$. In the shear zone and a logarithmically decreasing ${\Delta}u_{oct}$, and is verified by comparing with the excess porewater pressure measured in overconsolidated specimens at the calibration chamber.

• 한국소음진동공학회논문집
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• 제19권10호
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• pp.1075-1082
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• 2009

Using GIS data of C-si as basic data when making noise map of road traffic, we estimated exactly the noise excess areas and consequently suggested the population and the area exposed to road traffic noise accurately. We made 3D noise map to assess regional distribution of noise quantitatively. The noise map consists of noise prediction model based on data base such as traffic volume and speed changes for estimating quantitatively the noise and 3D urban space model which includes locations of noise sources, 3D buildings, topography and roads. We made noise standard map according to land use conditions and compared this map to road traffic noise map, and consequently made excess noise map. Using excess noise map, we assessed areas which exceed environmental noise level standards and noise guidelines quantitatively and effectively through GIS spatial analysis, and consequently more accurate noise exposed area and noise exposed population could be estimated. To show buildings' outer walls noise exposure, we analyzed 3D urban noise distributions using 3D-analysis of GIS.

• 한국농공학회논문집
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• 제52권2호
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• pp.1-9
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• 2010

This study was carried out to comparison of coefficient of consolidation and the prediction of excess pore water pressure in agricultural reservoir on soft clay ground. For the purpose of verification of the proposed equation, laboratory model tests and field tests were performed and excess pore water pressure was compared to those predicted with the Terzaghi's method. The predicted excess pore water pressure according to ponding was very applicable to practice because it was close to the observed data. Also, for the comparison of coefficient of consolidation, the oedometer, constant rate of strain (CRS), and Rowe cell tests were performed. The coefficient of consolidation at the Rowe cell and CRS tests showed a greate increase than in the oedometer test. The ratio of the vertical and horizontal coefficient of consolidation showed a large difference according to various tests method and mixing ratio. Therefore, it is recommended that careful attention should be paid to predicting the required consolidation period in agricultural reservoir.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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• pp.570-573
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• 2002

Pb(Zr0.52Ti0.48)O3 (PZT) thin films were deposited on the Pt/Ti bottom electrode by rf magnetron sputtering method from target containing 5%, 25% and 50% Pb excess for applying ferroelectric random access memory (FRAM). PZT films were deposited at $300^{\circ}C$ and then they were crystallized by rapid thermal annealing (RTA) at $700^{\circ}C$. After RTA treatment, our results showed that all PZT films indicated perovskite polycrystalline structure with preferred orientation (110) and no pyrochlore phase was observed by X-ray diffraction (XRD) and by Scanning electron microscopy (SEM). A well-fabricated PZT film of excess Pb 25% capacitor showed a leakage current density in the order of $2.63{\times}10^{-7}A/cm^2$ at 100kV/cm, a remanent polarization of $3.385{\mu}C/cm^2$ and a coercive field of 41.32 kV/cm. The results showed that Pb excess of target affects to electrical properties of PZT thin film.

• 대한기계학회논문집B
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• 제31권6호
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• pp.539-546
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• 2007

An experimental study was performed to investigate the characteristics of chemiluminescence in a radiant burner, varying the excess air ratio from 0.91 to 1.67 at firing rate 80.5 to 134.2 kW/m2 on $OH^*,\;CH^*,\;{C_2}^*$ in LNG-Air premixed flames. The signals from electronically excited states of $OH^*,\;CH^*,\;{C_2}^*$ were detected using a Intensified Couple Charged Detector (ICCD) camera. The measurements of exhausted emission were made to investigate the correlation between chemiluminescence and emissions. The chemiluminescence intensity was increased with increase of firing rate like characteristics of $NO_x$ emission. $NO_x$ also increased with increase of firing rate and excess air ratio. It is found that offset of firing rate is more dominant excess air ratio $NO_x$ emission. The maximum chemiluminescence intensity occurs near the stoichiometric excess air ratio or lean conditions in case of high firing rate and the maximum intensity occurs rather than rich conditions in case of relatively low firing rate. Amount of $NO_x$ emission is maximum at near stoichiometric excess air ratio, which is chemiluminescence intensity is maximum.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2008년도 춘계학술대회논문집
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• pp.409-412
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• 2008

This paper presents the effects of excess air factors(0.84${\sim}$0.90) and opened throttle area ratios(AR=0.15${\sim}$0.25) on the emission and performance of a small spark-ignition gasoline engine. The engine used in this paper was a single cylinder, diaphragm carburetor, two-stroke, air-cooled 26cc engine for brush cutter. The rpm, torque, fuel consumption and CO emission were measured under the four different excess air factors and three different opened area ratios conditions on the engine loads respectively. The results showed that the rpm was decreased and torque was increased at increasing load, the maximum power and minimum fuel consumption could be obtained critical rpm on each throttle opened area ratios and brake specific fuel consumption was decreased 13${\sim}$17%, CO emissions was decreased 21${\sim}$38% at excess air factor 0.90 than 0.84.