• 제목/요약/키워드: essential spectra

검색결과 114건 처리시간 0.03초

저장조건에 따른 싸주아리쑥 정유의 휘발성 성분 변화 (Effects of Storage Conditions on Essential Oil of Artemisia princeps Pampan. cv. ssajuari (ssajuarissuk))

  • 정미숙
    • 한국식품조리과학회지
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    • 제26권6호
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    • pp.840-847
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    • 2010
  • In this study, we identified the volatile compounds of Artemisia princeps Pampan. cv. ssajuari (ssajuarissuk) essential oils and analyzed changes in the contents of volatile compounds under four different storage conditions, such as exposure to air at $20^{\circ}C$ and $40^{\circ}C$. Sixty-five volatile compounds consisting of 6 monoterpene hydrocarbons, 23 oxygenated monoterpenes, 16 sesquiterpene hydrocarbons, 6 oxygenated sesquiterpenes, 1 diterpene, 6 benzene derivatives, and 7 non-isoprenoid compounds were identified on the basis of their mass spectra characteristics and retention indices from original ssajuarissuk essential oils. Identified compounds constituted 90.56% of the total peak area. Borneol (10.29%) was the most abundant compound in the original ssajuarissuk essential oils, followed by 1,8-cineole (9.06%), viridiflorol (8.99%), spathulenol (8.73%), $\alpha$-thujone (5.28%), and camphor (4.39%). After six months storage at $40^{\circ}C$ with the cap opened for 3 min everyday, the total amount of volatile compounds in essential oil as determined by the percentage peak area decreased by 84.93%. The total levels of cis-sabinene hydrate, camphor, 4-terpineol, humulene oxide, $\beta$-caryophyllene oxide, and caryophyllene alcohol increased significantly. For ssajuarissuk essential oils stored under experimental conditions, changes in the contents of volatile compounds in essential oils were accelerated by temperature and contact with the atmosphere.

Changes in the Volatile Compounds of Artemisia princeps var. orientalis Essential Oils During Storage

  • Chung, Mi-Sook
    • Food Science and Biotechnology
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    • 제18권2호
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    • pp.481-487
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    • 2009
  • The compositional changes of wormwood (Artemisia princeps var. orientalis) essential oils were studied under 4 different storage conditions i.e., being exposed to air at 20 and $40^{\circ}C$. Sixty-four volatile compounds consisting of 24 terpene hydrocarbons, 18 alcohols, 11 ketones, 6 esters, 1 aldehyde, 2 hydrocarbons, and 2 oxides were identified on the basis of their mass spectra characteristics and retention indices in original wormwood essential oils. Identified compounds constituted 80.53% of the total peak area. Borneol (12.13%) was the most abundant compound, followed by $\alpha$-thujone (8.66%), T-cadinol (6.67%), and 1,8-cineole (6.21%) in original wormwood essential oils. Under the condition of $40^{\circ}C$ of temperature with the cap being opened for 3 min everyday respectively during 6 months of storage, the total amount of functional groups in essential oil determined by peak area percent were decreased by 79.45%, at most. The total level of monoterpene hydrocarbons decreased markedly in the aerobic condition and high temperatures. Whereas the total level of esters increased significantly. Wormwood essential oils were stored in experimental conditions, with the changes in the volatile compounds of essential oils being accelerated by high temperatures and contact with the atmosphere.

진단용 X-선 스펙트럼의 몬테칼로 전산모사 측정 (Diagnostic X-ray Spectra Detection by Monte Carlo Simulation)

  • 백철하;이승재;김대홍
    • 한국방사선학회논문지
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    • 제12권3호
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    • pp.289-295
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    • 2018
  • 대부분의 진단용 방사선 장치는 엑스선을 사용하며, 엑스선은 다양한 에너지를 갖는 스펙트럼을 갖는다. 진단 영상에서 엑스선의 정량적 및 정성적 분석은 선량을 줄이면서 영상 화질을 유지하는데 필수적이다. 본 연구의 목적은 진단 영상에 사용되는 엑스선 스펙트럼을 몬테칼로 시뮬레이션으로 측정하는 것이다. 다양한 엑스선 에너지 스펙트럼이 몬테칼로 시뮬레이션으로 측정되었다. 이 스펙트럼들은 다항식을 보간 한 양극 텅스텐 모델에 의해 계산된 결과와 비교하였다. 엑스선 관전압은 50, 60, 80, 100, 110 kV 였다. 검출기로는 카드뮴 텔루라이드와 비정질 셀레늄 물질을 사용하였다. 엑스선 에너지 스펙트럼의 시뮬레이션 결과는 참조 결과와 일치하였고, NRMSD 값은 최소 1.1%에서 최대 5.7%를 보였다. 시뮬레이션 결과에 의하면 진단 영상을 획득할 때 적절한 관전압의 선택을 가능하게 할 것이다. 또한, 영상 획득 전 환자에 전달되는 선량을 예측하는데 기여할 것이다.

GC/MS와 data system을 이용한 한국산 향끽미종 잎담배의 정유성분 분석 (Analysis of Essential Oils from Korean Aromatic Tobacco Varieties by GC/MS and data system.)

  • 박진우;이운철;김용태;허일
    • 한국연초학회지
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    • 제4권1호
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    • pp.61-66
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    • 1982
  • Essential oil components were isolated from Korean aromatic tobaccos by using a simultaneous distillation and extraction apparatus. The essential oils were analyzed by GC/M S and date system. Forty-two volatile components were identified on the basis of their mass spectra. Determination of contents of essential oil components from Hyangcho and Sohyang was achieved by pseudo-multiple ion selection (Ml S) technique. Varietal differences were detected from the quantitative comparison of the MIS data.

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ESSENTIAL SPECTRUM OF A WEIGHTED GEOMETRIC REALIZATION

  • Hatim, Khalid;Baalal, Azeddine
    • Nonlinear Functional Analysis and Applications
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    • 제26권4호
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    • pp.701-716
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    • 2021
  • In this present article, we construct a new framework that's we call the weighted geometric realization of 2 and 3-simplexes. On this new weighted framework, we construct a nonself-adjoint 2-simplex Laplacian L and a self-adjoint 2-simplex Laplacian N. We propose general conditions to ensure sectoriality for our new nonself-adjoint 2-simplex Laplacian L. We show the relation between the essential spectra of L and N. Finally, we prove the absence of the essential spectrum for our 2-simplex Laplacians L and N.

A New Iron Emission Template for Active Galactic Nuclei

  • Park, Daeseong;Barth, Aaron J.;Ho, Luis C.;Laor, Ari
    • 천문학회보
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    • 제44권2호
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    • pp.36.2-36.2
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    • 2019
  • Fe II emission is a prominent and ubiquitous feature in the spectra of broad-line Active Galactic Nuclei (AGN) by producing a pseudo-continuum from UV to optical with complex and strong blends of the numerous emission lines themselves, other emission lines, and continuum. Since theoretical modeling of such intricate Fe II emission is very difficult and still far from able to reproduce observed data in detail, an empirical iron emission template, derived from observations of a narrow-line Seyfert 1 galaxy, is an essential and practical tool to obtain accurate measurements of all the emission lines and continuum in AGN spectra. However, the existing iron templates, based on the single prototypical strong Fe II emitter I Zw 1, are suffering from inadequate S/N and non-simultaneous, inconsistent data with limited wavelength coverage, which consequently limit the accuracy of all the spectral measurements. To overcome the limitations and construct an improved iron template with wide spectral coverage, high-quality UV and optical spectra for the new and better identified template galaxy, Mrk 493, were successfully obtained from our HST STIS program (GO-14744). We will show the preliminary results for multicomponent spectral decomposition of the data and template construction with application tests to various AGN spectra and comparison with previous templates.

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A SIGNATURE OF CHROMOSPHERIC ACTIVITY IN BROWN DWARFS: A RECENT RESULT FROM NIRLT MISSION PROGRAM

  • Sorahana, Satoko;Suzuki, Takeru K.;Yamamura, Issei
    • 천문학논총
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    • 제32권1호
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    • pp.131-133
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    • 2017
  • We present the latest results from the Mission Program NIRLT (PI: I.Yamamura), the near-infrared spectroscopy of brown dwarfs using the AKARI/IRC grism mode with the spectral resolution of ~ 120. The near-infrared spectra in the wavelength range between 2.5 and $5.0{\mu}m$ are especially important to study the brown dwarf atmospheres because of the presence of major molecular bands, including $CH_4$ at $3.3{\mu}m$, $CO_2$ at $4.2{\mu}m$, CO at $4.6{\mu}m$, and $H_2O$ around $2.7{\mu}m$. We observed 27 sources, and obtained 16 good spectra. Our model fitting reveals deviations between theoretical model and observed spectra in this wavelength range, which may be attributed to the physical condition of the upper atmosphere. The deviations indicate additional heating, which we hypothesize to be due to chromospheric activity. We test this effect by modifying the brown dwarf atmosphere model to artificially increase the temperature of the upper atmosphere, and compare the revised model with observed spectra of early- to mid-L type objects with $H{\alpha}$ emission. We find that the chemical structure of the atmosphere changes dramatically, and the heating model spectra of early-type brown dwarfs can be considerably improved to match the observed spectra. Our result suggests that chromospheric activity is essential to understand early-type brown dwarf atmospheres.

Multichannel Quantum Defect Theory Analysis of Overlapping Resonance Structures in Lu-Fano Plots of Rare Gas Spectra

  • Lee, Chun-Woo;Kong, Ja-Hyun
    • Bulletin of the Korean Chemical Society
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    • 제30권8호
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    • pp.1783-1792
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    • 2009
  • Although overlapping resonances have been studied extensively in conventional resonance theories, there have not been many studies on them in multichannel quantum defect theories (MQDT). In MQDT, overlapping resonances occur between the channels instead of states, which pose far greater difficulty. Their systematic treatment was obtained for cases involving degenerate closed channels by applying our previous theory, which decouples background scattering from the resonance scattering in the MQDT formulation. The use of mathematical theory on con-diagonalization and con-similarity was essential for handling the non-Hermitian symmetric complex matrix. Overlapping resonances in rare gas spectra of Ar, Kr and Xe were analyzed using this theory and the results were compared with the ones of the previous alternative parameterizations of MQDT which make the open-open part $K^{oo}$ and closed-closed part $K^{cc}$ of reactance submatrices zero. The comparison revealed that separation of background and resonance scatterings achieved in our formulation in a systematic way was not achieved in the representation of $K^{oo}\;=\;0\;and\;K^{cc}$ = 0 when overlapping resonances are present.

펄스 플라즈마 제트내에 있는 구리원자의 발광 스펙트럼 정밀 보정 (Precise correction of the copper emission spectra from the pulsed plasma jet)

  • 김종욱;고동섭;오승묵
    • 한국광학회지
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    • 제12권2호
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    • pp.115-120
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    • 2001
  • 본 연구는 고온 고압의 전열(electrothermal)플라즈마내에 존재하는 구리원자의 발광 스펙트럼을 정량적으로 분석하는 방법에 대해 논하였다. 플라즈마는 플라즈마 발생장치내에 설치되어 있는 모세관 양단의 두 개의 전극이 방전함으로써 발생하며 고속으로 대기를 향해 전파해 나간다. 플라즈마의 특성을 분석하기 위해서는 플라즈마의 여기온도나 전자밀도와 같은 물리량의 측정이 필요하다. 그러나 여기온도나 전자밀동와 직접적으로 관련이 있는 발광 스펙트럼은 분광시스템의 파장에 따른 서로다른 응답 특성 때문에 왜곡되어질 수 있다 따라서 본 연구에서는 펄스 플라즈마 제트로부터 얻은 구리원자의 발광 스펙트럼을 정밀하게 보정하는 방법을 제시하였다.

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도계육 표면 내장 잔유물 오염 검사를 위한 형광 조사 및 방출파장 선정에 관한 연구 (Study on Fluorescence Excitation and Emission Bands for Detection of Fecal Residue on Poultry Carcasses)

  • 조병관;김문성
    • Journal of Biosystems Engineering
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    • 제33권2호
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    • pp.136-141
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    • 2008
  • Fecal contaminations on poultry carcasses, not easily discemable by human eyes, are potential harbor sites of pathogenic Escherichia Coli (E. coli O157:H7). Development of sensitive detection methods for fecal contamination is essential to ensure safe production of poultry products. Fluorescence has been shown to be very sensitive in detecting fecal and other biological substances that can harbor pathogens. In this study, fluorescence excitation-emission spectra of poultry fecal matter were compared with spectra for poultry skin and meat. Results indicated that the combinations of fluorescence intensities at the wavelength of 520 nm, 579 nm, 625 nm, and 635 nm with 411 nm excitation showed above 97% accuracy for differentiation of the contaminants from poultry tissues. Excitation and emission bands determined could be used for constructing a real-time fluorescence imaging device for detection of harmful residues on poultry carcasses.