• Applied Chemistry for Engineering
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• v.30 no.2
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• pp.190-197
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• 2019

The adsorption of methyl green dye using an activated carbon from an aqueous solution was investigated. Adsorption experiments were carried out as a function of the adsorbent dose, initial concentration, contact time and temperature. The Langmuir isotherm model showed a good fit to the equilibrium adsorption data. Based on the estimated Langmuir separation factor, ($R_L=0.02{\sim}0.106$), this process could be employed as the effective treatment (0 < $R_L$ < 1). It was found that the adsorption was a physical process with the adsorption energy (E) value range between 316.869 and 340.049 J/mol obtained using Dubinin-Radushkevich equation. The isothermal saturation capacity obtained from brunauer emmett teller (BET) model increased with increasing the temperature. The kinetics of adsorption followed a pseudo second order model. The free energy and enthalphy values of -5.421~-7.889 and 31.915 kJ/mol, respectively indicated that the adsorption process follows spontaneous endothermic reaction. The isosteric heat of adsorption increased with the increase of equilibrium adsorption amounts, and the total interaction of the adsorbent - adsorbate increased as the surface coverage increased.

• Korean Journal of Metals and Materials
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• v.56 no.12
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• pp.870-877
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• 2018

Cyanex 272 shows the highest separation factor for the rare earth elements from hydrochloric acid solution among the organophosporus acidic extractants, D2EHPA and PC 88A. Solvent extraction of Tb(III) from weak hydrochloric acid solution with an initial pH 3 to 6 was compared with Cyanex 272, its mixture with Alamine 336, and ionic liquid with Aliquat 336. The solvent extraction reaction of Tb(III) using Cyanex 272 was the same as that of light rare earth elements. Synergism was observed for the extraction of Tb(III) by the mixture with Alamine 336 when the initial concentration ratio of Cyanex 272 to Alamine 336 was higher than 5. Use of the ionic liquid led to a great increase in the extraction percentage of Tb(III) from the same initial extraction conditions. While the equilibrium pH of the mixture was always lower than the initial pH, under some conditions extraction with the ionic liquid resulted in a higher equilibrium pH than the initial pH. The loading capacity of the mixture and the ionic liquid was the same and 2.6 times larger than that using Cyanex 272 alone. Ionic liquid was recommended as a suitable extractant for the extraction of Tb(III) from hydrochloric acid solution based on the ease of handling and higher extraction percentage.

• Structural Engineering and Mechanics
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• v.85 no.5
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• pp.593-605
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• 2023

This work presents a comparison between analytical and finite element analysis for bending of porous sandwich functionally graded material (FGM) plates. The plate is rectangular and simply supported under static sinusoidal loading. Material properties of FGM are assumed to vary continuously across the face sheets thickness according to a power-law function in terms of the volume fractions of the constituents while the core is homogeneous. Four types of porosity are considered. A refined higher-order shear with normal deformation theory is used. The number of unknowns in this theory is five, as against six or more in other shear and normal deformation theories. This theory assumes the nonlinear variation of transverse shear stresses and satisfies its nullity in the top and bottom surfaces of the plate without the use of a shear correction factor. The governing equations of equilibrium are derived from the virtual work principle. The Navier approach is used to solve equilibrium equations. The constitutive law of the porous FGM sandwich plate is implemented for a 3D finite element through a subroutine in FORTRAN (UMAT) in Abaqus software. Results show good agreement between the finite element model and the analytical method for some results, but the analytical method keeps giving symmetric results even with the thickness stretching effect and load applied to the top surface of the sandwich.

• Applied Chemistry for Engineering
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• v.24 no.2
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• pp.184-189
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• 2013

In the present study, batch experiments were carried out for the utilizatioin of activated carbon as a potential adsorbent to remove a hazardous malachite green from an aqueous solution. The effects of various parameters such as temperature, contact time, initial concentration on the adsorption system were investigated. On the basis of adsorption data Langmuir and Freundlich adsorption isotherm model were also confirmed. The equilibrium process was described well by Langmuir isotherm model. From determined separation factor, the activated carbon could be employed as an effective treatment for removal of malachite green. From kinetic experiments, the adsorption process followed the pseudo second order model, and the adsorption rate constant ($k_2$) decreased with increasing both the initial concentration of malachite green and the adsoprtion temperature. Thermodynamic parameters like that activation energy, change of free energy, enthalpy, and entropy were also calculated to predict the adsorption nature. The activation energy calculated from Arrhenius equation indicated that the adsortpion of malachite green on the zeolite was physical process. The negative Gibbs free energy change ($\Delta$G = -3.68~-7.76 kJ/mol) and the positive enthalpy change ($\Delta$H = +26.34 kJ/mol) indicated the spontaneous and endothermic nature of the adsorption in the temperature range of 298~318 K.

• Journal of the Korean Geotechnical Society
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• v.30 no.4
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• pp.35-45
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• 2014

Limit equilibrium methods of slope stability analysis have been widely adopted mainly due to their simplicity and applicability. However, the conventional methods may not give reliable and convincing results for various geological conditions such as nonhomogeneous and anisotropic soils. Also, they do not take into account soil slope history nor the initial state of stress, for example excavation or fill placement. In contrast to the limit equilibrium analysis, the analysis of deformation and stress distribution by finite element method can deal with the complex loading sequence and the growth of inelastic zone with time. This paper proposes a technique to determine the critical slip surface as well as to calculate the factor of safety for shallow failure on partially saturated soil slope. Based on the effective stress field in finite element analysis, all stresses are estimated at each Gaussian point of elements. The search strategy for a noncircular critical slip surface along weak points is appropriate for rainfall-induced shallow slope failure. The change of unit weight by seepage force has an effect on the horizontal and vertical displacements on the soil slope. The Drucker-Prager failure criterion was adopted for stress-strain relation to calculate coupling hydraulic and mechanical behavior of the partially saturated soil slope.

• Journal of Energy Engineering
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• v.17 no.4
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• pp.241-246
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• 2008

Increase of $CO_2$ by using fossil fuels makes mainly global warming and the international efforts to reduce the $CO_2$ emission is being promoted. Absorption process using aqueous alkanolamine solution to remove acid components in the mixed gases has been used commercially. This method was used to remove $CO_2$ in the flue gas in recent years. $CO_2$ Absorption characteristics of several aqueous alkanolamine solutions such as MEA, DEA and AMP was studied by measuring vapor-liquid-equilibrium(VLE) and absorption velocity in this study. VLE measuring equipment, shell and reactor type, was used to acquire VLE data, equilibrium $CO_2$ pressure(${P_{CO_2}}^*$) and time at each pulse gas input. We also acquired the $CO_2$ absorption velocity by measuring the time to arrive the VLE at $40{\sim}80^{\circ}C$ and first gas input. The $CO_2$ absorption capacity of MEA 10wt% solution was higher than two alkanolamine solutions at $40^{\circ}C$ and the equilibrium $CO_2$ loading was 0.5. Absorption capacity was excellent as follows; AMP>DEA>MEA. But absorption velocity was fast as follows; MEA>AMP>DEA. Though good absorbent was considered by many variables, absorption velocity and capacity was more important factor.

• Applied Chemistry for Engineering
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• v.25 no.4
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• pp.430-436
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• 2014

Allura Red (AR) is a water-soluble harmful tar-based food colorant (FD & C Red 40). Batch adsorption studies were performed for the removal of AR using bituminous coal based granular activated carbon as adsorbent by varying the operation parameters such as adsorbent dosage, initial concentration, contact time and temperature. Experimental equilibrium adsorption data were analyzed by Langmuir, Freundlich and Temkin isotherms. The equilibrium process was described well by Freundlich isotherm. From determined separation factor ($R_L$), adsorption of AR by granular activated carbon could be employed as effective treatment method. Temkin parameter, B was determined to 1.62~3.288 J/mol indicating a physical adsorption process. By estimation of adsorption rate experimental data, the value of intraparticle diffusion rate constant ($k_m$) increased with the increasing adsorption temperature. The adsorption process were found to confirm to the pseudo second order model with good correlation. Thermodynamic parameters like change of free energy, enthalpy, and entropy were also calculated to predict the nature adsorption in the temperature range of 298~318 K. The negative Gibbs free energy change (${\Delta}G$ = -2.16~-6.55 kJ/mol) and the positive enthalpy change (${\Delta}H$ = + 23.29 kJ/mol) indicated the spontaneous and endothermic nature of the adsorption process, respectively.

• Clean Technology
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• v.27 no.2
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• pp.182-189
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• 2021

The adsorption of disperse yellow 3 (DY 3) on granular activated carbon (GAC) was investigated for isothermal adsorption and kinetic and thermodynamic parameters by experimenting with initial concentration, contact time, temperature, and pH of the dye as adsorption parameters. In the pH change experiment, the adsorption percent of DY 3 on activated carbon was highest in the acidic region, pH 3 due to electrostatic attraction between the surface of the activated carbon with positive charge and the anion (OH^-) of DY 3. The adsorption equilibrium data of DY 3 fit the Langmuir isothermal adsorption equation best, and it was found that activated carbon can effectively remove DY 3 from the calculated separation factor (R_L). The heat of adsorption-related constant (B) from the Temkin equation did not exceed 20 J mol^-1, indicating that it is a physical adsorption process. The pseudo second order kinetic model fits well within 10.72% of the error percent in the kinetic experiments. The plots for Weber and Morris intraparticle diffusion model were divided into two straight lines. The intraparticle diffusion rate was slow because the slope of the stage 2 (intraparticle diffusion) was smaller than that of stage 1 (boundary layer diffusion). Therefore, it was confirmed that the intraparticle diffusion was rate controlling step. The free energy change of the DY 3 adsorption by activated carbon showed negative values at 298 ~ 318 K. As the temperature increased, the spontaneity increased. The enthalpy change of the adsorption reaction of DY 3 by activated carbon was 0.65 kJ mol^-1, which was an endothermic reaction, and the entropy change was 2.14 J mol^-1 K^-1.

• The Journal of Korean Society for Radiation Therapy
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• v.8 no.1
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• pp.29-35
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• 1996

We are often faced with the clinical situations that is inevitably extended SSD for electron beam therapy due to anatomical restriction or applicator structure. But there are some difficulties in accurately predicting output and properties. In electron beam treatment , unlike photon beam the decrease in output for extended SSD does not follow inverse-square law accurately because of a loss of side scatter equilibrium, which is particularly significant for small cone size and low energies. The purpose of our study is to analyze the output in changing with the energy, cone size, air gap beyond the standard SSD and to compare inverse-square law factor derived from calculated effective SSD, mominal SSD with measured output factor. In addition, we have analyzed the change of PDD for several cones with different SSDs which range from 100cm to 120cm with 5cm step and with different energies(6MeV, 9MeV, 12MeV, 16MeV, 20MeV). In accordance with our study, an extended SSD produces a significant change in beam output, negligible change in depth dose which range from 100cm to 120cm SSDs. In order to deliver the more accurate dose to the neoplastic tissue, first of all we recommend inverse-square law using the table of effective SSDs with cone sizes and energies respectively or simply to create a table of extended SSD air gap correction factor. The second we need to have an insight into some change of dose distribution including PPD, penumbra caused by extended SSD for electron beam therapy.

• The Journal of Engineering Geology
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• v.14 no.4 s.41
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• pp.451-460
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• 2004

The strength of sliding plane is usually assigned on the whole sliding plane with same value in 2D limit equilibrium slope stability method. However, the potential sliding plane is divided into two or three parts which have different sliding resistances. According to the calculation results of 3D slope stability analyses using 4 types of slope cutting models, marginal sliding resistance could affect the safety of slope significantly. In this calculation two kinds of the sliding plane strengths were applied differently to the parts of bottom and margin of the model slope. The effect of marginal resistance was calculated quantitatively. In case of lower sliding resistance of the bottom, the safety factor becomes low in a margin cutting model. However, in case of higher sliding resistance of the bottom, the safety factor decreased slightly in a lower part cutting model and increased in a upper margin cutting model.