• Journal of Korean Society for Atmospheric Environment
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• v.16 no.2
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• pp.113-120
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• 2000

Effects of sea-salts on the properties of aerosol collected in a coastal region were studied by applying a gas-particle equilibrium model SCAPE to the measurement data from Korea Cheju Island in summer 1994. It was found that the observed higher ammonium concentrations in fine particles (PM2.5) than in TSP were caused by forced evaporation of ammonium in coarse fraction of aerosol by sea-salts and the degree of evaporation was quantified through an application of SCAPE. By subtracting the sea-salt fraction from the measured concentra-tions the changes of aerosol property were also studied. The concentrations of nitrate at both TSP and PM2.5 decreased when alkaline sea-salt fraction was removed from the measured data. Estimates of aerosol acidity increased for most samples with sea salt loadings, However in some cases with high mass fractions of sea-salt components the aerosol acidity of PM2.5 decreased slightly. This is though to be related with the formation of solid salt with the removal of sea-salts.

• The Transactions of the Korean Institute of Electrical Engineers
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• v.45 no.3
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• pp.415-425
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• 1996

This study presents an analytical method of solving the behaviors of arc plasma in a nozzle constricting transferred-type torch and purposes to obtain the basic data for the design of a plasma torch, which can be obtained from the temperature, pressure, velocities and voltage distributions. We have to solve some conservation equations simultaneously and need to know the exact thermal gas properties in order to obtain the correct behaviors of arc plasma. It is also necessary to give the relevant physical or geometric boundary conditions. For the simplicity of analysis, we assumed that (a) the plasma flow is laminar, (b)the local thermodynamic equilibrium, i.e. LTE, prevails over the entire arc column region. The electrode sheath effects were neglected and the nozzle area was excluded from the analysis by assuming that the current flow into the nozzle is zero. We solved the momentum transfer equation including the self-magnetic pinch effect, and obtained the temperature distribution from the energy conservation equation. From this temperature, we could get arc voltage distribution. (author). refs., figs., tabs.

• Journal of the Korean Institute of Gas
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• v.3 no.3 s.8
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• pp.34-38
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• 1999

To propose a model equation, an acetic acid and n-heptane binary vapor liquid equilibrium system were investigated at 298.15K and 318.15K. Pressure was theoretically estimated using an association model based on the chemical theory, in conjunction with Margules, Wilson, NRTL models. Results were compared with those of calculated values without considering association. The theoretically calculated results of association model equations show a good agreement with the experimentally observed values.

• 한국전산유체공학회:학술대회논문집
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• 1999.05a
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• pp.29-34
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• 1999

A two-dimensional Navier-Stokes code based on AUSMPW+ scheme has been developed to simulate the hypersonic flowfield of hypersonic shock-shock interaction. AUSMPW+ scheme is a new hybrid flux splitting scheme, which is improved by introducing pressure-based weight functions to eliminate the typical drawbacks of AUSM-type schemes, such as non-monotone pressure solutions. To study the real gas effects, three different gas models are taken into account in this paper: perfect gas, equilibrium flow and nonequilibrium flow. It has been investigated how each gas model influences on the peak surface loading, such as wall pressure and wall heat transfer, and unsteady flowfield structure in the region of shock-shock interaction. With the results, the value of peak pressure is not sensitive to the real gas effects nor to the wall catalyticity. However, the value of peak heat transfer rates is affected by the real gas effects and the wall catalyticity. The structure of the flowfield also changes drastically in the presence of real gas effects.

• 한국가스학회:학술대회논문집
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• no.5
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• pp.171-174
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• 2002

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.6
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• pp.660-669
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• 2012

Gas resources captured in the form of gas hydrates are an order of magnitude larger than the resources available from conventional resources. Focus of this research is to investigate the effect of DME on phase equilibria of methane hydrate, as well as the possibility of the use of the PRO/II computer simulation to estimate the phase equilibria. In systems containing water and a gaseous component like, for instance, methane, ethane, and propane, gas hydrates may occur, if conditions in terms of pressure and temperature are satisfied. Mixtures of gases, e.g. LPG or natural gas, are also able to form gas hydrates in the presence of water. The experiments presented here were performed at temperatures varying between 268.15K and 288.15K and at pressures varying between 1.88 MPa and 10.56 MPa. It was found that the phase equilibria of methane hydrate is influenced by the addition of DME to the system. The pressure for the equilibrium hydrate-liquid water-vapor (H - $L_w$ - V) in the system water + methane is reduced upon addition of DME. The phase equilibria of methane hydrate can be estimated by the PRO/II computer simulation, whereas those of methane hydrate containing DME or LPG can't be estimated properly.

• Nuclear Engineering and Technology
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• v.44 no.1
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• pp.21-32
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• 2012

Fluorinated compounds mainly used in the semiconductor industry are potent greenhouse gases. Recently, thermal plasma gas scrubbers have been gradually replacing conventional burn-wet type gas scrubbers which are based on the combustion of fossil fuels because high conversion efficiency and control of byproduct generation are achievable in chemically reactive high temperature thermal plasma. Chemical equilibrium composition at high temperature and numerical analysis on a complex thermal flow in the thermal plasma decomposition system are used to predict the process of thermal decomposition of fluorinated gas. In order to increase economic feasibility of the thermal plasma decomposition process, increase of thermal efficiency of the plasma torch and enhancement of gas mixing between the thermal plasma jet and waste gas are discussed. In addition, noble thermal plasma systems to be applied in the thermal plasma gas treatment are introduced in the present paper.

• Environmental and Resource Economics Review
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• v.30 no.2
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• pp.169-205
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• 2021

This study quantitatively analyzes the impact of greenhouse gas (GHG) emissions reduction policies on the global economy. To this end, we develop a multi-national and multi-industry static computational general equilibrium model that includes three components-GHG emissions from production, disutility due to GHG emissions, and governments' GHG emissions reduction policies. Then we calibrate the model with the relevant data and solve for the equlibrium using the most recent methodology (exact hat algebra). We find that the strengthening of unilateral GHG emissions reduction policies for each country reduces carbon emissions from domestic producers, but does not necessarily reduce global carbon emissions as production is relocated to other countries. On the other hand, we can reduce GHG emissions when all major countries simultaneously implement the strengthened reduction policies proposed by the OECD (2016). Our results imply that aligned reduction efforts of major countries are necessary to reduce global GHG emissions.

• Korean Chemical Engineering Research
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• v.43 no.2
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• pp.259-265
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• 2005

Binary isothermal vapor-liquid equilibrium(VLE) data were measured for water+n-methylformamide(NMF), benzene+NMF and toluene+NMF systems by using headspace gas chromatography(HSGC) at 353.15K. Additionally, the ternary liquid-liquid Equilibrium(LLE) data were determined by measuring of tie-line for the systems of NMF+benzene+n-heptane and NMF+toluene+n-heptane at 298.15 K. The measured isothermal binary VLE data have no azeotropes and were correlated well with $g^E$ model equations of Margules, van Laar, Wilson, NRTL and UNIQUAC. The experimental ternary tie line data were also correlated well with NRTL and UNIQUAC models. Besides their accuracy was analyzed by Hirata-Fujita and Maior-Swenson equations.

• 한국연소학회:학술대회논문집
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• 2006.10a
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• pp.104-109
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• 2006

Improvements in internal combustion engine and aftertreatment technologies are needed to meet future environmental quality goals. Plasmatron fuel converters provide a rapid response, compact means to transform a wide range of hydrocarbon fuels (including gasoline, natural gas and diesel fuel) into hydrogen-rich gas. Hydrogen-rich gas can be used as an additive to provide NOx reductions of more than 80% in diesel engine vehicles by enabling very lean operation or heavy exhaust engine recirculation. For diesel engines, use of compact plasmatron reformers to produce hydrogen-rich gas for the regeneration of NOx absorber/absorbers and particulate traps for diesel engine exhaust after-treatment could provide significant advantages. Recent tests of conversion of diesel fuel to hydrogen-rich gas using a low current plasmatron fuel converter with non-equilibrium plasma features are described.