• Title/Summary/Keyword: equilibrium temperature

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Thermodynamic non-equilibrium and anisotropy in Mars atmosphere entry

  • Zuppardi, Gennaro
    • Advances in aircraft and spacecraft science
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    • v.8 no.1
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    • pp.1-15
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    • 2021
  • Mars exploration demands aerodynamic computations for a proper design of missions of spacecraft carrying instruments and astronauts to Mars. Both Computational Fluid Dynamics (CFD) and Direct Simulation Monte Carlo (DSMC) method play a key role for this purpose. To the author's knowledge, the altitude separating the fields of applicability of CFD and DSMC in Mars atmosphere entry is not yet clearly defined. The limitations in using DSMC at low altitudes are due to technical limitations of the computer. The limitations in using CFD at high altitudes are due to thermodynamic non-equilibrium. Here, this problem is studied in Mars atmosphere entry, considering the Mars Pathfinder capsule in the altitude interval 40-80 km, by means of a DSMC code. Non-equilibrium is quantified by the relative differences between translational temperature and: rotational (θt-r), vibrational (θt-v), overall (θt-ov) temperatures, anisotropy is quantified by the relative difference between the translational temperature component along x and those along y (θx-y) and along z (θx-z). The results showed that θt-r, θt-v, θx-y, θx-z are almost equivalent. The altitude of 45 km should be the limit altitude for a proper use of a CFD code and the altitude of 40 km should be the limit altitude for a reasonable use of a DSMC code.

Numerical Study of Chemical Reaction for Liquid Rocket Propellant Using Equilibrium Constant (평형상수를 이용한 액체로켓 추진제의 화학반응 수치연구)

  • Jang, Yo Han;Lee, Kyun Ho
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.44 no.4
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    • pp.333-342
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    • 2016
  • Liquid rocket propulsion is a system that produces required thrust for satellites and space launch vehicles by using chemical reactions of a liquid fuel and a liquid oxidizer. Monomethylhydrazine/dinitrogen tetroxide, liquid hydrogen/liquid oxygen and RP-1/liquid oxygen are typical combinations of liquid propellants commonly used for the liquid rocket propulsion system. The objective of the present study is to investigate useful design and performance data of liquid rocket engine by conducting a numerical analysis of thermochemical reactions of liquid rocket propellants. For this, final products and chemical compositions of three liquid propellant combinations are calculated using equilibrium constants of major elementary equilibrium reactions when reactants remain in chemical equilibrium state after combustion process. In addition, flame temperature and specific impulse are estimated.

A Study on the Phenomena at a Liquid-Vapor Interface by the Molecular Dynamics Method (분자동역학법을 이용한 기액계면현상에 관한 연구)

  • Choi, Hyun-Kue;Song, Chi-Sung;Kim, Hye-Min;Lee, Jung-Hye;Choi, Soon-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.1 s.232
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    • pp.159-168
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    • 2005
  • In recent studies, it was reported that there existed the temperature discontinuity at a liquid-vapor interface in an equilibrium state. However, from the viewpoint of the classical thermodynamics, it is highly questionable result although considering that the experiments related with a boundary layer is very difficult due to the extremely thin thickness of it. To clarify whether the temperature discontinuity over a liquid-vapor interface really exists, the computer simulations were performed. From the simulation results, it could be concluded that the misconception in a temperature calculation might result in non-uniform temperature distributions over an interface under an equilibrium state.

Sulfur Redox Equilibrium in Mixed Alkali Silicate Glass Melts

  • Kim, Ki-Dong;Hwang, Jong-Hee
    • Journal of the Korean Ceramic Society
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    • v.48 no.3
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    • pp.205-210
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    • 2011
  • The dependence of sulfur redox behavior and its diffusivity on temperature and composition was studied in mixed alkali silicate melts by means of square wave voltammetry (SWV) at different frequencies in a temperature range of $1000^{\circ}C$ to $1400^{\circ}C$. The voltammograms showed two reduction peaks at high frequency but only one peak at low frequency. Irrespective of $K_2O/(Na_2O+K_2O)$, each peak potential due to reduction of $S^{6+}$ to $S^{4+}$ and $S^{4+}$ to $S^0$ moved toward a negative direction with temperature decrease, and the peak current showed a strong dependence on frequency at a constant temperature. However, the compositional dependence of the peak potential showed an inconsistent behavior with an increase of $K_2O$. The mixed alkali effect was not observed in sulfur diffusion. This inconsistency of both peak potential and diffusion for compositional dependence may be derived from the strong volatilization of sulfur in melts.

The Effect of Temperature on the Stable Region of Magnesium Ion in Aqueous System (수중 마그네슘이온의 안정영역 변화에 대한 온도효과)

  • Kim, Hee-Jin;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.27 no.4
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    • pp.438-444
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    • 2011
  • Magnesium is one of the abundant natural resources in the earth crust and seawater, which is directly related to various organisms activities interconnecting with water-rock system. In aqueous system, magnesium is known to predominantly exist in the form of $Mg^{2+}$ ion which is verified in its $E_h-pH$ diagram. When it is at equilibrium in aqueous system, temperature takes an essential role to complete equilibrium states. This study represents the change of the stable region of magnesium ion according to temperature, and how the consequences would affect aquatic organisms. It was revealed that there is a noticeable tendency shrinking the stable region of magnesium ion in a diagram as temperature increases, and as a result, aquatic bio-species presumably have difficulties to absorb the nutrient. Also, it was considered that the water system would be acidified by decreasing alkalinity.

Dispersion of High Temperature and High Salinity Water Discharged from Offshore Desalination Plant (해상 담수화 공장에서 배출되는 고온고염 해수의 확산예측)

  • Lee Moonjin;Hong Keyyong
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.3 no.2
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    • pp.33-40
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    • 2000
  • Dispersion of high temperature and high salinity water discharged from a desalination plant is numerically estimated to investigate its impact on marine environment. The plant is installed on a floating barge located in Jinhae Bay and takes 200 tons of seawater per day. Fifty tons of intake are changed into fresh water, while 150 tons of those are discharged as the water of 15℃ warmer and 1.33 times saltier than surrounding seawater. In this dispersion model, advection is described by two-dimensional tidal currents and turbulent diffusion is simulated by Monte Carlo technique. Decay of water temperature is modelled by heat exchange between the atmosphere and the ocean, while decay of water salinity is ignored. The distributions of temperature and salinity come to equilibrium when the dispersion model is run for 100 days for temperature and for 365 days for salinity, respectively. At equilibrium state the water temperature and salinity rise 0.01℃ and 0.001‰ higher than ambient seawater, respectively.

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A Comparative Study on Heat Transfer Characteristics in Tissue Model with Application of Heating or Cooling Therapeutic Modalities (조직모델에서 냉.온치료기의 열전달 특성 비교 연구)

  • Kim, Yu Jong;Shin, Kyung Min;Kim, Eun Jung;Kim, Kyung Ho;Kim, Kap Sung;Lee, Seung Deok
    • Journal of Acupuncture Research
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    • v.30 no.4
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    • pp.125-138
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    • 2013
  • Objectives : This study aimed to investigate temperature characteristics by heat transfer type of therapeutic modalities. Methods : We selected heating and cooling modalities that are frequently used in clinical by heat transfer type: conduction, convection, radiation, and conversion. We used ham as tissue model, and applied the modalities for 30 minutes. We measured real-time changed temperature($^{\circ}C$) of the surface, 2, 4, 6, 8, 10, 12, and 14 mm depth. Results : 1. In conduction-using hot pack, ice pack, and CryoStamp heating-cooling combination therapy unit($40^{\circ}C/{\sim}15^{\circ}C$), the surface temperature sharply rose close to equilibrium in first 5 minutes. 2. In convection-using smokeless moxa, temperature slowly rose to the maximum at 25-minute elapsed time. But in another convection-using CRAiS cryotherapy device, result was similar to that of conduction. 3. In radiation-using infrared lamp, result was similar to that of conduction, but not reached equilibrium during applying time. 4. In conversion-using ultrasound device, temperature was the highest at 6 mm depth, and not reached equilibrium during applying time. Conclusions : We could comprehend temperature characteristics and proper use of modalities by heat transfer type. It would be necessary to consider in vivo physical conditions in further studies.

AN EXPERIMENTAL STUDY ON POST-CHF HEAT TRANSFER FOR LOW FLOW OF WATER IN A $3\times3$ ROD BUNDLE

  • MOON SANG-KI;CHUN SE-YOUNG;CHO SEOK;KIM SE-YUN;BAEK WON-PIL
    • Nuclear Engineering and Technology
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    • v.37 no.5
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    • pp.457-468
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    • 2005
  • An experimental study on post-CHF heat transfer has been performed with a $3\times3$ rod bundle using a vertical steam-water two-phase flow at low flow conditions. The effects of various parameters on the post-CHF heat transfer are investigated and the reasons for the parametric effects are discussed. As the heat transfer regime changes from CHF to post-CHF, the radial wall temperature distribution is changed depending on the pressure and the mass flux conditions. The superheat of the fluid increases considerably with an increase of the wall temperature (or heat flux) and with a decrease of the mass flux. This implies, indirectly, a strong thermal non-equilibrium at high wall temperature and low mass flux conditions. In order to improve the prediction accuracy of the existing post-CHF correlations, it is necessary to perform more experiments, particularly direct measurement of the vapor superheat, and to modify the correlation by considering a strong thermal non-equilibrium at low flow and low pressure conditions.

Electrochemical Approach in Plasma Display Panel Glass Melts doped with Sulfate and Sulfide I. Oxygen Equilibrium Pressure

  • Kim, Ki-Dong;Kim, Hyo-Kwang
    • Journal of the Korean Ceramic Society
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    • v.45 no.2
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    • pp.90-93
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    • 2008
  • The oxygen gas behavior in PDP (plasma Display Panel) glass melts doped with sulfate ($SO_4^{-2}$) or blast furnace slag (BFS, $S^{2-}$) or both by means of yttria-stabilized zirconia (YSZ) electrodes was observed after the first fining. The temperature dependence of oxygen equilibrium pressure ($P_{O2}$) in each melt showed typical behavior, namely $P_{O2}$ decreased as temperature decreased. This suggests that an oxidation of $S^{4+}$ to $S^{6+}$ took place. However, the $P_{O2}$-value at constant temperature increased in the following order: BFS$P_{O2}$ of the melt doped with sulfate+BFS was much lower than that of the melt with only sulfate, although only 10% of sulfur was added by the BFS. This behavior can be explained by the redox reaction between sulfide ions in the BFS and dissolved oxygen ions in the melt during the first fining.

Sorption Characteristics of Red Pepper Powder with Relative Humidity and Temperature (저장상대습도 및 온도에 따른 분말고추의 흡습특성(吸濕特性))

  • Kim, Hyun-Ku;Park, Mu-Hyun;Min, Byong-Yong;Suh, Kee-Bong
    • Korean Journal of Food Science and Technology
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    • v.16 no.1
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    • pp.108-112
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    • 1984
  • The sorption characteristics of red pepper powder stored at various relative humidity and temperature were studied. At low relative humidity below RH 57%, the sorption equilibrium was easily attained, whereas at higher relative humidity above RH 75%, the powder was browned by higher equilibrium moisture content. The moisture content of monolayer value for the powder was ranging from 11.32% to 12.13% with temperature. First order regression equation of equilibrium moisture content for relative humidity was determined.

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