• Title/Summary/Keyword: evolution heat

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A Numerical Analysis of Growth of Non-spherical Silica Particles in a Premixed Flat Flame (예혼합 평면화염에서 비구형 실리카 입자의 성장에 관한 수치해석적 연구)

  • Oh, Se-Baek;Lee, Bang-Weon;Choi, Man-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.10
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    • pp.1351-1358
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    • 2000
  • Two dimensional aerosol dynamics considering the effects of particle generation, coagulation, thermophoresis, sintering and convection has been studied to obtain the growth of non-spherical silica particles in conjunction with determining flame temperature by performing combustion analysis of premixed flat flame. Heat and mass transfer analysis includes 16 species, 29 chemical reaction steps together with oxidation and hydrolysis of SiCl4. The effect of radiation heat loss has also been included. The predictions of flame temperatures and the evolution of particle size distributions were in a reasonable agreement with the existing experimental data.

Microstructure and Mechanical Properties of AZ91 Magnesium Alloy Containing a Small Amount of Sn (미량 Sn을 함유한 AZ91 마그네슘 합금의 미세조직 및 기계적 특성)

  • Jun, Joong-Hwan
    • Journal of the Korean Society for Heat Treatment
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    • v.27 no.3
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    • pp.115-120
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    • 2014
  • Microstructural features were comparatively investigated in AZ91 (Mg-9%Al-1%Zn) and AZ91-0.5%Sn alloys, in order to clarify the reason for the enhancement in room temperature tensile properties by the addition of small amount of Sn in Mg-Al-based alloy. In as-cast state, the Sn-containing alloy showed increased YS, UTS and elongation than the Sn-free alloy. The microstructural examination revealed that various factors including finer cell size, reduction of lamellar (${\alpha}+{\beta}$) phase and morphological change of bulky ${\beta}$ phase from partially divorced shape to fully divorced shape, are likely to be responsible for the improvement in tensile properties for the Sn-containing alloy. It is noted that two alloys showed similar tensile properties after solution treatment. This implies that microstructural evolution related to the ${\beta}$ phase plays a key role in better tensile properties in the Sn-containing alloy.

Energy and Mass Balance of Snowpack - Rapid snowmelt during Fohn events in the Takada plain -

  • ;Shinichi Takami
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.32 no.E
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    • pp.88-94
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    • 1990
  • Several models physically based to predict the evolution of the snowpack have been proposed. Validity of these models for hourly estimation is, however, questionable, since they have been tested only on a daily basis. A computational model to predict the amount of snowpack on an hourly basis in terms of snowload from a set of meterological measurements was developed and investigated the rapid snowmelt conditions during Fohn events in the Takada plain.

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THE PERFORMANCE OF CLAY BARRIERS IN REPOSITORIES FOR HIGH-LEVEL RADIOACTIVE WASTE

  • Pusch, Roland
    • Nuclear Engineering and Technology
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    • v.38 no.6
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    • pp.483-488
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    • 2006
  • Highly radioactive waste is placed in metal canisters embedded in dense clay termed buffer. The radioactive decay is associated with heat production, which causes degradation of the buffer and thereby time-dependent loss of its waste-isolating potential. The buffer is prepared by compacting air-dry smectite clay powder and is initially not fully water saturated. The evolution of the buffer starts with slow wetting by uptake of water from the surrounding rock followed by a long period of exposure to heat, pressure from the rock and chemical reactants. It can be described by conceptual and theoretical models describing processes related to temperature (T), hydraulic (H), mechanical (M) and chemical performance (C). For temperatures below 90 C more than 75 % of the smectite will be preserved for 100 000 years but cementation may reduce the excellent performance of the buffer to a yet not known extention.

Microstructural Observation of Cu/Cr Multilayers by Heat Treatment (열처리에 따른 Cu/Cr 다층 박막의 미세 조직 관찰)

  • 양혁수;김기범
    • Journal of the Korean institute of surface engineering
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    • v.28 no.6
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    • pp.376-385
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    • 1995
  • Copper-chromium multilayers with a nominal bilayer thickness of about 400 $\AA$ (200 $\AA$ each) were prepared by dc magnetron sputtering and the evolution of microstructure during heat treatment was investigated by using x-ray diffractometry(XRD), Auger electron spectroscopy(AES) and transmission electron microscopy(TEM). It was observed that an amorphous phase with a thickness of about 40 $\AA$ was formed at the interfaces of the as-deposited Cu/Cr multilayered film using cross-sectional TEM. At elevated temperatures, the Cu(111) reflection showed increasing intensity and decreasing line-width as a result of copper grain growth. The intermixed amorphous phase disappeared after annealing at $250^{\circ}C$ for 1 h and the multilayer structure was stable up to $400^{\circ}C$ for 1 h annealing. At $600^{\circ}C$ annealing, it was observed that the multilayer structure was completely destroyed and copper and chromium phases were fully intermixed.

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Modeling of temperature history in the hardening of ultra-high-performance concrete

  • Wang, Xiao-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.3
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    • pp.273-284
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    • 2014
  • Ultra-high-performance concrete (UHPC) consists of cement, silica fume (SF), sand, fibers, water and superplasticizer. Typical water/binder ratios are 0.15 to 0.20 with 20 to 30% silica fume. In the production of ultra-high performance concrete, a significant temperature rise at an early age can be observed because of the higher cement content per unit mass of concrete. In this paper, by considering the production of calcium hydroxide in cement hydration and its consumption in the pozzolanic reaction, a numerical model is proposed to simulate the hydration of ultra-high performance concrete. The heat evolution rate of UHPC is determined from the contributions of cement hydration and the pozzolanic reaction. Furthermore, by combining a blended-cement hydration model with the finite-element method, the temperature history in the hardening of UHPC is evaluated using the degree of hydration of the cement and the silica fume. The predicted temperature-history curves were compared with experimental data, and a good correlation was found.

The Effects of the Heavy Metal Ions on the Hydration and Microstructure of the Cement Paste (중금속이온이 시멘트의 수화 및 미세구조에 미치는 영향)

  • 김창은;이승규
    • Journal of the Korean Ceramic Society
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    • v.30 no.11
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    • pp.967-973
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    • 1993
  • The effect on the hydration of cement was that Cu and Pb reacted with alkali to form soluble hydrates at theinitial stage and then there followed a slow reaction forming insoluble metal hydroxides. These hydroxides were deposited on the surface of cement particles providing a barrier against further hydration. But as a slow reaction continued, the insoluble layers were eventually destroyed and the hydration reaction resumed. Thereafter, another retardation occured by restricting the polymerization of silicates, shown by FT-IR spectroscopy analysis. In the case of Cr, as its reaction with cement caused H2O, the coordinator of Cr complex, to replace or polymerize with OH-, the formation of Cr complex promoted the leakage of OH- and increased the heat of dissolution. So the total heat evolution during hydration was larger than that in the case of Pb or Cu. The retarding effect of heavy metal ions was in the order Pb>Cu>Cr.

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$ZrO_2$ Ceramic Fiber Fabrication by Sol-Gel Processing (Sol-Gel법에 의한$ZrO_2$ Ceramic Fiber 제조)

  • ;;W.C. LaCourse
    • Journal of the Korean Ceramic Society
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    • v.27 no.6
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    • pp.824-828
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    • 1990
  • Zirconia gel fibers were fabricated by sol-gel processing using zirconium alkoxides and 2, 4-pentanedione. Their phase transformation and microstructural evolution were studied after heat treatments up to 150$0^{\circ}C$. Tetragonal ZrO2 began to form at 50$0^{\circ}C$ and followed by monoclinic, tetragonal phase during subsequent heat treatments at 1000, 150$0^{\circ}C$ for 1hour respectively. During cooling from 150$0^{\circ}C$, cracks were created, propagated along grain boundaries due to the volume change from tetragonal to monoclinic transformation.

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The synthesis of $Nb_3Sn$ alloy powders by mechanical alloying (기계적 합금화 방법에 의한 $Nb_3Sn$합금 제조)

  • Lee, Sung-Man
    • Proceedings of the KIEE Conference
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    • 1996.11a
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    • pp.464-467
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    • 1996
  • The microstructural evolution during mechanical alloying of Nb and Sn powders, of average composition Nb3Sn, has been investigated by X-ray diffraction(XRD) and scanning electron microscopy(SEM). Observations by SEM showed a progressive change of milling time. From the XRD studies, the structural development with milling time depends on the ball size for a given powder/ball ratio. Using a larger ball of 9.5mm diameter, the elemental powders initially alloy mechanically to form an A15 structure phase, and then amorphised with continued milling. However, in case of milling with a smaller ball of 3.968mm diameter, an amorphous phase is first formed. These results can be understood by considering the dependence of the milling energy on the ball size. The homogeneous stoichiometric $Nb_3Sn$ phase could be easily obtained by heat treatment of a supersaturated solid solution produced by MA. Heat treatment of an amorphous phase formed by MA resulted in the mixture of the $Nb_3Sn$ and $Nb_6Sn_5$ phases.

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Characteristics on Temperature Evolution in the Metallic Specimen by Ultrasound-Excited Thermography

  • Choi, M.Y.;Park, J.H.;Kang, K.S.;Kim, W.T.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.3
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    • pp.200-206
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    • 2010
  • In ultrasound-excited thermography, the injected ultrasound to an object is transformed to heat and the appearance of defects can be visualized by thermography camera. The advantage of this technology is selectively sensitive to thermally active defects. Despite the apparent simplicity of the scheme, there are a number of experimental considerations that can complicate the implementation of ultrasound excitation thermography inspection. Factors including acoustic horn location, horn-crack proximity, horn-sample coupling, and effective detection range all significantly affect the detect ability of this technology. As conclusions, the influence of coupling pressures between ultrasound exciter and specimen was analyzed, which was dominant factor in frictional heating model.