• 제목/요약/키워드: equilibrium factor

검색결과 418건 처리시간 0.025초

Magnetic dependence of cyclotron resonance in the electron-piezoelectric phonon interacting materials

  • Park, Jung-Il;Sug, Joung-Young
    • 한국자기공명학회논문지
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    • 제24권1호
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    • pp.16-22
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    • 2020
  • Based on quantum transport theory, we investigated theoretically the magnetic field dependence of the quantum optical transition of quasi 2-dimensional Landau splitting system, in CdS and ZnO Through the analysis of the current work, we found the increasing properties of the cyclotron resonance line-profiles (CRLPs) which show the absorption power and the cyclotron resonance line-widths (CRLWs) with the magnetic field in CdS and ZnO We also found that that CRLWs, γtotal(B) of CdS < γtotal(B) of ZnO in the magnetic field region B < 15 Tesla.

Kinetic Studies on the Reduction of 1-Benzyl-3-cyanoquinolinium Cations by Sodium Borohydride and the Applicability Marcus Theory

  • Han, In-Sook;Lee, Chang-Kiu;Han, In-Sup
    • Bulletin of the Korean Chemical Society
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    • 제8권2호
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    • pp.79-83
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    • 1987
  • The reduction of a series of 1-substituted benzyl-3-cyanoquinolinium ions (p-$cH_3$, H, p-Br, m-F, p-CN) by sodium borohydride has been investigated. In all cases the products from these reactions were found to be 1, 2-dihydroquinolines over 82% yields. Rates of reduction were measured in basic condition and in solvent system consisting of 4 parts of isopropyl alcohol and 1 part of water by volume. Second order rate constants were obtained for these reactions. When the ratio of [$OH^-$] to [$BH_4^-$] becomes large the observed rate constants ($K_{obs}$) decrease by a small factor. Reaction scheme and rate law are discussed. Bronsted ${\alpha}(=\frac{d\;In\;k}{d\;In\;K})$ obtained by using the value of equilibrium constant K, which was obtained previously, was not 0. Instead, a value of 0.36 was obtained which indicated that the reduction by borohydride was structure-dependent according to the Marcus formalism even though the reaction rate was close to the diffusion limit.

Enzyme Kinetics of Multiple Inhibition in the Presence of Two Reversible Inhibitors

  • Han, Moon H.;Seong, Baik L.
    • Bulletin of the Korean Chemical Society
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    • 제3권3호
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    • pp.122-129
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    • 1982
  • In order to extend our understanding on the multiple inhibition enzyme kinetics, a general equation of an enzyme reaction in the presence of two different reversible inhibitors was derived by what we call "match-box mechanism" under the combined assumption of steady-state and quasi-equilibrium for inhibitor binding. Graphical methods were proposed to analyze the multiple inhibition of an enzyme by any given sets of different inhibitors, i.e., competitive, noncompetitive, and uncompetitive inhibitors. This method not only gives an interaction factor $({\alpha})$ between two inhibitors, but also discerns ${\alpha}_1$ and ${\alpha}_2$ with and without substrate binding, respectively. The factors involved in the dissociation constants of inhibitors can also be evaluated by the present plot. It is also shown that the present kinetic approach can be extended to other forms of activators or hydrogen ions with some modification.

원심력기반 3차원 관성밸브 모델링을 통한 정밀 미세유체제어 (3D-inertia Valve Component for Centrifugal Force-based Micro Fluid Control)

  • 강동희;김나경;강현욱
    • 한국가시화정보학회지
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    • 제19권1호
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    • pp.12-17
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    • 2021
  • A three-dimensional slope valve component is used for controlling micro volume of liquid on a centrifugal force-based microfluidic disk platform, also called a lab-on-a-disk. The modeling factor of the slope valve component is determined to centrifugal force for liquid passing the crest of a slope valve via variation of slope length and angle as well as the radius to start point of slope valve. The centrifugal force is calculated by the equilibrium equation of the capillary and gravitational forces according to the microchannel surface roughness and the liquid volume, respectively. As a result, the slope valve is analyzed by the minimum angular velocity for liquid passing at crest point and the ratio between the length of micro liquid and slope length to obtain the factors for optimal slope angle modeling.

Analyses of centrifuge modelling for artificially sensitive clay slopes

  • Park, Dong Soon
    • Geomechanics and Engineering
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    • 제16권5호
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    • pp.513-525
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    • 2018
  • Slope stability of sensitive clayey soils is particularly important when subjected to strength loss and deformation. Except for progressive failure, for most sensitive and insensitive slopes, it is important to review the feasibility of conventional analysis methods based on peak strength since peak strength governs slope stability before yielding. In this study, as a part of efforts to understand the behavior of sensitive clay slopes, a total of 12 centrifuge tests were performed for artificially sensitive and insensitive clay slopes using San Francisco Bay Mud (PI = 50) and Yolo Loam (PI = 10). In terms of slope stability, the results were analyzed using the updated instability factor ($N_I$). $N_I$ using equivalent unit weight to cause a failure is in reasonable agreement shown in the Taylor's chart ($N_I$ ~ 5.5). In terms of dynamic deformation, it is shown that two-way sliding is a more accurate approach than conventional one-way sliding. Two-way sliding may relate to diffused shear surfaces. The outcome of this study is contributable to analyzing stability and deformation of steep sensitive clay slopes.

A novel refined plate theory for stability analysis of hybrid and symmetric S-FGM plates

  • Bourada, Fouad;Amara, Khaled;Bousahla, Abdelmoumen A.;Tounsi, Abdelouahed;Mahmoud, S.R.
    • Structural Engineering and Mechanics
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    • 제68권6호
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    • pp.661-675
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    • 2018
  • In this paper, buckling analysis of hybrid functionally graded plates using a novel four variable refined plate theory is presented. In this theory the distribution of transverse shear deformation is parabolic across the thickness of the plate by satisfying the surface conditions. Therefore, it is unnecessary to use a shear correction factor. The variations of properties of the plate through the thickness are according to a symmetric sigmoid law (symmetric S-FGM). The principle virtual works is used herein to extract equilibrium equations. The analytical solution is determined using the Navier method for a simply supported rectangular plate subjected to axial forces. The precision of this theory is verified by comparing it with the various solutions available in the literature.

Geometrically nonlinear meshfree analysis of 3D-shell structures based on the double directors shell theory with finite rotations

  • Mellouli, Hana;Jrad, Hanen;Wali, Monther;Dammak, Fakhreddine
    • Steel and Composite Structures
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    • 제31권4호
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    • pp.397-408
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    • 2019
  • In this paper, a geometrically nonlinear meshfree analysis of 3D various forms of shell structures using the double director shell theory with finite rotations is proposed. This theory is introduced in the present method to remove the shear correction factor and to improve the accuracy of transverse shear stresses with the consideration of rotational degrees of freedom.The present meshfree method is based on the radial point interpolation method (RPIM) which is employed for the construction of shape functions for a set of nodes distributed in a problem domain. Discrete system of geometrically nonlinear equilibrium equations solved with the Newton-Raphson method is obtained by incorporating these interpolations into the weak form. The accuracy of the proposed method is examined by comparing the present results with the accurate ones available in the literature and good agreements are found.

Anomalous Propagation Characteristics of an Airy Beam in Nonlocal Nonlinear Medium

  • Wu, Yun-Long;Ye, Qin;Shao, Li
    • Current Optics and Photonics
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    • 제5권2호
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    • pp.191-197
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    • 2021
  • The anomalous propagation characteristics of a single Airy beam in nonlocal nonlinear medium are investigated by utilizing the split-step Fourier-transform method. We show that besides the normal straight propagation trajectory, the breathing solitons formed by the interaction between Airy beam and nonlocal nonlinear medium can propagate along the sinusoidal trajectory, and the anomalous trajectory can be modulated arbitrarily by altering the initial amplitude and the nonlocal nonlinear coefficient. In addition, the initial amplitude and the nonlocal nonlinear coefficient can have inverse impacts on the formation and transformation of the equilibrium state of spatial solitons, when the two parameters are larger than certain values. Therefore, the reversible transformation of the evolution dynamics of two soliton states can be realized by adjusting those two parameters properly. Finally, it is shown that the propagation properties of the solitons formed by the interaction between Airy beam and nonlocal nonlinear medium can be controlled arbitrarily, by adjusting the distribution factor and nonlocal coefficient.

BIFURCATIONS OF STOCHASTIC IZHIKEVICH-FITZHUGH MODEL

  • Nia, Mehdi Fatehi;Mirzavand, Elaheh
    • 호남수학학술지
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    • 제44권3호
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    • pp.402-418
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    • 2022
  • Noise is a fundamental factor to increased validity and regularity of spike propagation and neuronal firing in the nervous system. In this paper, we examine the stochastic version of the Izhikevich-FitzHugh neuron dynamical model. This approach is based on techniques presented by Luo and Guo, which provide a general framework for the bifurcation and stability analysis of two dimensional stochastic dynamical system as an Itô averaging diffusion system. By using largest lyapunov exponent, local and global stability of the stochastic system at the equilibrium point are investigated. We focus on the two kinds of stochastic bifurcations: the P-bifurcation and the D-bifurcations. By use of polar coordinate, Taylor expansion and stochastic averaging method, it is shown that there exists choices of diffusion and drift parameters such that these bifurcations occurs. Finally, numerical simulations in various viewpoints, including phase portrait, evolution in time and probability density, are presented to show the effects of the diffusion and drift coefficients that illustrate our theoretical results.

한계평형해석에 의한 연약지반 위의 철도노반 고성토를 위한 직포 보강 효과 (The Reinforcement Effect of Woven Geotextiles for Railway Roadbed High-Embankment on Soft Ground by the Limit Equilibrium Analysis)

  • 김유성;최재선
    • 한국지반신소재학회논문집
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    • 제9권4호
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    • pp.27-37
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    • 2010
  • 직포 보강재는 연약지반 성토시 장비주행성, 지지력 및 활동안정성 개선 등을 목적으로 활발하게 적용되고 있다. 이 논문에서는 연약지반 위에 고강도의 직포를 2층 보강하여 철도제방을 성공적으로 구축한 사례를 소개하였다. 한계평형해석에 근거한 비탈면 활동안정분석결과 연약지반 위에 고강도의 직포를 2층 보강하고 흙쌓기를 수행하였을 때 제체의 활동에 대한 안전율은 0.91에서 1.14로 약 25%증가하고, 2개월 이상의 공기단축효과가 있는 것으로 나타났다. 따라서, 공기가 촉박하거나, 안전율이 다소 부족한 현장의 경우 고강도 직포보강에 의한 연약지반처리공법은 유용한 것으로 판단된다.

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