• 제목/요약/키워드: equilibrium temperature

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Thermodynamic non-equilibrium and anisotropy in Mars atmosphere entry

  • Zuppardi, Gennaro
    • Advances in aircraft and spacecraft science
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    • 제8권1호
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    • pp.1-15
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    • 2021
  • Mars exploration demands aerodynamic computations for a proper design of missions of spacecraft carrying instruments and astronauts to Mars. Both Computational Fluid Dynamics (CFD) and Direct Simulation Monte Carlo (DSMC) method play a key role for this purpose. To the author's knowledge, the altitude separating the fields of applicability of CFD and DSMC in Mars atmosphere entry is not yet clearly defined. The limitations in using DSMC at low altitudes are due to technical limitations of the computer. The limitations in using CFD at high altitudes are due to thermodynamic non-equilibrium. Here, this problem is studied in Mars atmosphere entry, considering the Mars Pathfinder capsule in the altitude interval 40-80 km, by means of a DSMC code. Non-equilibrium is quantified by the relative differences between translational temperature and: rotational (θt-r), vibrational (θt-v), overall (θt-ov) temperatures, anisotropy is quantified by the relative difference between the translational temperature component along x and those along y (θx-y) and along z (θx-z). The results showed that θt-r, θt-v, θx-y, θx-z are almost equivalent. The altitude of 45 km should be the limit altitude for a proper use of a CFD code and the altitude of 40 km should be the limit altitude for a reasonable use of a DSMC code.

평형상수를 이용한 액체로켓 추진제의 화학반응 수치연구 (Numerical Study of Chemical Reaction for Liquid Rocket Propellant Using Equilibrium Constant)

  • 장요한;이균호
    • 한국항공우주학회지
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    • 제44권4호
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    • pp.333-342
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    • 2016
  • 액체로켓 추진시스템은 액체 추진제와 액체 산화제의 화학반응을 통해 추력을 발생하는 방식으로써 우주발사체 및 인공위성을 포함한 우주비행체에 광범위하게 적용되고 있다. 일반적으로 사용되는 액체로켓 추진제로는 모노메틸하이드라진/사산화이질소, 액체수소/액체산소 및 RP-1/액체산소 조합 등이 있다. 본 연구의 목적은 액체로켓 추진제의 열화학적 반응을 수치적으로 분석함으로써, 이를 통해 궁극적으로 액체로켓엔진의 설계와 성능에 필요한 유용한 정보를 예측하고자 하는 데 있다. 이를 위해 앞서 언급한 3가지 조합의 연료와 산화제에 대하여 연소반응 후 화학평형상태에 도달했을 때 주요 요소평형반응들의 평형상수 값들을 이용해 최종 생성물의 성분과 화학조성을 계산하였고 그 결과를 이용해 단열화염온도와 로켓성능변수인 비추력을 예측하는 연구를 진행하였다.

분자동역학법을 이용한 기액계면현상에 관한 연구 (A Study on the Phenomena at a Liquid-Vapor Interface by the Molecular Dynamics Method)

  • 최현규;송치성;김혜민;이정혜;최순호
    • 대한기계학회논문집B
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    • 제29권1호
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    • pp.159-168
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    • 2005
  • In recent studies, it was reported that there existed the temperature discontinuity at a liquid-vapor interface in an equilibrium state. However, from the viewpoint of the classical thermodynamics, it is highly questionable result although considering that the experiments related with a boundary layer is very difficult due to the extremely thin thickness of it. To clarify whether the temperature discontinuity over a liquid-vapor interface really exists, the computer simulations were performed. From the simulation results, it could be concluded that the misconception in a temperature calculation might result in non-uniform temperature distributions over an interface under an equilibrium state.

Sulfur Redox Equilibrium in Mixed Alkali Silicate Glass Melts

  • Kim, Ki-Dong;Hwang, Jong-Hee
    • 한국세라믹학회지
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    • 제48권3호
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    • pp.205-210
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    • 2011
  • The dependence of sulfur redox behavior and its diffusivity on temperature and composition was studied in mixed alkali silicate melts by means of square wave voltammetry (SWV) at different frequencies in a temperature range of $1000^{\circ}C$ to $1400^{\circ}C$. The voltammograms showed two reduction peaks at high frequency but only one peak at low frequency. Irrespective of $K_2O/(Na_2O+K_2O)$, each peak potential due to reduction of $S^{6+}$ to $S^{4+}$ and $S^{4+}$ to $S^0$ moved toward a negative direction with temperature decrease, and the peak current showed a strong dependence on frequency at a constant temperature. However, the compositional dependence of the peak potential showed an inconsistent behavior with an increase of $K_2O$. The mixed alkali effect was not observed in sulfur diffusion. This inconsistency of both peak potential and diffusion for compositional dependence may be derived from the strong volatilization of sulfur in melts.

수중 마그네슘이온의 안정영역 변화에 대한 온도효과 (The Effect of Temperature on the Stable Region of Magnesium Ion in Aqueous System)

  • 김희진;김동수
    • 한국물환경학회지
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    • 제27권4호
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    • pp.438-444
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    • 2011
  • Magnesium is one of the abundant natural resources in the earth crust and seawater, which is directly related to various organisms activities interconnecting with water-rock system. In aqueous system, magnesium is known to predominantly exist in the form of $Mg^{2+}$ ion which is verified in its $E_h-pH$ diagram. When it is at equilibrium in aqueous system, temperature takes an essential role to complete equilibrium states. This study represents the change of the stable region of magnesium ion according to temperature, and how the consequences would affect aquatic organisms. It was revealed that there is a noticeable tendency shrinking the stable region of magnesium ion in a diagram as temperature increases, and as a result, aquatic bio-species presumably have difficulties to absorb the nutrient. Also, it was considered that the water system would be acidified by decreasing alkalinity.

해상 담수화 공장에서 배출되는 고온고염 해수의 확산예측 (Dispersion of High Temperature and High Salinity Water Discharged from Offshore Desalination Plant)

  • 이문진;홍기용
    • 한국해양환경ㆍ에너지학회지
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    • 제3권2호
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    • pp.33-40
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    • 2000
  • 해상에 설치되는 담수화 공장의 가동에 따른 환경영향평가를 위하여 고온고염 배출수의 확산을 예측하였다. 진해만에 설치될 담수화 공장에서는 200ton/일의 해수를 유입하여 50ton은 담수화 하고 150ton은 고온고염수로서 배출한다. 배출되는 해수의 수온은 15℃ 상승되며, 염분은 약 1.33배 증가된다. 배출수의 확산예측에서는 2차원 조류모델로 이류를 계산하며, 몬테카르로 방법으로 난류확산을 재현한다. 배출수에 의한 수온상승의 예측에서는 대기를 통한 열량 방출을 감소요인으로 고려하였으며, 100일간의 계산을 통하여 평형상태의 확산분포를 재현하였다. 고염수에 의한 확산에서는 감쇠가 없는 것으로 간주하였으며, 약 1년간의 계산을 통하여 평형상태의 확산분포를 재현하였다. 평형상태에서 배출수에 의한 수은상승과 염분상승은 배수구 근처에 국한되어 나타났으며, 각각 약 0.01℃와 0.001‰의 상승폭을 보였다.

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조직모델에서 냉.온치료기의 열전달 특성 비교 연구 (A Comparative Study on Heat Transfer Characteristics in Tissue Model with Application of Heating or Cooling Therapeutic Modalities)

  • 김유종;신경민;김은정;김경호;김갑성;이승덕
    • Journal of Acupuncture Research
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    • 제30권4호
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    • pp.125-138
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    • 2013
  • Objectives : This study aimed to investigate temperature characteristics by heat transfer type of therapeutic modalities. Methods : We selected heating and cooling modalities that are frequently used in clinical by heat transfer type: conduction, convection, radiation, and conversion. We used ham as tissue model, and applied the modalities for 30 minutes. We measured real-time changed temperature($^{\circ}C$) of the surface, 2, 4, 6, 8, 10, 12, and 14 mm depth. Results : 1. In conduction-using hot pack, ice pack, and CryoStamp heating-cooling combination therapy unit($40^{\circ}C/{\sim}15^{\circ}C$), the surface temperature sharply rose close to equilibrium in first 5 minutes. 2. In convection-using smokeless moxa, temperature slowly rose to the maximum at 25-minute elapsed time. But in another convection-using CRAiS cryotherapy device, result was similar to that of conduction. 3. In radiation-using infrared lamp, result was similar to that of conduction, but not reached equilibrium during applying time. 4. In conversion-using ultrasound device, temperature was the highest at 6 mm depth, and not reached equilibrium during applying time. Conclusions : We could comprehend temperature characteristics and proper use of modalities by heat transfer type. It would be necessary to consider in vivo physical conditions in further studies.

AN EXPERIMENTAL STUDY ON POST-CHF HEAT TRANSFER FOR LOW FLOW OF WATER IN A $3\times3$ ROD BUNDLE

  • MOON SANG-KI;CHUN SE-YOUNG;CHO SEOK;KIM SE-YUN;BAEK WON-PIL
    • Nuclear Engineering and Technology
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    • 제37권5호
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    • pp.457-468
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    • 2005
  • An experimental study on post-CHF heat transfer has been performed with a $3\times3$ rod bundle using a vertical steam-water two-phase flow at low flow conditions. The effects of various parameters on the post-CHF heat transfer are investigated and the reasons for the parametric effects are discussed. As the heat transfer regime changes from CHF to post-CHF, the radial wall temperature distribution is changed depending on the pressure and the mass flux conditions. The superheat of the fluid increases considerably with an increase of the wall temperature (or heat flux) and with a decrease of the mass flux. This implies, indirectly, a strong thermal non-equilibrium at high wall temperature and low mass flux conditions. In order to improve the prediction accuracy of the existing post-CHF correlations, it is necessary to perform more experiments, particularly direct measurement of the vapor superheat, and to modify the correlation by considering a strong thermal non-equilibrium at low flow and low pressure conditions.

Electrochemical Approach in Plasma Display Panel Glass Melts doped with Sulfate and Sulfide I. Oxygen Equilibrium Pressure

  • Kim, Ki-Dong;Kim, Hyo-Kwang
    • 한국세라믹학회지
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    • 제45권2호
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    • pp.90-93
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    • 2008
  • The oxygen gas behavior in PDP (plasma Display Panel) glass melts doped with sulfate ($SO_4^{-2}$) or blast furnace slag (BFS, $S^{2-}$) or both by means of yttria-stabilized zirconia (YSZ) electrodes was observed after the first fining. The temperature dependence of oxygen equilibrium pressure ($P_{O2}$) in each melt showed typical behavior, namely $P_{O2}$ decreased as temperature decreased. This suggests that an oxidation of $S^{4+}$ to $S^{6+}$ took place. However, the $P_{O2}$-value at constant temperature increased in the following order: BFS$P_{O2}$ of the melt doped with sulfate+BFS was much lower than that of the melt with only sulfate, although only 10% of sulfur was added by the BFS. This behavior can be explained by the redox reaction between sulfide ions in the BFS and dissolved oxygen ions in the melt during the first fining.

저장상대습도 및 온도에 따른 분말고추의 흡습특성(吸濕特性) (Sorption Characteristics of Red Pepper Powder with Relative Humidity and Temperature)

  • 김현구;박무현;민병용;서기봉
    • 한국식품과학회지
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    • 제16권1호
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    • pp.108-112
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    • 1984
  • 분말고추를 상대습도 11%에서 84%까지 8단계의 RH조건별로 $15^{\circ}C,{\;}25^{\circ}C$$35^{\circ}C$ 온도구에 저장하면서 분말고추의 흡온특성(吸溫特性)을 조사하였다. 저장시간에 따른 분말고추의 흡습곡선은 RH57% 이하에서는 단시간내에 평형에 도달하여 수분함량의 변화가 거의 없었으나 RH75% 이상에서는 평형수분함량이 급격히 증가하여 갈변현상이 발생하였다. 분말고추의 단분자층(單分子層)의 수분함량은 온도에 따라서 11.32%에서 12.13%로서 온도가 하강함에 따라 다소 증가하는 경향을 보였으며 상대습도에 따라서 평형수분함량을 예측할 수 있는 1차 회귀방정식을 도출하였다

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