• 제목/요약/키워드: ethylene removal

검색결과 99건 처리시간 0.026초

역삼투막 공정에서 화학적 세정에 의한 $SiO_2$ scale 제거특성 (Characteristics of $SiO_2$ Scale Removal by Chemical Cleaning in Reverse Osmosis Membrane Process)

  • 독고석;이형집
    • 상하수도학회지
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    • 제24권1호
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    • pp.93-101
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    • 2010
  • Reverse osmosis (RO) membranes have been widely used for desalination as well as water and wastewater treatment facilities. Cleaning process is important to maintain stable operation as well as prevention of membrane fouling. Purpose of this research is to analyze electrostatistic and chemical characteristics after cleaning of RO membrane against $SiO_2$ scale. Four RO membranes of polyamide are used and examined about effect of chemical cleaning. EDTA (ethylene diamine tetraacetic acid) and SDS (sodium dodecil sulfate) and NaOH are applied for cleaning process after operation in synthetic water. Then, cleaning was performed with chemicals such concentration as 6hr, 12hr and 24hr, respectively. As a result, transmittances of FT-IR of four membranes are compared at each cleaning concentration. Ta/Tv shows difference of chemical composition between new membrane and cleaning membrane after cleaning. Type B of RO membrane is turned out to be most vulnerable to cleaning among four membranes. In terms of zeta potential, new membrane has -16 mV to +6 mV on pH while scaled membrane has -18 mV to 2 mV. However, it changed -23mV to 0.9 mV after cleaning. In comparison with existing salt rejection of RO membranes after cleaning, the rejection of the membranes goes down 0.7% maximum. Though cleaning changes the characteristics of membrane surface, it does not greatly affect salt rejection. pH is a critical factor to flux change in PA (polyamide) membrane.

사용 후 태양광 실리콘 모듈의 리싸이클링 (Recycling of End-of-Life Photovoltaic Silicon Modules)

  • 김준수;조재영;이재경;박아름;박진혁;윤현목;전연수
    • 자원리싸이클링
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    • 제28권5호
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    • pp.19-29
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    • 2019
  • 최근에 들어 태양광 발전의 시설용량이 급격히 증가되고 기 설치된 태양광 패널의 수명이 다하여 폐기될 모듈의 양이 점점 많아짐에 따라, 이에 대한 처리가 환경문제 해결뿐만 아니라 유가물질의 회수차원에서도 크나큰 관심을 받고 있다. 사용 후 태양광 모듈의 처리 공정은 대부분 알루미늄 프레임의 해체, 강화유리의 분리 회수, 실리콘 웨이퍼에 부착된 에틸렌 비닐 아세테이트(EVA)의 제거 및 태양광 셀 중에 함유된 유가금속의 회수 등으로 구성되어 있다. 전술한 태양광 폐모듈의 리싸이클링 기술들을 치밀하게 검토한 다음, 물질 선별기술을 포함한 효과적인 처리 기술을 제시하였다. 그리고 리싸이클링 산업의 활성화를 위해서 필수적인 생산자 책임제도의 시행을 비롯한 종합적인 의견을 제안하였다.

상향류 및 하향류의 유입 조건에 따른 여재의 제거효율 비교 (Comparison of Removal Efficiencies by Filter Media Experiments under the Upward and Downward Influent Conditions)

  • 김지아;김병준;최이송;오종민;박재로
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2016년도 학술발표회
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    • pp.441-444
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    • 2016
  • 본 연구에서는 유입수의 유입 방향을 달리 하였을 때 각 여재의 처리효율 차이점을 조사하고자 하였다. 실험재료는 제올라이트, 화산석, 발포 세라믹, 폴리에틸렌(Poly Ethylene) 4종의 여재이며 총 용적 31 L의 아크릴반응조에 각각의 여재를 충진하였고 각각 상향류 및 하향류의 흐름 방식을 적용하여 2차에 걸쳐 여과실험을 진행하였다. 제거효율은 유입수 대비 유출수의 농도 변화를 통하여 관찰하였고, 수질 측정은 SS, COD, T-N, T-P 네 항목으로 수질공정시험법에 의거하여 분석하였다. 실험 결과 제올라이트는 SS, COD, T-N항목에서 상향류를 적용한 여과에서 제거효율이 높은 경향을 보였다. 특히 T-N항목의 경우 상향류 조건에서 49.2%, 하향류 조건에서 34.4%의 제거효율을 나타내 흐름조건별 제거효율에 가장 큰 격차를 보였다. 화산석의 경우 SS, COD, T-N항목은 흐름방식에 따른 제거효율에 주목할 만한 차이를 드러내지 않았으나 예외적으로 T-P항목만 상향류 조건에서 24.2%, 하향류 조건에서 15.9%의 제거효율을 나타냄으로써 상향류 조건에서 8.3% 높은 제거효율을 얻었다. 발포 세라믹 여재는 하향류를 적용한 여과에서 제거효율이 우세한 경향을 보였으며 특히 COD 항목의 경우 상향류 조건에서보다 하향류 조건에서 제거효율이 7.5% 향상된 결과를 얻었다. 폴리에틸렌 여재는 전반적으로 유입 조건에 따른 경향성을 나타내지 않았으나 예외적으로 SS항목의 경우 하향류 조건에서보다 상향류 조건을 적용한 여과에서 7.9% 높은 제거효율을 얻었다.

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Effect of Exposure to Vitrification Solutions on Maturation and Cleavage Rates of Immature Porcine Oocytes in Vitro

  • Park, I. K.;H. B. Song
    • 한국발생생물학회:학술대회논문집
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    • 한국발생생물학회 2003년도 제3회 국제심포지움 및 학술대회
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    • pp.113-113
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    • 2003
  • This study was conducted to investigate the effect of vitrification solution(VS) on in vitro developmental competence of immature porcine oocytes. The immature porcine oocytes were exposed to the following vitrification solution, at RT. 1) EFS sol. : 20% ethylene glycol (EG) 3 min, 40% EG + 18%(w/v) Ficoll(MV70, 000) + 0.3 M sucrose 30 sec, 2) GE sol. : 10% glycerol 5 min, 10% G + 20% EG 5 min, 25% G +25% EG 30 sec, 3) EG sol : 1.5M EG 2.5 min, 5.5 M EG + 1.0 M sucrose 30 sec. Oocytes were immediately transferred into 1.0 M, 0.5 M, 0.25 M, 0125 M, 0 M sucrose solution for 2.5 min each at RT. After removal of VS, immature oocytes were matured in vitro and subsequently all oocytes were subjected to IVF followed in vitro culture for 7 days. Maturation rates of oocytes were 38.8%, 44.5%, 22.4% and 57.6%, in EFS, EG, GE and Control, respectively, maturation rates of oocytes in EG and Control was significantly higher than EFS and GE(P<0.01). Fertilization rates of oocytes in Control was significantly higher than other treated groups(P<0.05), but no difference were observed among treated groups. Polyspermic rates were no significant difference among four groups. Cleavage rates of oocytes were 21.9%, 47.1%, 19.0% and 65.9%, in EFS, EG, GE and Control, respectively, cleavage rates of oocytes in EG and Control was significantly higher than EFS and GE(P<0.05), but blastocyst formation rates were no significant difference among four groups. These results suggested that the use of EG solution could be a great challenge for reaching a successful vitrification of immature porcine oocytes.

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Aluminum Powder Metallurgy Current Status, Recent Research and Future Directions

  • Schaffer, Graham
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2001년도 추계학술강연 및 발표대회
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    • pp.7-7
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    • 2001
  • The increasing interest in light weight materials coupled to the need for cost -effective processing have combined to create a significant opportunity for aluminum P/M. particularly in the automotive industry in order to reduce fuel emissions and improve fuel economy at affordable prices. Additional potential markets for Al PIM parts include hand tools. Where moving parts against gravity represents a challenge; and office machinery, where reciprocating forces are important. Aluminum PIM adds light weight, high compressibility. low sintering temperatures. easy machinability and good corrosion resistance to all advantages of conventional iron bm;ed P/rv1. Current commercial alloys are pre-mixed of either the AI-Si-Mg or AL-Cu-Mg-Si type and contain 1.5% ethylene bis-stearamide as an internal lubricant. The powder is compacted in closed dies at pressure of 200-500Mpa and sintered in nitrogen at temperatures between $580~630^{\circ}C$ in continuous muffle furnace. For some applications no further processing is required. although most applications require one or more secondary operations such as sizing and finishing. These sccondary operations improve the dimension. properties or appearance of the finished part. Aluminum is often considered difficult to sinter because of the presence of a stable surface oxide film. Removal of the oxide in iron and copper based is usually achieved through the use of reducing atmospheres. such as hydrogen or dissociated ammonia. In aluminum. this occurs in the solid st,lte through the partial reduction of the aluminum by magncsium to form spinel. This exposcs the underlying metal and facilitates sintering. It has recently been shown that < 0.2% Mg is all that is required. It is noteworthy that most aluminum pre-mixes contain at least 0.5% Mg. The sintering of aluminum alloys can be further enhanced by selective microalloying. Just 100ppm pf tin chnnges the liquid phase sintering kinetics of the 2xxx alloys to produce a tensile strength of 375Mpa. an increilse of nearly 20% over the unmodified alloy. The ductility is unnffected. A similar but different effect occurs by the addition of 100 ppm of Pb to 7xxx alloys. The lend changes the wetting characteristics of the sintering liquid which serves to increase the tensile strength to 440 Mpa. a 40% increase over unmodified aIloys. Current research is predominantly aimed at the development of metal matrix composites. which have a high specific modulus. good wear resistance and a tailorable coefficient of thermal expnnsion. By controlling particle clustering and by engineering the ceramic/matrix interface in order to enhance sintering. very attractive properties can be achicved in the ns-sintered state. I\t an ils-sintered density ilpproaching 99%. these new experimental alloys hnve a modulus of 130 Gpa and an ultimate tensile strength of 212 Mpa in the T4 temper. In contest. unreinforcecl aluminum has a modulus of just 70 Gpa.

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BTEX 분해미생물의 순수분리와 혼합 배양에 따른 기질 분해율 및 미생물 성장률 변화에 관한 연구 (A Study on Isolation of BTEX Degrading Microorganism and Variation of BTEX Removal Efficiency and Microorganism Growth Rate According to Co-Culture)

  • 정경미;이상협;이한웅;홍석원;김영오;최용수;유명진
    • 한국물환경학회지
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    • 제21권4호
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    • pp.347-352
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    • 2005
  • The isolated microorganisms, Pseudomonas stutzeri, Raoultella planticola (Klebsiella), Serratia fonticola from petroleum contaminated soil were enriched on benzene, toluene, ethylbenzene, o-xylene as carbon and energy sources, respectively. And the degradation characteristics of BTEX was observed in the mixed BTEX substrates. We found that the BTEX in mixed substrates were degraded more than 50% by three isolated microorganisms. Among three isolated microorganisms, the highest degradation rate was observed in Pseudomonas stutzeri, but the degradation rate was different according to microorganisms. In order to increase the degradation efficiency, we applied the co-culture of isolated three microorganisms. The mixture rate of pseudomonas stutzeri : Raoultella planticola (Klebsiella) : Serratia fonticola was follows ; 1:2:1, 1:1:2, and 2:1:1, respectively. In two co-culture of 1:2:1 and 1:1:2, degradation rate was lower than isolated microorganisms. However, degradation rate became higher than isolated microorganisms and the degradation rate of benzene, toluene, and ethylene was more than 95% in co-culture of 2:1:1. The degradation rate increased through the co-culture of isolated microorganisms, however, the growth rate decreased. This was resulted from the substrate competition between microorganisms. The co-culture of microorganisms is a effective method to increase the degradation efficiency of BTEX and the co-culture mixing rate is a important factor for determination of degradation efficiency.

EDTA를 이용한 치근면 처리가 치은섬유모세포의 초기 부착에 미치는 영향 (Effect of Root Surface Treatment Using EDTA on the Initial Attachment of Human Gingival Fibroblasts)

  • 김성봉;임기정;김상목;김병옥;한경윤
    • Journal of Periodontal and Implant Science
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    • 제30권1호
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    • pp.145-157
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    • 2000
  • Cytotoxic substances in dental calculus and root cementum of periodontally diseased teeth inhibit new attachment and regeneration. The purpose of scaling and root planing is to remove pathologic structures harboring these cytotoxic substances in order to create a biologically acceptable root surface. However, these procedures inevitably leave a non-biocompatible smear layer. Conventionally, the smear layer has been removed with low pH etching agents such as citric acid, phosphoric acid and tetracycline hydrochloride(TC). Lately, a supersaturated neutral pH etching solution of ethylene diamine tetraacetic acid(EDTA) has been found to be as effective as low pH etchants with respect to smear removal and to be superior in exposing root surfaceassociated collagen. The aim of the present study was to determine the effect of root surface treatment using EDTA on the initial attachment of human gingival fibroblasts. 27 human teeth, extracted due to severe periodontitis, were cut into dentin slices after root planing. The specimens were divided into TC group(treated with $50㎎/m{\ell}$ tetracycline-HCl, pH 1.52), EDTA group(treated with 17% EDTA, pH 7.4), and non-treated control group. After sterilization, 5th subcultured human gingival fibroblasts were seeded in each culture well containing a prepared root slice and incubated for 15 min., 60 min., and 4 hours in 5% $CO_2$ incubator at $37^{\circ}C$. At each incubation time, the number of attached fibroblasts were counted on the microphotographs taken at a magnification of x100. The difference of the number of attached cells between groups was statistically analyzed by the ANOVA followed by Duncan test in SPSS/PC+programs. The results were as follows : 1. After incubation for 15 min, the attached cells were significantly more in EDTA group and TC group than non-treated control group(p<0.05), but there was no significance in the difference between EDTA group and TC group(p>0.1). 2. After incubation for 60 min and 4 hours, there was no significant difference in the number of attached cells between all groups(p>0.1). 3. In both EDTA group and TC group, there was no significant difference in the number of attached cells between different incubation(p>0.1). But in control group, the number of attached cells was significantly increased after incubation for 60 min, compared with incubation for 15 min(p<0.05). The above results suggest that root surface treatment using EDTA could enhance the initial attachment of gingival fibroblasts to root surface as effective as tetracycline-HCl.

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Echinochloa colona 종자(種子)의 휴면(休眠) 및 발아특성(發芽特性) (SEED DORMANCY AND GERMINATION BEHAVIOUR OF ECHINOCHLOA COLONA)

  • 전재철;키이쓰 무디
    • 한국잡초학회지
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    • 제7권1호
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    • pp.12-18
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    • 1987
  • E. colona 종자(種子)의 휴면성(休眠性) 및 광(光)과 발아관여기체(發芽關與氣體)에 대한 발아(發芽) 반응성(反應性)을 조사(調査)하였다. E. colona는 휴면상성(休眠賞醒)을 위해 후숙기간(後熟期間)을 요(要)하지 않하였다. 종피(種皮)를 통(通)한 수분(水分) 이동(移動)은 용이(容易)하였다. 수화(水和) 및 건조(乾燥)의 반복처리(反復處理)는 종자(種子)의 발아력(發芽力)을 감소(減少)시켰다. 24 시간(時間)의 종자(種子) 침윤(浸潤)으로 수분함량(水分含量)은 21%까지 증가(增加)되었으나, 실온(室溫)에서 13 시간(時間) 후(後)에는 원상태(原狀態)로 회복(回復)되었다. 종피(種皮)의 제거(除去)는 암조건하(暗條件下)에서 발아율(發芽率)을 현저히 증가(增加)시켰으며, 광(光)은 완전종자(完全種子)의 발아(發芽)를 촉진(促進)시켰다. 일광도(日光度) 51.9$Wm^{-2}$ 이하(以下)의 조건하(條件下)에서의 발아(發芽)는 현저하게 감소(減少)되었다. 광조사(光照射) 1일(日) 1시간(時間) 처리(處理)는 1일(日) 2 시간(時間) 이상(以上) 처리(處理)에 비하여 현저하게 낮은 발아율(發芽率)을 보였다. 청색광(靑色光) 조사(照射) 종자(種子)는 적색광(赤色光) 조사(照射)에 비하여 발아(發芽)가 지연(遲延)되었으며, 발아율(發芽率)도 낮았다. 광존재하(光存在下)에 외생적(外生的)으로 처리(處理)한 에칠렌 및 탄산가스는 발아(發芽)를 촉진(促進)시켰으며, 이 두 기체(氣體)의 동시처리(同時處理)는 공력효과(共力效果)를 나타내었다. 그러나 암조건하(暗條件下)에서는 이 두 기체(氣體)의 작용력(作用力)이 나타나지 않하였다.

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식물 생장을 촉진할 수 있는 구리 내성 세균의 분리 (Isolation of copper-resistant bacteria with plant growth promoting capability)

  • 김민주;송홍규
    • 미생물학회지
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    • 제53권4호
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    • pp.251-256
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    • 2017
  • 구리 스트레스를 받는 식물에 구리 내성을 부여하며 생장을 촉진할 수 있는 여러 구리 내성 근권세균을 분리하였다. 분리균주 Pseudomonas veronii MS1과 P. migulae MS2는 금속 킬레이트제인 siderophore를 각각 0.13과 0.26 mmol/ml 생성하였으며 또한 20 mg/L Cu 수용액에서 각각 64.6과 77.9%의 구리에 대한 생물흡착능을 나타내었다. 구리는 생물체에서 산화스트레스를 유발할 수 있는 유해한 자유 라디칼 형성을 유도할 수 있다. MS1과 MS2 균주의 1,1-diphenyl-2-picryl hydrazyl 라디칼 제거능과 항산화능은 24시간 배양 후 대조군에 비해 각각 82.6과 78.1% 증가하였다. 이들은 식물에서 스트레스 호르몬인 에틸렌의 수준을 낮추는 1-aminocyclopropane-1-carboxylic acid deaminase 활성을 각각 7.10과 $6.42{\mu}mol$ ${\alpha}$-ketobutyrate mg/h 나타내었으며 한편 비생물적 스트레스 하의 식물 생장을 도울 수 있는 indole-3-acetic acid와 salicylic acid도 생성하였다. 이 모둔 결과들은 이 구리-내성 근권세균들이 식물에 구리 내성을 부여하며 생장을 촉진할 수 있다는 것을 가리킨다.