• The Journal of Engineering Research
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• v.6 no.2
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• pp.85-98
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• 2004

The adsorption equilibrium data for the binary gas mixture system from the pure gas adsorption data of carbon dioxide and ethylene on ZSM-5 prepared were predicted. The binary gas mixture adsorption data have been examined against predicted values by two models-the vacancy solution model(VSM) and the statistical thermodynamic model(STM), using parameters obtained from the single component isotherm. The binary gas mixture data for the carbon dioxide-ethylene system were obtained for cation exchanged forms of ZSM-5 for the gas phase carbon dioxide mole fraction of 0.752 at $37^{\circ}C$ and 1 atm. The experimental adsorption phase diagrams were obtained for carbon dioxide-ethylene on sodium form ZSM-5 synthesized. The single component adsorption isotherms for carbon dioxide and ethylene were also obtained for this zeolite. The single component data were used to obtain parameters derived in two models. These parameters were, in turn, used to predict the binary mixture isotherms for this zeolite. Both the vacancy solution and the statistical thermodynamic models give satisfactory predictions of adsorption phase diagrams for the binary gas mixtures of carbon dioxide and ethylene on sodium exchanged ZSM-5. Also the correlation between the experimental data and the predicted values is generally in good agreement. The system appears to show ideal behavior with a relatively constant separation factor. The slight increase in adsorption capacity with an increase in ionic radius is due, in part, to the higher polarizability associated with larger cations.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.39 no.1 s.119
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• pp.64-68
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• 2007

The oak and pine charcoal were used to develop the inner packaging material for maintaining the freshness of vegetables and fruits, and to investigate the possibility in the application for inner packaging. The effects of the charcoal type, species, particle size, and grammage on the adsorption efficiency of ethylene gas were studied. White charcoal has superior ethylene gas adsorption performance to those of black charcoal. Pine charcoal was superior to oak charcoal in the ethylene gas adsorption. Higher gas adsorption was obtained by the higher grammage sheet. The difference in the adsorption efficiency was not significant between ONP and KOCC.

• Korean Chemical Engineering Research
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• v.48 no.6
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• pp.768-775
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• 2010

Adsorption dynamics of ethane/ethylene mixture gas and desorption dynamics during the displacement desorption with propane as a desorbent in the column filled with faujasite adsorbent were investigated experimentally and theoretically. The simulation that adopted heat and mass balance and an ideal adsorbed solution theory (IAST) for the multicomponent adsorption equilibrium well predicted the experimental breakthrough curves of the adsorption and desorption. At the adsorption breakthrough experiments, roll-ups of ethane increased as the adsorption pressure increased and the adsorption temperature decreased. During the displacement desorption with propane in the column saturated with ethane/ethylene mixture gas, almost 100% of ethylene was obtained for a certain time interval. The adsorption strength of the desorbent greatly affected the adsorption and re-adsorption dynamics of ethylene. The re-adsorption capacity for ethylene has been greatly reduced when iso-propane, which is stronger desorbent than propane, was used as desorbent. It was found from the simulation that the performance of the displacement desorption process would be superior when the ratio of ${(q_s{\times}b)}_{C_2H_4}/{(q_s{\times}b)}_{C_3H_s}$ was 0.83, that is, the adsorption strengths of ethylene and the desorbent were similar.

• Journal of the Korean Wood Science and Technology
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• v.31 no.6
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• pp.83-88
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• 2003

The woodceramics are porous amorphous carbon and glassy carbon composite materials. Woodceramics attracted a lot of attention in recent years because they are environmentally friendly and because of their unique functional characteristics such as catalysis, moisture absorption, deodorization, purification, carrier for microbial activity, specific stiffness, corrosion and friction resistance, and their electromagnetic shielding capacity. In this paper, we made new products of clay-woodceramics to investigate the industrial analysis and ethylene gas adsorption for basic data of building- and packging- materials keeping fruit fresh for a long time. Clay-woodceramics were carbonized for 3 h of heating in a special furnace under a gas flow of nitrogen(15 ml/min.) from 3 layers-clay-woodparticleboard made from pallet waste wood, phenol- formaldehyde resin(hereafter PF, Non volatile content:52%, resin content 30%), and clay(10%, 20% and 30%). Carbonization temperature was 400℃, 600℃ and 800℃. Experimental results shows that the higher the carbonization temperature, the higher the fixed carbon and the lower the volatile contents. The higher the clay content, the more the ash content. The higher the carbonization temperature, the more the ethylene gas adsorption. Carbonization temperature of 800℃ gave the best reslts as same as that of white charcoal and activated carbon.(800℃-clay-woodceramic: 5.36 ppm, white charcoal: 5.66 ppm, activated carbon: 5.79 ppm) The clay contents did not make difference of ethylene gas adsoption.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2006.06b
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• pp.455-458
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• 2006

The oak and pine charcoal were used to develop the internal packaging raw material for maintaining the freshness of vegetables and fruits, and to investigate the possibility in the application for pulp mold packaging. The effects of the charcoal type, species, particle size, and grammage on the adsorption efficiency of ethylene gas were studied. White charcoal has superior ethylene gas adsorption performance to those of black charcoal. Pine charcoal was superior to oak charcoal in the ethylene gas adsorption. Higher gas adsorption was obtained by the higher grammage sheet. The difference in the adsorption efficiency was not significant between ONP and KOCC.

• Journal of the Korea Furniture Society
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• v.14 no.1
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• pp.1-9
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• 2003

This research was carried out for packing materials and building materials to examine thylene gas adsorption and effect of keeping fruit fresh of wet formed charcoal-fiber mposite made from defibrated fiber of Pinus densiflora Sieb. et Zucc. and white charcoal from uercus variabilis Bl.(wood fiber: charcoal=8:2, 6:4, 4:6, 2:8), with/without phenol formaldehyde resin(PF, Non volatile content:$52\%$, resin content $1,3,5\%$). The results are summarized as follows: 1. The higher the charcoal content, the more the ethylene gas adsorption. At the same mixing ratio of fiber to charcoal, $\#100-200$ of charcoal particle size gave the better reslts than $\#60-100$. 2. Adding PF into the charcoal fiber composite decreased the capacity of ethylene gas adsorption but there was no significant difference until $5\%$ adding amount of PF. 3. For keeping fruit fresh for a long time, Charcoal fiber composite was $66\%$ longer than control. The higher the white charcoal content, the longer fresh time.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.35 no.2
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• pp.46-51
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• 2003

The charcoal is known to have gas adsorption capability and is used frequently to mitigate the unpleasant smells from food and clothing. It is also used to treat water to remove dissolved organic and inorganic substances. In this paper, we applied the several different kinds of charcoals to the papers in three different ways to investigate if charcoal application method affects its gas adsorption capability. Wet end addition, making multiply, and coating method were tested. Specific ethylene gas adsorption capabilities were measured. Experimental results shows that manufacturing conditions of the charcoal itself changed its gas adsorption properties. The boxes used for agricultural produces, and the packaging paper for flowers are to be well fitted application for the charcoal added paper. Mulch paper, which needs opacity and air permeability with proper strength properties, is another candidate for the application of charcoal added paper.

• Journal of the Korean Wood Science and Technology
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• v.32 no.5
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• pp.86-92
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• 2004

This research was carried out to examine the ethylene gas adsorption and preservation life of white charcoal boards for packaging. Two types of white charcoal board were made of #40-60 charcoal particles and mixed charcoal particles with PVA and MDI resin by wet process. For not only beauty effect but also avoiding stain from touching, white charcoal boards were overlaid with two kinds of overlay material, thin printed paper and non woven fabric. A charcoal board adsorbed ethylene gas much more than the paper and even white charcoal itself. There was no difference between two board types, between overlay treatments, and between overlay materials. Gray mold growth of strawberry arised after 2 days in a paper box and after 4 days in a white charcoal board. Preservation life of white charcoal board box was approximately twice more than that. of a paper box. There was no difference in the ability of keeping freshness between two board types, between overlay treatments, and between overlay materials.

• Journal of the Korean Wood Science and Technology
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• v.38 no.1
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• pp.27-35
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• 2010

To evaluate the basic characteristics and adsorption properties of commercial wood charcoal, we investigated the proximate analysis, porosimetry analysis, methylene blue adsorption, removal ratios of formaldehyde, and removal ratio of ethylene gas. Fixed carbon contents of traditional black and white charcoal, and mechanical charcoal were 51.8~76.6%, 72.9~84.6%, and 48.5~80.3%, respectively. Refining degrees of the most traditional black charcoal were 9, and those of white charcoal and mechanical charcoals were zero. Specific surface area of traditional black charcoal was 0.1~13.7 $m^2/g$, which was quite lower than that of white charcoal (53.2~372.6 $m^2/g$) and mechanical charcoals (224.3~464.6 $m^2/g$). Also, amounts of methylene blue adsorption were quite lower in black charcoal (0.53~1.97 mg/g) compared with white charcoal (2.68~7.68 mg/g) and mechanical charcoal (11.63~26.10 mg/g). Removal ratios of formaldehyde of the black charcoal were 11.4~26.7%, which is quite similar to white charcoal (17.9~34.9%) and mechanical charcoal (5.5~25.8%). Removal ratios of ethylene gas for traditional black charcoal, traditional white charcoal, and mechanical charcoal were 2.2~43.5%, 21.7~39.1%, 21.7~39.1%, respectively. There was no significant difference in the removal ratios of formaldehyde and ethylene gas among traditional black charcoal, traditional white charcoal, and mechanical charcoal.

• Korean Chemical Engineering Research
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• v.50 no.3
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• pp.527-534
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• 2012

The adsorption dynamics of activated carbon (AC) and carbon molecular sieve (CMS) beds were studied to recover ethylene from FCC fuel gas. In this study, the FCC fuel gas used consisted of six-component mixture ($CH_4/C_2H_4/C_2H_6/C_3H_6/N_2/H_2$,32:15:14:2:12:25 vol.%). And the breakthrough experiments of adsorption and desorption were carried out. The breakthrough sequence in the AC bed was $H_2$ < $N_2$ < $CH_4$ < $C_2H_4$ < $C_2H_6$ while the sequence in the CMS bed was $H_2$ < $CH_4$ < $N_2$ < $C_2H_6$ < $C_2H_4$. The separation performance of the CMS bed during the adsorption step was lower than that of the AC bed. However, due to the characteristics of kinetic separation, the CMS bed could remove $CH_4/N_2$ as well asthe molecules that are larger than $C_2H_6$, which was not easy to be done by the AC bed. Since it was hard to regenerate the adsorption bed by simple depressurization, vacuum regeneration should be adopted. As a result, the pressure vacuum swing adsorption (PVSA) process, consisting of CMS pretreatment process and AC main process, was suggested to recover ethylene efficiently.