• Bulletin of the Korean Chemical Society
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• v.33 no.5
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• pp.1686-1692
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• 2012

Densities (${\rho}$), Viscosities (${\eta}$) and ultrasonic speeds (u) of pure acetophenone (AP), propiophenone (PP), $p$-methyl acetophenone ($p$-MeAP), $p$-chloroacetophenone ($p$-ClAP) and those of their binary mixtures with $N$-ethyl aniline ($N$-EA) as a common component, were measured at 303.15 K over the entire composition range. These experimental data were used to calculate the excess volume $V^E$, deviation in ultrasonic speeds ${\Delta}u$, isentropic compressibility $K_s$, intermolecular free length $L_f$, acoustic impedance Z, deviations in isentropic compressibility ${\Delta}K_s$, deviation in viscosity ${\Delta}{\eta}$ and excess Gibbs free energy of activation of viscous flow ($G^{*E}$) at all mole fractions of $N$-ethyl aniline. These parameters, especially excess functions, are found to be quite sensitive towards the intermolecular interactions between component molecules. Theoretical values of viscosity of the binary mixtures were calculated using different empirical relations and theories. The relative merits of these relations and theories were discussed. The experimental results were correlated by using the polynomial proposed by Redlich-Kister equation.

• The Bulletin of The Korean Astronomical Society
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• v.40 no.1
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• pp.48.2-48.2
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• 2015

van Dokkum and Conroy revisited the strong Na I lines at $8200{\AA}$ found in some giant elliptical galaxies and interpreted it as evidence for bottom-heavy initial mass function. Jeong et al. later found a lot of galaxies showing strong Na D doublet absorption line at $5900{\AA}$ (Na D excess objects; a.k.a. NEOs) and showed that their origins can be different for different types of galaxies. While the excess in Na D seems related with interstellar medium in late-type galaxies, smooth-looking early-type NEOs suggest no compelling sign of ISM contributions. To test this finding, we measured doppler shift in the Na D line. We hypothesized that ISM is more likely to show blueshift due to outflow caused by either star formation or AGN activities. In order to measure the doppler shift, we tried both Gaussian and Voigt functions to fit each galaxy spectrum near the Na D line. We found that Voigt profiles reproduce the shapes of the Na D lines markedly better. Many of late-type NEOs clearly show blueshift in their Na D lines, which is consistent with the former interpretation that the Na D excess found in them is related with star formation-caused gas outflow. On the contrary, early-type NEOs do not show any notable doppler component, which is also consistent with the interpretation of Jeong et al. that the Na D excess in early-type NEOs is likely not related with ISM activities but purely stellar in origin.

• Journal of the Korean Institute of Telematics and Electronics T
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• v.36T no.3
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• pp.7-12
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• 1999

In this paper, dielectric and strain properties of (1-f-y)PMN-yPT-xST ceramics investigated with the amount of $\textrm{SrTiO}^3$(ST). The $\textrm{SrTiO}^3$ content is ranged within 1~6㏖%. Another compositions with excess MgO also investigated. As the amount of ST is increased, dielectric constant has a maximum value at 5㏖% composition. The Curie temperature is decreased linearly with increasing the amount of ST. Coercive field and ramnant polarization has a maximum value at l㏖% composition. As for the effects of excess MgO, the dielectric constant has been increased by the addition of excess MgO up to 3㏖% to a 0.8PMN-0.12PT-0.04ST specimen. But the strain has been decreased by the addition of excess MgO.

• Journal of the Korean Chemical Society
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• v.29 no.4
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• pp.341-347
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• 1985

Formation of metal complex is the first step in the many biological actions of metal ions present in the biological systems. In this work the not electron affinity necessary for the formation of such metal complexes has been determined for a series of metal ions. It has been found that excess polarizing strength can be adopted as a measure of electron affinity and trend is the excess polarizing strength is related to Irving-Williams series. Those metal ions having greater than 0.22 in value of excess polarizing strength have been found to show carcinogenicity and other metal ions, which are supposed to be carcinogenic, have shows to have greater than 0. 22 in value of excess polarizing strength, demonstrating that excess polarizing strength could be used to determine if any metal ion possesses carcinogenic activity.

• Proceedings of the Korean Geotechical Society Conference
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• 2006.10a
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• pp.312-333
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• 2006

This paper presents the results of an analysis of the excess porewater pressure distribution due to piezocone penetration in overconsolidated clays. From piezocone test results for moderately and heavily overconsolidated clays, it was observed that the excess porewater pressure increases monotonically from the piezocone surface to the outer boundary of the shear zone and then decreases logarithmically to the outer boundary of the plastic zone. It was also found that the size of the shear zone decreases from approximately 2.2 to 1.5 times the cone radius with increasing OCR, while the plastic radius is about 11 times the piezocone radius, regardless of the OCR. The equation developed in this study based on the modified Cam clay model and the cylindrical cavity expansion theory, which take into consideration the effects of the strain rate and stress anisotropy, provide a good prediction of the initial porewater pressure at the piezocone location. The method of predicting the spatial distribution of excess porewater pressure proposed in this study is based on a linearly increasing ${\Delta}u_{shear}$. In the shear zone and a logarithmically decreasing ${\Delta}u_{oct}$, and is verified by comparing with the excess porewater pressure measured in overconsolidated specimens at the calibration chamber.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.19 no.10
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• pp.1075-1082
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• 2009

Using GIS data of C-si as basic data when making noise map of road traffic, we estimated exactly the noise excess areas and consequently suggested the population and the area exposed to road traffic noise accurately. We made 3D noise map to assess regional distribution of noise quantitatively. The noise map consists of noise prediction model based on data base such as traffic volume and speed changes for estimating quantitatively the noise and 3D urban space model which includes locations of noise sources, 3D buildings, topography and roads. We made noise standard map according to land use conditions and compared this map to road traffic noise map, and consequently made excess noise map. Using excess noise map, we assessed areas which exceed environmental noise level standards and noise guidelines quantitatively and effectively through GIS spatial analysis, and consequently more accurate noise exposed area and noise exposed population could be estimated. To show buildings' outer walls noise exposure, we analyzed 3D urban noise distributions using 3D-analysis of GIS.

• Journal of The Korean Society of Agricultural Engineers
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• v.52 no.2
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• pp.1-9
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• 2010

This study was carried out to comparison of coefficient of consolidation and the prediction of excess pore water pressure in agricultural reservoir on soft clay ground. For the purpose of verification of the proposed equation, laboratory model tests and field tests were performed and excess pore water pressure was compared to those predicted with the Terzaghi's method. The predicted excess pore water pressure according to ponding was very applicable to practice because it was close to the observed data. Also, for the comparison of coefficient of consolidation, the oedometer, constant rate of strain (CRS), and Rowe cell tests were performed. The coefficient of consolidation at the Rowe cell and CRS tests showed a greate increase than in the oedometer test. The ratio of the vertical and horizontal coefficient of consolidation showed a large difference according to various tests method and mixing ratio. Therefore, it is recommended that careful attention should be paid to predicting the required consolidation period in agricultural reservoir.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07b
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• pp.570-573
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• 2002

Pb(Zr0.52Ti0.48)O3 (PZT) thin films were deposited on the Pt/Ti bottom electrode by rf magnetron sputtering method from target containing 5%, 25% and 50% Pb excess for applying ferroelectric random access memory (FRAM). PZT films were deposited at $300^{\circ}C$ and then they were crystallized by rapid thermal annealing (RTA) at $700^{\circ}C$. After RTA treatment, our results showed that all PZT films indicated perovskite polycrystalline structure with preferred orientation (110) and no pyrochlore phase was observed by X-ray diffraction (XRD) and by Scanning electron microscopy (SEM). A well-fabricated PZT film of excess Pb 25% capacitor showed a leakage current density in the order of $2.63{\times}10^{-7}A/cm^2$ at 100kV/cm, a remanent polarization of $3.385{\mu}C/cm^2$ and a coercive field of 41.32 kV/cm. The results showed that Pb excess of target affects to electrical properties of PZT thin film.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.31 no.6 s.261
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• pp.539-546
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• 2007

An experimental study was performed to investigate the characteristics of chemiluminescence in a radiant burner, varying the excess air ratio from 0.91 to 1.67 at firing rate 80.5 to 134.2 kW/m2 on $OH^*,\;CH^*,\;{C_2}^*$ in LNG-Air premixed flames. The signals from electronically excited states of $OH^*,\;CH^*,\;{C_2}^*$ were detected using a Intensified Couple Charged Detector (ICCD) camera. The measurements of exhausted emission were made to investigate the correlation between chemiluminescence and emissions. The chemiluminescence intensity was increased with increase of firing rate like characteristics of $NO_x$ emission. $NO_x$ also increased with increase of firing rate and excess air ratio. It is found that offset of firing rate is more dominant excess air ratio $NO_x$ emission. The maximum chemiluminescence intensity occurs near the stoichiometric excess air ratio or lean conditions in case of high firing rate and the maximum intensity occurs rather than rich conditions in case of relatively low firing rate. Amount of $NO_x$ emission is maximum at near stoichiometric excess air ratio, which is chemiluminescence intensity is maximum.

• 한국전산유체공학회:학술대회논문집
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• 2008.03b
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• pp.409-412
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• 2008

This paper presents the effects of excess air factors(0.84${\sim}$0.90) and opened throttle area ratios(AR=0.15${\sim}$0.25) on the emission and performance of a small spark-ignition gasoline engine. The engine used in this paper was a single cylinder, diaphragm carburetor, two-stroke, air-cooled 26cc engine for brush cutter. The rpm, torque, fuel consumption and CO emission were measured under the four different excess air factors and three different opened area ratios conditions on the engine loads respectively. The results showed that the rpm was decreased and torque was increased at increasing load, the maximum power and minimum fuel consumption could be obtained critical rpm on each throttle opened area ratios and brake specific fuel consumption was decreased 13${\sim}$17%, CO emissions was decreased 21${\sim}$38% at excess air factor 0.90 than 0.84.