• 제목/요약/키워드: eutectic

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일방향응고시킨 Al-Co 합금의 특성에 관한 연구 (Characteristics of the Unidirectionally Solidified Al-Co Alloy)

  • 박수정;전현용;이현규
    • 한국주조공학회지
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    • 제25권1호
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    • pp.30-35
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    • 2005
  • The structures and mechanical property of the unidirectionally solidified Al-Co eutectic alloy were investigated. Al-Co eutectic alloy was unidirectionally solidified with growth rates(R) between I cm/hr and 10 cm/hr in the induction furnace maintaining the thermal gradient (G) at solid-liquid interface, $32^{\circ}C$/cm. The eutectic microstructure was varied with the growth condition(G/R ratio). When the G/R ratio was larger than $8.5{\times}10^{3}^{\circ}C/cm^{2}/sec$, a lamellar structure was formed, But the G/R ratio was smaller than $8.5{\times}10^{3}^{\circ}C/cm^{2}/sec$, a colony structure was formed. It was found that the interlamellar spacing(${\lambda}$) was dependent on the growth rate(R) with the relationship, ${\lambda}^{2}{\cdot}R=constant$. The microhardness of this eutectic alloy increased with increase in the growth rate.

회주철 판형 주조품의 공정 셀 수와 칠 깊이에 미치는 두께, 기본 원소 및 접종제의 영향 (Effects of Thickness, Base Element and Inoculants on the Number of Eutectic Cells and Chill Depth of Gray Cast Iron Plate Casting)

  • 김태형;오정혁;권해욱
    • 한국주조공학회지
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    • 제31권3호
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    • pp.137-144
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    • 2011
  • The effects of thickness, base element and inoculants on the number of eutectic cells and chill depth of gray cast iron plate casting were investigated. Meanwhile the number of eutectic cells increased by inoculation, chill depth decreased. The former decreased and the latter increased by holding the melt at the temperature range between 1,450 and $1,500^{\circ}C$. The former was more for the thinner casting with the thickness of 5 mm than the other. The result of thermal analysis coincided well with the change of macrostructure. The former increased and the latter decreased with the increased contents of carbon, silicon and the silicon content by inoculation. The former decreased and the latter increased with increased manganese content. The performance of the Superseed Extra was the best among 5 inoculants.

Sr과 TiB 첨가에 따른 다이캐스팅용 Al-Si 합금의 미세조직과 공정온도의 변화 (Influence of Sr and TiB on the Microstructure and Eutectic Temperature of Al-12Si Die-Cast Alloys)

  • 최용락;김선화;김동현;윤상일;김기선
    • 한국재료학회지
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    • 제27권10호
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    • pp.544-551
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    • 2017
  • In order to develop a new commercial Al-12%Si casting alloy with improved physical properties, we investigated the effect of adding Sr and TiB to the alloy. Al-12%Si alloys were prepared by die casting at $660^{\circ}C$. The eutectic temperature of the Sr-modified Al-12%Si alloy decreased to $9^{\circ}C$ and the mushy zone region increased. The shape of the Si phase changed from coarse acicula to fine fiber with the addition of Sr. The addition of TiB in the Al-12%Si alloy reduced the size of the primary ${\alpha}$-Al and eutectic Si phases. When Sr and TiB were added together, it worked more effectively in refinement and modification. The density of twins in the Si phase-doped Sr increased and the width of the twins was refined to 5 nm. These results are related to the impurity induced twinning(IIT) growth.

AC4C 합금의 기계적 성질에 미치는 주조조건과 열처리의 영향에 관한 연구 (The Effect of Casting Condition and Heat Treatment on the Mechanical Properties of AC4C Alloy Castings)

  • 강효경;천병욱;최창옥
    • 한국주조공학회지
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    • 제13권5호
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    • pp.450-461
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    • 1993
  • AC4C alloy casts in the metallic mold, zircon sand mold, silica sand mold and shell mold with the pouring temperatures of 680, 710 and $740^{\circ}C$ have been investigated. The tensile strength, elongation and hardness of AC4C alloy castings have been influenced by the kind of molds used. The mechanical properties in zircon sand mold castings were greater than those in other sand mold castings, but were inferior to the properties in metallic mold castings. Eutectic Si particle size and DAS were increased in the order of metallic mold, ziron sand mold, silica sand mold and shell mold. Also, they were increased with the increase of pouring temperatures. DAS, eutectic Si particle size and grain size decreased with the increase of mechanical properties as the cooling rate increased. The eutectic Si particle size and DAS of AC4C alloy castings after T6 treatment were decreased in as-cast. The variation of eutectic Si particle size has been effected on the tensile strength, elongation and fractured surface.

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고크롬 백주철의 미세조직과 기계적 특성에 미치는 초기응고 조직의 영향 (Effect of Primarily Solidified Structure on the Microstructure and the Mechanical Properties of High Cr White Iron)

  • 조현욱;도정현;조원제;정현득;이재현;조창용
    • 한국주조공학회지
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    • 제35권6호
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    • pp.178-184
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    • 2015
  • Due to excellent abrasion resistance the high-chrome white irons are widely used in mining and mineral industries. Minor variation of carbon content in 28% chrome white iron resulted in difference in primarily solidified microstructure. Sub-eutectic (hypoeutectic) composition led to formation of primarily solidified dendrites. Formation of primarily solidified dendrites which were supersaturated with carbon and chrome also caused precipitation of fine secondary carbides that are different from relatively large plate type $M_7C_3$ carbides in the eutectic structure. Small portion of primarily solidified dendrite expected to contribute significantly to the improvement of abrasion resistance of the white iron because the dendrites provided mechanical support to carbides. The relative fraction of primary dendrite increased with reduction of carbon content from the eutectic composition. The increased fraction of primary dendrite increased hardness value of the white irons.

Al-10.5wt%Si-2wt%Cu 다이 캐스팅용 2차 지금의 미세조직에 미치는 Sr의 양과 유지시간의 영향 I (The Effect of Sr Addition and Holding Time on Microstructure of Al-10.5%Si-2%Cu Secondary Die-casting Alloys)

  • 신상수;김명용;염길용
    • 한국주조공학회지
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    • 제30권5호
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    • pp.161-166
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    • 2010
  • In this examination, the effect of Sr addition and holding time on microstructure of Al-10.5wt%Si-2wt%Cu secondary die-casting alloy was investigated. Degree of undercooling was improved with increasing the Sr content in this alloy. Up to 0.02wt%Sr addition, acicular and lamellar eutectic structure was observed in the microstructure. Meanwhile, the eutectic Si was modified toward the fine fibrous form by increasing Sr content with more than 0.03wt% and holding time of the melt. The well- modified alloys showed decreased eutectic silicon size from 3.25 ${\mu}m$ to less than 0.8 ${\mu}m$. From these results, the optimal strontium content and holding time were identified on the Al-10.5wt%Si-2wt%Cu secondary die-casting alloy.

Al2Ca를 함유한 A356 합금에서의 다양한 열처리 조건에 따른 공정 Si 개량화 거동 (Modification Behavior of Eutectic Si with Varying Heat Treatment Conditions in A356 Alloy with Al2Ca)

  • 김세준;현승균;김세광;윤영옥
    • 한국주조공학회지
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    • 제34권5호
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    • pp.156-161
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    • 2014
  • This study is focused on the effect of $Al_2Ca$ as a modifier on eutectic Si modification of A356 alloy. Microstructural observation was carried out for as-cast, as-solution treated and as-aged samples. Solution treatment and aging were performed for 2, 4, 6 and 10 hrs at $540^{\circ}C$ and $170^{\circ}C$, respectively. Although A356 alloy, which $Al_2Ca$ was added, has no significant difference in as-cast phases with normal A356 alloys, it shows much more modified eutectic Si, grain refinement and improved tensile property both in as-cast and as-heat treated conditions. TGA result shows that $Al_2Ca$ added A356 alloy has a certain improvement in oxidation resistance.

나노/마이크로 경도 측정에 의한 레오캐스트 A356 합금의 시효경화특성 평가 (Evaluation of Age-Hardening Characteristics of Rheo-Cast A356 Alloy by Nano/Micro Hardness Measurement)

  • 조상현;윤성원;강충길
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2005년도 춘계학술대회 논문집
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    • pp.471-474
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    • 2005
  • This study investigates the nano/microstructure, the aging response, and the mechanical/tribological properties of the eutectic regions in rheoformed A356 alloy-T5 parts using nano/micro-indentation and mechanical scratching, combined with optical microscopy and atomic force microscope (AFM). Most eutectic Si crystals in the A356 alloy showed a modified morphology as fine-fibers. The loading curve for the eutectic region was more irregular than that of the primary Al region due to the presence of various particles of varying strength. The aging responses of the eutectic regions in the rheoformed A356 alloys aged at $150^{\circ}C$ for different times (0, 2, 4, 8, 10, 16, 24, 36, and 72 h) were investigated. Both Victors hardness $(H_v)$ and indentation $(H_{IT})$ test results showed a similar trend of aging curves, and the peak was obtained at the same aging time of 10 h. A remarkable size-dependence of the tests was found.

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Probabilistic Estimation of LMR Fuel Cladding Performance Under Transient Conditions

  • Kwon, Hyoung-Mun;Lee, Dong-Uk;Lee, Byung-Oon;Kim, Young ll;Kim, Yong-Soo
    • Nuclear Engineering and Technology
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    • 제35권2호
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    • pp.144-153
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    • 2003
  • The object of this paper is the probabilistic failure analysis on the cladding performance of WPF(Whole Pin Furnace) test fuel pins under transient conditions, and analysis of the KALIMER fuel pin using the preceding analysis. The cumulative damage estimation and Weibull probability estimation of WPF test are performed. The probabilistic method was adapted for these analyses to determine the effective thickness thinning due to eutectic penetration depth. In the results, it is difficult to assume that a brittle layer depth made by eutectic reaction is all of the thickness reduction due to cladding thinning. About 93% cladding thinning of the eutectic penetration depth is favorable as an effective thickness of cladding. And the unreliability of the KALIMER driver fuel pin under the same WPF test condition is lower than that of the WPF pin because of the higher plenum-fuel volume ratio and lower cladding inner radius vs. thickness ratio. KALIMER fuel pin developed from conceptual design has a more stable transient performance for a failure mechanism due to fission gas buildup than the WPF pin.

공융 갈륨-인듐 액체금속 전극 기반 전기이중층 커패시터 (An Electric Double-Layer Capacitor Based on Eutectic Gallium-Indium Liquid Metal Electrodes)

  • 김지혜;구형준
    • 한국수소및신에너지학회논문집
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    • 제29권6호
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    • pp.627-634
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    • 2018
  • Gallium-based liquid metal, e.g., eutectic gallium-indium (EGaIn), is highly attractive as an electrode material for flexible and stretchable devices. On the liquid metal, oxide layer is spontaneously formed, which has a wide band-gap, and therefore is electrically insulating. In this paper, we fabricate a capacitor based on eutectic gallium-indium (EGaIn) liquid metal and investigate its cyclic voltammetry (CV) behavior. The EGaIn capacitor is composed of two EGaIn electrodes and electrolyte. CV curves reveal that the EGaIn capacitor shows the behavior of electric double-layer capacitors (EDLC), where the oxide layers on the EGaIn electrodes serves as the dielectric layer of EDLC. The oxide thicker than the spontaneously-formed native oxide decreases the capacitance of the EGaIn capacitor, due to increased voltage loss across the oxide layer. The EGaIn capacitor without oxide layer exhibits unstable CV curves during the repeated cycles, where self-repair characteristic of the oxide was observed. Finally, the electrolyte concentration is optimized by comparing the CV curves at various electrolyte concentrations.