• Title/Summary/Keyword: eutectic

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Density of Molten Salt Mixtures of Eutectic LiCl-KCl Containing UCl3, CeCl3, or LaCl3

  • Zhang, C.;Simpson, M.F.
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.15 no.2
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    • pp.117-124
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    • 2017
  • Densities of molten salt mixtures of eutectic LiCl-KCl with $UCl_3$, $CeCl_3$, or $LaCl_3$ at various concentrations (up to 13 wt%) were measured using a liquid surface displacement probe. Linear relationships between the mixture density and the concentration of the added salt were observed. For $LaCl_3$ and $CeCl_3$, the measured densities were significantly higher than those previously reported from Archimedes' method. In the case of $LiCl-KCl-UCl_3$, the data fit the ideal mixture density model very well. For the other salts, the measured densities exceeded the ideal model prediction by about 2%.

Damping Capacity of Heat-Treated Mg-Nd Alloy (열처리한 Mg-Nd 합금의 진동감쇠능)

  • Jun, Joong-Hwan
    • Journal of the Korean Society for Heat Treatment
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    • v.26 no.4
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    • pp.185-190
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    • 2013
  • Influence of solution treatment (T4) and peak-aging (T6) on damping capacity was investigated in permanent-mold cast Mg-3%Nd alloy. In as-cast state, the microstructure was characterized by eutectic $Mg_{12}Nd$ intermetallic phase network in the intergranular region. T4 treatment resulted in a dissolution of the eutectic particles, but small amount of the particles still remained in the microstructure. After T6 treatment, nano-sized ${\beta}^{\prime}(Mg_{12}Nd)$ particles were precipitated within the matrix. T4 microstructure showed higher damping capacity than as-cast and T6 ones. In view of the microstructural features, this may well be associated with the dissolution of second-phase particles which play a role in pinning the dislocations acting as a damping source.

Compatibility Study Using Differential Scanning Calorimetry (시차주사열량분석을 이용한 배합성 연구)

  • Sohn, Young-Taek;Lee, Aea-Kyoung
    • Journal of Pharmaceutical Investigation
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    • v.29 no.2
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    • pp.117-126
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    • 1999
  • Differential scanning calorimetry(DSC) was used as a screening technique for assessing the compatibility of some drugs with excipients. On the basis of DSC results, interaction of ibuprofen with PVP K40 was found and eutectic formations with PEG 6000 or magnesium stearate were demonstrated. Fenoprofen Ca was found to interact with PEG 6000. Naproxen showed interactions with PEG 6000, PVP K40, PVPP and Mg stearate. Interactions of tiaprofenic acid with PVP K40 or PVPP were found and eutectic formations with PEG 6000 or Mg stearate were observed. Bisoprolol hemifumarate, metoprolol tartrate and penbutolol sulfate were found to interact with lactose.

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The Effect of Cooling Rate on the Solidification Behavior and Segregation of 7075 and 7050 Aluminum Alloys (7075 및 7050 알루미늄 합금의 응고 거동 및 편석에 미치는 냉각 속도의 영향)

  • Choi, Jeong-Yun;Kwon, Young-Dong;Lee, Joo-Won;Lee, Zin-Hyoung
    • Journal of Korea Foundry Society
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    • v.21 no.6
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    • pp.343-349
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    • 2001
  • The effect of cooling rate on the solidification microstructure and segregation behavior of 7075 and 7050 aluminum alloy was investigated. Samples were solidified with cooling rates from 0.3 to $17^{\circ}K/sec$. Using the cooling curves of each sample, liquidus, eutectic and intermetallic reaction temperatures were estimated. The microstructures were characterized in terms of dendrite arm spacing and eutectic volume fraction. The segregation behavior of each alloying element of these alloys in various cooling rates was discussed.

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Characterization of Cu/cordierite Interfaces by STEM (STEM에 의한 구리와 코디에라이트 접촉면의 특성 연구)

  • Han, Byung-Sung
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.27 no.10
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    • pp.101-105
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    • 1990
  • The use of a sol-gel processed cordierite precursor sinterable about$900^{\circ}C$ allows cosintering of the copper and the ceramic. A strong bonding between the copper film and the cordierite substrate can be achieved through an eutectic bonding technique. These interfaces were investigated using STEM. copper diffusion as well as strong chemical and structural modifications was observed in the interface region. Although these interfaces have good adhesion properties, there was no evidence of the formation of the copper compound at the interface.

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Melting Phenomena of Compacted Vermicular Graphite Cast Iron (CV흑연주철의 용해현상에 관한 연구)

  • Lee, H.C.;Lim, C.H.;Ra, H.Y.
    • Journal of Korea Foundry Society
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    • v.7 no.3
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    • pp.184-191
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    • 1987
  • In this study the principles of melting phenomena of compacted vermicular graphite cast iron are discussed by considering the effects of the variation of phosphorus content and heating rate on the quenched microstructure of the specimens. In compacted vermicular graphite cast iron containing little phosphorus, the melting phenomena are found initially at the outer region of austenite shell and subsequently progressed with the diffusion of carbon through the austenite shell without regard to heating rate. But as the phosphorus content was increased over than 0.12wt.%, the melting phenomena initiated at the boundary of eutectic shell and progressed along the contact area between the melt and graphite tips at higher heating rate. At lower heating rate, the melt of steadite dissolved at the lower temperature than that of eutectic was moved toward the graphite through the austenite grain-boundary and promoted melting of graphite and matrix.

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Unidirectional Solidification of $Al-CuAl_2$ Eutectic Composites under Forced Convection by Vibration (진동하에서 일방향응고 시킨 $Al-CuAl_2$ 공정복합재료의 응고에 관한 연구)

  • Lee, Hyun-Kyu;Lee, Kil-Hong
    • Journal of Korea Foundry Society
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    • v.18 no.3
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    • pp.234-239
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    • 1998
  • Unidirectional solidification of $Al-CuAl_2$ eutectic composites was studied under the condition of forced convection by vibration. It has been shown that thermal gradient for solid is different from that for liquid during solidification under force convection by vibration. With increase of vibration, mobility of liquid increases, but decreases with decreasing vibration. The rate of solidification is very high initially, and decreases suddenly. For further solidification, the rate of solidification decrceases slowly, and shows a L-type behavior. The mechanical vibration during solidification effects efficiently on nucleation, and induces a forced convection in liquid. By the forced convection, great thermal gradient of liquid interface between solid and liquid can be obtained. The amount of solute near the interface also decreases as solute distribution is improved by the forced convection.

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Effects of Thickness, Si and Mn Contents on the Mechanical Properties of 3.3 wt%C-0.1 wt%S Thin-Section Gray Cast Iron (3.3 wt%C-0.1 wt%S 박육 주철의 기계적 성질에 미치는 두께, 규소 및 망간의 영향)

  • Lee, Woo-Jong;Kim, Tae-Hyeong;Kwon, Hae-Wook
    • Journal of Korea Foundry Society
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    • v.32 no.5
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    • pp.211-218
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    • 2012
  • The effects of thickness, silicon and manganese contents on the mechanical properties of 3.3 wt%C-0.1 wt%S thin-section gray cast iron plates were investigated. The eutectic cell counts and volume fraction of pearlite in the matrix decreased with increased thickness and therefore the strength and hardness decreased with it. Even though the eutectic cell count increased with increased silicon content, the volume fraction of pearlite decreased and the strength and hardness decreased with it. The pearlite was refined more with increased manganese content and therefore the strength and hardness increased with it.

A Numerical Study of the Effect of Casting Temperature and Rotational Frequency of Mold on the Functionally Graded Microstructure in Centrifugal Casting of Hyper-eutectic Al-Si Alloy (과공정 Al-Si합금의 원심주조시 용탕온도와 금형회전수가 경사기능 조직에 미치는 영향에 대한 해석적 고찰)

  • Park, Jeong-Wook;Kim, Heon-Joo
    • Journal of Korea Foundry Society
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    • v.29 no.2
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    • pp.78-85
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    • 2009
  • Functionally graded microstructure of centrifugal cast Al-Si alloy, especially distribution of primary Si particles according to the changes of melt pouring temperature and rotation frequency was investigated by numerical simulation. Moving velocity of Si particles increased as the melt pouring temperature and rotational frequency of mold increased. Therefore, segregation tendency of primary Si particles toward inner side of cylindrical sample increased as the melt pouring temperature and rotational frequency of mold increased. Rich distribution region of particles was located at 0.9, 0.7, 0.4 mm from inner surface of cylindrical sample under the centrifugal cast condition of $750^{\circ}C$ melt pouring temperature and 1500, 2000 and 2500 rpm mold rotational frequencies, respectively, by numerical simulation.

The Estimate of Abrasion resistance of High chromium white cast irons by Dry sand/rubber wheel tester (토사마모실험을 통한 고크롬철계 주조합금의 내마모성 평가)

  • 김상호;김기열;이범주;조정환;박채규
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1998.10a
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    • pp.38-48
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    • 1998
  • To apply the high chromium white cast irons for sliding parts of construction equipments, the wear characteristics of these alloys which have three kinds of microstructure(hypoeutectic, near-eutectic, hypereutectic) were investigated by dry sand/rubber wheel tester. Also, the effect of heat treatment was investigated for the same alloys. As result of the test, heat treatment have no effect on the wear characteristics. And, hypereutectic composition alloy has the highest wear resistance against SiO$_2$. Also after test, cracking was observed in eutectic and primary carbides of all materials tested. This phenomenon was important factor in the wear resistance.

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