• 제목/요약/키워드: evolution heat

검색결과 380건 처리시간 0.028초

개질 처리된 저발열 슬래그시멘트 특성에 관한 연구 (The research about properties of modified low heat slag cement)

  • 김홍주;김원기;김훈상;이원준;신진호
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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    • pp.677-680
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    • 2008
  • 저발열형 고로슬래그 시멘트의 초기강도 발현 특성을 향상시키기 위하여 낮은 분말도의 고로슬래그 분말과 보통 포틀랜드시멘트를 혼합 분쇄하여 입자 표면을 개질하였다. 사전 분쇄한 고로슬래그 분말의 비표면적은 $2535cm^2/g$(BS2), $3245cm^2/g$(BS3)의 2가지를 사용하였으며, 고로슬래그 분말과 시멘트를 진동밀에 투입하여 10분부터 30분까지 혼합 분쇄하여 표면을 개질하였다. 시멘트에 대한 고로슬래그 분말의 혼합비는 60$^{\sim}$80%의 3수준으로 변화시켰으며 혼합분쇄 후 비표면적의 변화, 입도분표, 시멘트의 수화열, 몰탈의 압축강도를 측정하였다. 시판 삼성분계 저발열 시멘트(LHC)와 비교시험 결과, 7일 압축강도발현의 100%이상과 72시간 누적수화열 170J/g 이하의 값을 만족하는 배합 및 혼합분쇄 시간을 찾을 수 있었으며 저분말도 고로슬래그를 다량으로 활용한 저발열 슬래그시멘트의 가능성을 확인하였다.

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Ti-6Al-4V 합금의 형상 링 압연공정 설계 및 제조기술 (Design and Manufacturing processes of Ti-6Al-4V profiled ring-products)

  • 김국주;김남용;이진모;염종택
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2009년도 추계학술대회 논문집
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    • pp.72-75
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    • 2009
  • Design and Manufacturing processes of Ti-6Al-4V profiled ring-products were investigated with three-dimensional FEM simulation and experimental analyses. FEM simulation for the ring-rolling process was used to calculate the state variables such as strain, strain rate and temperature. In the simulation results of strain and temperature distributions for a plane ring rolling process, the strain level at the surface area is higher than that at the mid-plane, but the temperature level at the surface area is lower than that at mid-plane due to heat transfer between the workpiece and the work roll. These distributions showed a great influence on the evolution of microstructure in different positions. In order to induce the uniform deformation of the profile ring and reduce the applied load, the final blank was prepared by two-step processes. The mechanical properties of Ti-6Al-4V alloy ring products made in this work were investigated with tensile and impact tests and analyzed with the evolution of microstructures during the ring rolling process.

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내열합금 구조품에서의 국부적 소성변형과 이중후방응력 경화 모델 (Localized Plastic Deformation in Heat-Resistant Alloy and Combined Two-Back Stress Hardening Model)

  • 윤수진;이상연;박동창;윤현걸
    • 한국추진공학회지
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    • 제15권5호
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    • pp.82-88
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    • 2011
  • 본 논문에서는 유한요소해석을 통해 연소시험 과정 중 발생한 내열 구조품의 파단현상이 분석되었다. 구조 불안정성은 소성변형으로 인한 것으로 이는 급격한 열하중의 변화에서 비롯된 것이다. 한편 소성변형 국부화 현상을 이해하기 위해 구성방정식에 연속체 파손변수가 포함되었으며 또한 Armstrong-Frederick과 Phillips 경화식을 이용, 이중후방응력 구성방정식이 제안되었다. 따라서 본 모델은 광범위한 소성변형거동을 해석할 수 있는 토대를 마련하였다. 수치해석을 통해 소성변형 집중 현상은 지배적인 후방응력의 전개에 의존하는 것으로 나타났다. 또한 물체 내에서의 파손 현상은 소성변형 집중을 가속화하는 것으로 밝혀졌다.

MICROSTRUCTURAL CHARACTERISTICS OF HOT FORGED AL 6061 ALLOY

  • Kwon Y.-N.;Lee Y.-S.;Lee J.-H.
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2003년도 The 8th Asian Symposium on Precision Forging ASPF
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    • pp.55-58
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    • 2003
  • Many researches have been already done on the issues of high temperature deformation and the microstructural evolution. The information has been very useful for the plasticity industry, especially successful for the extrusion. However, the parts made with forging usually have a complex shape. It is difficult to control the distribution of the variables like strain, strain rate and temperature rise due to the working heat during a hot-forging process. Consequently, the microstructural variation could be occurred depending on the plastic deformation history that the forged part would get during a hot forging. In the present study, the microstructural characteristic of a hot-forged 6061 aluminum alloy has been discussed on the aspect of grain size evolution. A forging of 6061 aluminum alloy has been carried out for a complex shape with a dimensional variation. Also, finite element analysis has been done to understand how the deformation variables such as strain, strain rate give an influence on the microstructure of a hot forged aluminum product.

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냉각판법에 의한 Mg-10Al-Mn 합금의 균질화 처리에 따른 미세조직 변화 (The Microstructural Evolution of Mg-10Al-Mn Alloy by Cooling Plate During Homogenization Treatment)

  • 김대환;최승화;김희경;심성용;임수근
    • 한국주조공학회지
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    • 제30권6호
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    • pp.235-240
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    • 2010
  • The evolution of microstructure and phases of Mg-10Al-Mn alloy by cooling plate method during homogenization treatment have been investigated with metallographic analysis, scanning electron microscopy and energy dispersive spectroscopy. The ingots used for this experiment were prepared by cooling plate and homogenization heat treatment was performed at 300 and $400^{\circ}C$ for various holding times (0, 1, 4, 8 and 12h). The casting ingots were consisted of the fine grains and eutectic phases. And, these eutectic phases were dissolved into the matrix during homogenization treatment at $400^{\circ}C$ but the lower temperature (at $300^{\circ}C$) did not be.

삼중수소 저장을 위한 ZrCo 저장재에서의 수소 흡장에 대한 수치해석적 연구 (I) (A Numerical Investigation of Hydrogen Absorption Reaction Based on ZrCo for Tritium Storage (I))

  • 유하늘;윤세훈;장민호;강현구;주현철
    • 한국수소및신에너지학회논문집
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    • 제23권5호
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    • pp.448-454
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    • 2012
  • In this paper, a three-dimensional hydrogen absorption model is applied to a thin double-layered annulus ZrCo hydride bed and validated against the temperature evolution data measured by Kang et al. The present model reasonably captures the bed temperature evolution behavior and the 99% hydrogen charging time. The equilibrium pressure expression for hydrogen absorption on ZrCo is derived as a function of temperature and the H/M atomic ratio based on the pressure-composition isotherm data given by Konishi et al. In addition, this present model provides multi-dimensional contours such as temperature and H/M atomic ratio in the thin doublelayered annulus metal hydride region. This numerical study provides fundamental understanding during hydrogen absorption process and indicates that efficient design of the metal hydride bed is critical to achieve rapid hydrogen charging performance. The present three-dimensional hydrogen absorption model is a useful tool for the optimization of bed design and operating conditions.

아연공기이차전지용 La1-xSrxCoO3 양극촉매의 제조 및 이를 적용한 양극의 전기화학적 특성연구 (Synthesis and Electrochemical Evaluation of La1-xSrxCoO3 Cathode Material for Zinc Air Secondary Batteries Application)

  • 엄승욱;선양국
    • 한국전기전자재료학회논문지
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    • 제21권5호
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    • pp.447-452
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    • 2008
  • We synthesized nano-sized $La_{1-x}Sr_xCoO_3$ ($x=0.1{\sim}0.4$) cathode catalyst for the zinc air secondary batteries by citrate method, And we measured the cathode's electrochemical characteristics according to content of strontium compose the cathode catalyst. We controlled the pH of precursor solution by 10 in the process of manufacturing the precursor, We heat treated the prepared precursor at various calcination temperature ($500{\sim}900^{\circ}C$), and examined the optimum calcinations temperature by XRD analysis and electrochemical evaluation. We examined the ORR (oxygen reduction reaction) and OER (oxygen evolution reaction) performance of the prepared $La_{1-x}Sr_xCoO_3$ catalyst powder. When we consider ORR and OER performance simultaneously, $La_{0.7}Sr_{0.3}CoO_3$ catalyst has shown the best performance because of its lowest voltage deference between charge and discharge.

CHARACTERISTICS OF FIRE PROTECTIVE COATING THE TERNARY SOLUBLE SILICATE

  • Lee, Nae-Woo;Choi, Jae-Wook;Kim, Jeong-Hun
    • 한국화재소방학회:학술대회논문집
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    • 한국화재소방학회 1997년도 International Symposium on Fire Science and Technology
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    • pp.120-129
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    • 1997
  • The fire protective coating can reduce certain damages in case of fire, also conserve energy by thermal insulation and prevent corrosion and errosion in normal daily life by means of blocking thermal transfer, that were generally made of organic, inorganic and metallic materials as adiabatic coating. In case of inorganic material such as soluble silicate, it produces less toxic substances which are exposed to Ore, and have a plenty of raw material. Also inorganic thermal insulator is good in heat resistance. To develope such a excellent inorganic thermal insulator, the study of fire protective coating using the alkali silicate is necessary The principle of intumescence for alkali silicate is from rapid evolution of water in the coating material, the quantity of water in it is of course influenced on the degree of intumescence. The phenomenon of intumescence in ternary silicate is increased as the radius of ion is bigger, and this is caused by evolution of so many kinds of water. The individual degree of intumescence is ordered like this ; $K^+$ > $Na^+$ > $Li^+$ . The best protection effect is similarity found to intumescence of ternary silicate. The result of X-ray diffraction analysis indicates that $KHSi_2O_5$ is an important ingredient in K-silicate.

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내열합금 구조품에서의 국부적 소성변형과 이중후방응력 경화 모델 (Localized Plastic Deformation in Heat-Resistant Alloy and Combined Two-Back Stress Hardening Model)

  • 윤수진;이상연;박동창;윤현걸
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2011년도 제36회 춘계학술대회논문집
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    • pp.272-278
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    • 2011
  • 본 논문에서는 유한요소해석을 통해 연소시험 과정 중 발생한 내열 구조품의 파단현상이 분석되었다. 구조 불안정성은 소성변형으로 인한 것으로 이는 급격한 열하중의 변화에서 비롯된 것이다. 한편 소성변형 국부화 현상을 이해하기 위해 Armstrong-Frederick과 Phillips 경화식을 이용, 이중후방응력 구성방정식이 제안되었으며, 또한 본 모델은 연속체 파손역학과 조합되었으며 광범위한 소성변형거동을 보일 수 있다. 수치해석을 통해 소성변형 집중 현상은 지배적인 후방응력의 전개에 의존하는 것으로 나타났다. 또한 물체 내에서의 파손 현상은 소성변형 집중을 가속화하는 것으로 밝혀졌다.

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Effect of temperature and blank holder force on non-isothermal stamp forming of a self-reinforced composite

  • Kalyanasundaram, Shankar;Venkatesan, Sudharshan
    • Advances in aircraft and spacecraft science
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    • 제3권1호
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    • pp.29-43
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    • 2016
  • Composite materials are rapidly gaining popularity as an alternative to metals for structural and load bearing applications in the aerospace, automotive, alternate energy and consumer industries. With the advent of thermoplastic composites and advances in recycling technologies, fully recyclable composites are gaining ground over traditional thermoset composites. Stamp forming as an alternative processing technique for sheet products has proven to be effective in allowing the fast manufacturing rates required for mass production of components. This study investigates the feasibility of using the stamp forming technique for the processing of thermoplastic, recyclable composite materials. The material system used in this study is a self-reinforced polypropylene composite material (Curv$^{(R)}$). The investigation includes a detailed experimental study based on strain measurements using a non-contact optical measurement system in conjunction with stamping equipment to record and measure the formability of the thermoplastic composites in real time. A Design of Experiments (DOE) methodology was adopted to elucidate the effect of process parameters that included blank holder force, pre heat temperature and feed rate on stamp forming. DOE analyses indicate that feed rate had negligible influence on the strain evolution during stamp forming and blank holder force and preheat temperature had significant effect on strain evolution during forming.