• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.48 no.2
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• pp.20-27
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• 2016

Ethylene gas is a natural hormone that directly affects the freshness of agricultural products, so it is very important for the maintenance of freshness to remove ethylene gas from corrugated board boxes. Many methods for the removal of this and other gases have been reported. In this study, the utilization of an absorbent using activated carbon was adopted for the removal of ethylene gas from a corrugated board box. Activated carbon powders were prepared by grinding in a laboratory and were used to treat the surface and to laminate paperboards with a starch solution. The ethylene gas absorption was evaluated by using a gas chromatography to measure the residual ethylene gas concentration. About 60% of the ethylene gas was absorbed by the activated carbon itself. However, the paperboards that were surface-treated and laminated with starch and activated carbon showed lower than 20% ethylene gas absorption. This was because the starch and smaller particles of activated carbon blocked the surface pores of activated carbon particles. Therefore, either the use of the binders must be minimized for the surface treatment of paperboards, or activated carbon packs can be used as absorbents in corrugated boxes.

• Applied Chemistry for Engineering
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• v.23 no.6
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• pp.608-613
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• 2012

Dielectric barrier discharge plasma reactor was applied to the removal of ethylene from a simulated storage facility ($1.0m^3$) of fruits and vegetables. The system operated in a closed-loop mode by feeding the contaminated gas to the plasma reactor and recirculating the treated gas back to the storage facility. The experiments were carried out with parameters such as discharge power, circulation flow rate, initial ethylene concentration and treatment time. The rate of ethylene decomposition was mainly controlled by the discharge power and the treatment time. With the other conditions kept constant, the ethylene decomposition rate in the presence of the manganese oxide ozone control catalyst installed downstream from the plasma reactor was lower than that in the absence of it. The suggests that unreacted ozone from the plasma reactor accumulated in the storage facility where it additionally decomposed ethylene. On the basis of an initial ethylene concentration of 50 ppm, the energy requirement for completing the decomposition was about 60 kJ.

• Journal of the Korean Wood Science and Technology
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• v.38 no.1
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• pp.27-35
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• 2010

To evaluate the basic characteristics and adsorption properties of commercial wood charcoal, we investigated the proximate analysis, porosimetry analysis, methylene blue adsorption, removal ratios of formaldehyde, and removal ratio of ethylene gas. Fixed carbon contents of traditional black and white charcoal, and mechanical charcoal were 51.8~76.6%, 72.9~84.6%, and 48.5~80.3%, respectively. Refining degrees of the most traditional black charcoal were 9, and those of white charcoal and mechanical charcoals were zero. Specific surface area of traditional black charcoal was 0.1~13.7 $m^2/g$, which was quite lower than that of white charcoal (53.2~372.6 $m^2/g$) and mechanical charcoals (224.3~464.6 $m^2/g$). Also, amounts of methylene blue adsorption were quite lower in black charcoal (0.53~1.97 mg/g) compared with white charcoal (2.68~7.68 mg/g) and mechanical charcoal (11.63~26.10 mg/g). Removal ratios of formaldehyde of the black charcoal were 11.4~26.7%, which is quite similar to white charcoal (17.9~34.9%) and mechanical charcoal (5.5~25.8%). Removal ratios of ethylene gas for traditional black charcoal, traditional white charcoal, and mechanical charcoal were 2.2~43.5%, 21.7~39.1%, 21.7~39.1%, respectively. There was no significant difference in the removal ratios of formaldehyde and ethylene gas among traditional black charcoal, traditional white charcoal, and mechanical charcoal.

• KSBB Journal
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• v.28 no.1
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• pp.48-53
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• 2013

Pretreatment of wastepaper using aqueous glycerol was investigated to enhance the enzymatic hydrolysis. The effects of four factors (solid/liquid ratio, glycerol concentration, acid concentration, and reaction time) on the dissolution yield, the removal of cellulose, hemicellulose and lignin, and the enzymatic digestibility were examined at $150^{\circ}C$. The 1/8 of solid/liquid was determined to perform the reaction uniformly, and the 93% of glycerol concentration was found to be a minimum concentration to conduct the reaction under atmospheric pressure. Also, it was found that the acid concentration and reaction time were strongly related to the dissolution yield and the removal of cellulose, hemicellulose and lignin, but moderately to the enzymatic digestibility. At an optimum condition of $150^{\circ}C$, 1 h and 1% acid concentration, 56% and 49% of hemicellulose and lignin, respectively, were removed, while only 4% of cellulose was removed. The enzymatic digestibility at this condition was 86%, meaning that 83% of the glucan present in the initial substrate was converted to glucose. Compared to glycerol with ethylene glycol as a pretreatment solvent, glycerol is much cheaper than ethylene glycol, but ethylene glycol is superior to glycerol in delignification.

• Korean Journal of Chemical Engineering
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• v.35 no.11
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• pp.2303-2312
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• 2018

Pretreatment process of silica-coated PET fabrics, a major low-grade PET waste, was developed using the reaction with NaOH solution. By destroying the structure of silica coating layer, impurities such as silica and pigment dyes could be removed. The removal of impurity was confirmed by X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDX). The pretreated PET fabric samples were used for depolymerization into its monomer, bis(2-hydroxylethyl) terephthalate (BHET), by glycolysis with ethylene glycol (EG), and zinc acetate (ZnAc) catalyst. The quality of BHET was confirmed by DSC, TGA, HPLC and NMR analyses. The highest BHET yield of 89.23% was obtained from pretreated PET fabrics, while glycolysis with raw PET fabric yielded 85.43%. The BHET yield from untreated silica-coated PET fabrics was 60.39%. The pretreatment process enhances the monomer yield by the removal of impurity and also improves the quality of the monomer.

• Bulletin of the Korean Chemical Society
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• v.27 no.12
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• pp.2064-2066
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• 2006

• Journal of Soil and Groundwater Environment
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• v.8 no.1
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• pp.42-47
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• 2003

A biofilter study was performed in order to remove mixed benzene and ethylene emitted from soil and groundwater remediation. In particular, more than 96% of ethylene was removed at residence times of 10～15 min, and the possibility of use of the biofilter was obtained. The benzene removal efficiency was achieved as much as 100% at residence times of 2～15 min. With a residence time of 15 min, the maximum elimination capacity of benzene and ethylene was 4.3 g/$\textrm{m}^3$hr and 1.4 g/$\textrm{m}^3$hr, respectively. The maximum elimination capacity of benzene was 3 times higher than that of ethylene. Carbon dioxide concentration decreased as residence times were lowered due to low ethylene degradation rate. The maximum carbon dioxide production rate of 3,169 [mg-$CO_2$/(g-${C_2}{H_4}$＋${C_6}{H_6$)] was investigated when benzene and ethylene were completely removed. It was found that dominant bacteria in the benzene-degrading microorganisms were identified as Bacillus mycoides and Pseudomonas fluorescens. Dominant bacteria in the ethylene-degrading microorganisms were identified as Pseudomonas putida and Pseudomonas fluorescens.

• Applied Chemistry for Engineering
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• v.16 no.5
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• pp.635-640
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• 2005

Mediated electrochemical oxidation (MEO) is an aqueous process which oxidizes organics electrochemicallly at low temperatures and pressures. The useful process can be used to treat mixed wastes containing hazardous organics. This paper have studied MEO of ethylene glycol (EG) in nitric acids by Fe(III)/Fe(II) and Co(III)/Co(II) system. It investigated current density, supporting electrolyte concentration, hydraulic retention time, removal efficiency of EG by MEO. Removal efficiency of EG by MEO was superior in Co(III)/Co(II) redox system than Fe(III)/Fe(II) redox system, where MEO removal efficiency was 100 percent. In case of EG, the reactions were fast and good yields of carbon dioxide formation was observed.

• Journal of the Korean Wood Science and Technology
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• v.39 no.4
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• pp.281-290
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• 2011

We analyzed the basic characteristics and adsorption property of carbonized materials from thinning byproducts of major Korean wood species for evaluating as charcoal making raw material. Yield of charcoal was decreased with increasing the carbonization temperature for all wood species. Refining degrees was 9.0 at $400^{\circ}C$, 3.3~5.0 at $600^{\circ}C$ and 0 at $800^{\circ}C$, and was no difference among wood species. With increasing the carbonization temperature, the fixed carbon content was also increased, and charcoal from softwoods had more fixed carbon content than that from hardwoods. Specific surface area was increased with increasing the carbonization temperature, softwood charcoal had more specific surface area than that of hardwood. Pinus rigida showed the highest specific surface area. In formaldehyde removal by charcoal, some materials had highest at $600^{\circ}C$ and the others had highest at $800^{\circ}C$. Pinus koraiensis, Qurcus acutissima and MDF showed maximum formaldehyde removal ability at $600^{\circ}C$. Ethylene gas removal ability of charcoal was increased with increasing the carbonization temperature, and the charcoal from Pinus rigida and Robinia pseudoacacia had higher ethylene gas removal ability than the other species.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.3
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• pp.315-323
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• 2003

The goal of this study if the optimization of discharge electrode for pulsed corona discharge reactor located in thermal power plant. For this purpose, we have performed experiments of NO$_{x}$ removal rate by exchange of discharge electrode diameter and arrangement of discharge electrode in the non -thermal plasma reaction facility using a ethylene as additive. If the diameter and numbers of discharge electrode were larger, the NO$_{x}$ removal rate was higher. From these results, if we optimized the shape and installed numbers of discharge electrode at the pilot plant, we could increase the NO$_{x}$ removal rate with less amount of additive than current amount.mount.