• Title/Summary/Keyword: equilibrium equation

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A CFD Modeling of Heat Generation and Charge-Discharge Behavior of a Li-ion Secondary Battery (Li-ion 이차전지의 충방전 시 발열 및 충방전 특성의 CFD 모델링)

  • Kang, Hyeji;Park, Hongbeom;Han, Kyoungho;Yoon, Do Young
    • Journal of the Korean Electrochemical Society
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    • v.19 no.3
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    • pp.114-121
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    • 2016
  • This study investigates a CFD modeling of the charge-discharge behavior due to heat generation during charge-discharge cycles of a Li-ion secondary battery(LIB). Present LIB system adopted a current-density equation, heat and mass transfer governing equations upon the 1-dimensional system to the thickness direction for the rectangular pouch configuration. According to the 3-kinds of the charge-discharge current densities of 1C($17.5A/m^2$), 3C($52.5A/m^2$) and 5C($87.5A/m^2$) subject to a 3 V of cut-off voltage, a constant-temperature system at 298 K and three different heat generating systems were analyzed with comparison. Battery capacity decreases with increment of charge-discharge densities not only at the constant-temperature system but also at the heat-generating system. The time for charge-discharge cycles increases at the heat-generating system compare to the constant-temperature system. These trends are considered that the increase of temperature due to heat generation causes the decrement of equilibrium potential of electrodes and the increment of diffusivity of Li ions. Furthermore, cooling effects were discussed in order to control the influence of heat generation due to charge-discharge behavior of a Li-ion secondary battery.

Dynamic Causality and Impulse Response between Maritime Import Volume, Relative Real Effective Exchange Rate, and Regional Industrial Activity : Focusing on a Trade Port of the Jeonnam Province (해상 수입물동량, 상대적 실질실효환율, 지역경기의 동태적 인과성과 충격반응 : 전남지역의 무역항을 중심으로)

  • Kim, Chang-Beom
    • Journal of Korea Port Economic Association
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    • v.33 no.1
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    • pp.47-59
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    • 2017
  • The objective of this study is to determine the short run and long run dynamics between maritime import volume (IMV), industrial production (IP), and real effective exchange rate (REER) of the Korean Won over the REER of certain major currencies (US Dollar, Chinese Yuan, and Japanese Yen) in Korea's Jeonnam province. The Johansen and Juselius cointegration results reveal that at least one cointegration vector or long-run relationship exists. Hence, this study estimated the long run equilibrium equation, which indicates that both IP and REER are inelastic, although the former is bigger than the latter. Moreover, the dynamic causality analysis reveals short and long-run unidirectional causality from IP and REER to IMV in all three models. Further, in all the models, the results indicate short run unidirectional causality from REER to IP. In addition, the impulse response (IR) results show that the impulse of IP and REER decayed after four months. Additionally, the IR analysis results indicate that the REER of the Korean Won over the REER of Japanese Yen is the biggest with respect to the impact of relative REER on IP, which is the proxy variable of regional real income. Thus, empirical results indicated that real income and REER play an important role in determining the Jeonnam's maritime import demand behavior in the short run and long run. More importantly, substantial actions reducing unexpected fluctuation of the REER and real income based on micro and macro economic policies will increase the imported volume in the ports of the Jeonnam province.

An Analysis on the Stage-Discharge Relation Curve with the Temporal Variation of the River Bed -at Indogyo Station of the Han River- (하상(河床) 경년변화(經年變化)에 따른 수위(水位)-유량(流量) 관계곡선(關係曲線)의 해석(解析) -한강(漢江) 인도교지점(人道橋地點)을 중심(中心)으로-)

  • Cheong, Heung Soo;Lee, Won Hwan;Lee, Jae Joon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.8 no.3
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    • pp.61-71
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    • 1988
  • The stage-discharge relation curve(rating curve) is the basic formula in hydrologic analysis. It plays an important role in converting to the discharge from available flood water level data including the daily mean stage. However, the river induces a cross section change at the gauging station because of the composed material of the river bed and three processes of the stream flow; i.e., erosion, transportation, and sedimentation. Rating curve has to be revised according to the temporal variation of the river bed due to the those factors. In this study, the basic rating curve is developed with respect to the current river bed to convert the existing rating curves and also to seize the hydraulic and geometric characteristics for the temporal variation of the river bed, relationships among the basic rating curve and the existing rating curves, water level, cross sectional area, and flow velocity are analyzed. Indogyo station, which is not only the key station of the Han river but also greatly changed the river bed after completion of the Han river development plan during the year 1983 to 1986, was chosen for the study. In this study, the river bed is assumed in a dynamic equilibrium condition. The basic rating curve is developed using hydrologic data of the physical year of 1987. For a given discharge, relationships for conversion of previous data, stage and velocity, the current one are formulated. To verify the usefulness of the relationships, stage-cross sectional area and stage velocity formula are also derived. Both hydrologic method using continuity equation and statistical method by the rating curve are compared and checked, then the validation of the both are positively shown.

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Sediment discharge assessment and stable channel analysis using Model Tree of data mining for Naesung Stream (데이터 마이닝의 Model Tree를 활용한 내성천의 유사량 산정 및 안정하도 평가)

  • Jang, Eun-Kyung;Ji, Un;Ahn, Myeonghui
    • Journal of Korea Water Resources Association
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    • v.51 no.11
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    • pp.999-1009
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    • 2018
  • A Model Tree technique of data mining was applied to derive optimal equations for sediment discharge assessment based on the measured sediment data and then to evaluate stable channel design for Naesung Stream. The sediment discharge formula as a function of channel width, velocity, depth, slope and median grain diameter which was developed by a Model Tree technique with sediment discharge data measured in Korean River had a high goodness-of-fit between measured and calculated results. In case of the sediment discharge formula as a function of channel width, velocity, depth and median grain diameter which was developed by a Model Tree technique with sediment discharge data only measured in Naesung Stream represented the highest goodness-of-fit. Two types of sediment discharge formulas were applied to evaluate stable channel analysis for Yonghyeol Station of Naesung Stream. As a result, bed erosion was expected in the study section compared to the current section. It was also presented that the be slope might be changed to be a milder slope than the current slope to reach equilibrium condition in the long term.

Classification of Groundwater Level Variation Types Near the Excavated Area of the Temporary Gulpocheon Discharge Channel (굴포천 임시방수로 굴착구간 주변의 지하수 수위 변동 유형 분류)

  • Kim, Chang-Hoon;Lee, Su-Gon;Hahn, Jeong-Sang;Kim, Nam-Ju;Jeon, Byeong-Chu
    • The Journal of Engineering Geology
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    • v.24 no.4
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    • pp.631-641
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    • 2014
  • Characteristics of water-level changes in the Temporary Gulpocheon Discharge Channel were identified by observing and analyzing changes in the subterranean water level induced by hydrological stresses the underground aquifer. The subterranean water level refers to the level at which the pressure of subterranean water passing through the corresponding position has an equipotential value that is in equilibrium with the atmospheric pressure at that location. This water level is not fixed but changes in response to hydrological stress. It can be identified by repeatedly measuring the distance from the observation point to the surface of the subterranean water. The subterranean water-level change equation and the variance range of the hydrological curve of subterranean water over 24 hours at the Gimpo-Gimpo National Groundwater Monitoring Network (NGMN) were used as assessment factors. The variance characteristics of the subterranean water at the 18 monitoring system locations were classified into three impact, observational wish, and non-impact. The impact type accounted for 50% of the subterranean water of and accurately reflected the water-level changes due to hydrological stress, showing that distance is the major controlling factor. The observational wish type accounted for 27.8% of the subterranean water, and one of the two assessment factors did not meet the assessment factors. The nonimpact type accounted for 22.2% of the subterranean water. This type satisfied the two assessment factors and represents subterranean water-level changes response to precipitation.

A Study on the Adsorption of Organophosphorus Pesticides Applying Sewage Sludge to Soil Amendment (하수슬러지의 토양개량재 적용시 유기인계 농약의 흡착 능력에 관한 연구)

  • 임은진;이재영
    • Journal of Soil and Groundwater Environment
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    • v.9 no.1
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    • pp.95-103
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    • 2004
  • This study has been assessed the influence of applying sewage sludge to soil amendments on the sorption properties, and leaching potential of three commonly used organophosphorus pesticides, Diazinon, Fenitrothion, and Chlorpyrifos. A sandy soil with a low content of organic carbon was treated with sewage sludge with a ratio sandy soil sludge ratio of 30:1. The sorption was determined with the batch equilibrium technique. The sorption isotherms could be described by Freundlich equation. The Freundlich constant, K value which measures sorption capacity, were 3.97, 9.94, 22.48 for Diazinon, Fenitrothion, Chlorpyrifos in non-amended soil. But in amended soil, K value was 12.58, 28.47, and 61.21 for Diazinon, Fenitrothion, and Chlorpyrifos. The overall effect of sewage sludge addition to soil was to increase pesticides adsorption, due to the high sorption capacity of the organic matter. The effect of sludge on the leaching of pesticides in the soil was studied using packed soil columns. Total recoveries of pesticides in soil and leachate with leaching in soil column, were in the range of about 73∼84%, was reduced with the passage of time. Diazinon moved more rapidly than Chlorpyrifos in the unamended soil due to greater sorption and lower water solubility of Chlorpyrifos. Total amounts of pesticides leached from the sewage sludge amended soils were significantly reduced when compared with unamended soils. This reduction may be mainly due to and increase in sorption in amended soils, as a consequence of the increase in the organic matter content.

Rheological Properties of Rehydrated Suspensions of Freeze Dried Kochujang Powders (동결건조 분말고추장의 재수화시 리올로지 특성)

  • Kim, Suk-Shin;Chang, Kyu-Seob;Yoon, Han-Kyo;Lee, Sang-Kyu;Lee, Shin-Young
    • Korean Journal of Food Science and Technology
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    • v.19 no.2
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    • pp.81-88
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    • 1987
  • Rheological properties of rehydrated suspensions of two kinds of freeze dried Kochujang powders, processed at different freezing rates, were compared with raw Kochujang using Brookfield wide-gap rotational viscometer at $25^{\circ}C-60^{\circ}C$. Shear rates ranged from $0.1965\;sec^{-1}$ to $1.9650\;sec^{-1}$ and solid content ranged from 47% to 56%. Rehydrated suspensions of quickly frozen Kochujang powder and slowly frozen Kochujang powder, and raw Kochujang exhibited pseudoplastic behaviors with yield stress and presented thixotropic properties which followed the second-order kinetic behavior proposed by Tiu. Suspensions of Kochujang powders exhibited considerably higher decaying rates than raw Kochujang. The dependency of the equilibrium structure parameter on the shear rate was weak, and there were no significant differences among the values of structure parameters of three samples. The temperature dependency of the apparent viscosity of Kochujang suspension was fully expressed by Arrhenius equation and activation energies of suspensions of quickly frozen Kochujang powder and slowly frozen Kochujang powder, and raw Kochujang were 2.21, 2.18, and 2.32 Kcal/g.mole respectively. Consistency indices of three samples increased with solid content and decreased with temperature. Flow behavior indices of three samples showed no considerable dependency on the temperature and solid content. There were no significant differences in the rheological properties between two Kochujang powders.

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On the Development of the Generalized Slope Deflection Method for the Analysis and Design of Ship Structures (선체(船體) 구조(構造) 해석(解析) 및 설계(設計)를 위한 일반화(一般化) 경사(傾斜) 처짐법(法) 개발(開發)에 관한 연구(硏究))

  • Chang-Doo Jang;Seung-Soo Na
    • Journal of the Society of Naval Architects of Korea
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    • v.29 no.4
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    • pp.202-213
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    • 1992
  • For the analysis and design of ship structures the generalized slope deflection method(GSDM) taking account of axial elongation effect as well as the bending and shearing deformation is developed. Using the span point concept, the existing slope deflection method is easy to transform the variable section to the equivalent uniform one under the bending moment and the shear force, but it is difficult to analyze the web frame with inclined members because the axial deformation effect is not considered. In the present method, the equilibrium conditions including all force components(i.e. axial force, shear force, bending moment) are formulated at the both ends of the variable section beam, such that the usual space frame stiffness equation which can be solved easily by the matrix method is derived. The accuracy and applicability of the present method is demonstrated by analyzing the ship web frame structures.

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Development of a Simulation Program for the Li-Reduction Process of PWR Spent Fuel (PWR 사용후핵연료의 Li 환원과정 모사 프로그램 개발)

  • Lee, Yun-Hee;Shin, Hee-Sung;Jang, Ji-Woon;Kim, Ho-Dong;Yoon, Ji-Sup
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.4 no.4
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    • pp.335-344
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    • 2006
  • In this paper a computer program was developed, which simulates the Li reduction process of PWR spent fuel, and the amount of a produced metal or chloride compound was calculated at the various amount of Li with the program. It establishes a database, which is composed of some characteristics related to a chemical reaction equation and thermodynamic data, and it calculates the transformed rate of PWR spent fuel oxide at the certain amount of Li by using the database as input data. As the results of the performance test of the program, it was validated that the transformed values of oxides, except for $Eu_2O_3$ and $Sm_2O_3$, were almost the same to within about a 6 % error with those calculated by the previous code and that the calculated amount of Li was also exactly consistent with the theoretical one, which is used for a complete reaction of each oxide in a single chemical reaction. A relationship between Li and the transformed metal of each oxide was analyzed on the basis of the quantities calculated with the verified development program. Of the results, when the amount of Li was given to be 250 mole, the 83.73 percentage of $UO_2$ was transformed into U while the remainder was still to be $UO_2$. In addition, it was appeared that the 297 mole of Li was needed to completely convert $UO_2$ into U.

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A Fundamental Study for the Automatic Control System in Greenhouse Using Microcomputer(III) -A variation of temperature and humidity by the window opening ways of the even-Span type house- (마이크로컴퓨터에 의한 시설재배의 자동화에 관한 기초연구(III) -양지붕형 하우스의 창 개방방법에 따른 온.습도의 변화-)

  • 김진현;김철수;구건효;이기명
    • Journal of Biosystems Engineering
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    • v.20 no.2
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    • pp.162-172
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    • 1995
  • The ventilation in greenhouse have been important for such as adjustment of temperature, supplying of the oxygen, prevention of the overhumidity, density adjustment of $CO_2$, discharge of harmfulness gas, etc. However, the general ventilation which had been used the quantitative control method in discharge of a property of air mechanism in greenhouse, and caused mainly in waste of the heating energy and growth obstacle of the vegetable. Therefore, this study was peformed to obtain more scientific ventilation method using by analysis and measurement of the isothermal lines according to opening of window ventilation in greenhouse, and the results are summarized as follows. 1. The ventilating amount was more influenced by rather opening amount of window than the ventilating time. 2. In window ventilation, the temperature in greenhouse was mostly changed within 5 minutes after ventilating not regard to the spot of opening, after about 10 minutes temperature became to equilibrium state under the respective ventilating conditions. 3. In opening of the skylight only, isothermal lines were complicated, therefore, a tall vegetable may be possible to damage by a cold-weather from the lower central port in greenhouse. 4. Isothermal lines were a tendency to simply in opening of a side window that may be more effective ventilation in kinds of the short vegetable. 5. In conditions of internal temperature>setting temperature>external temperature, a skylight can be suitable to open 10~20cm in order to the optimum ventilation in greenhouse. 6. In conditions of internal temperature>external temperature>setting temperature, opening of all the windows or both the side windows that can be suitable in order to obtain the optimum ventilation in greenhouse. 7. An effect of ventilation was the most excellent to open of all the windows or both the side windows, and it were also found orderly excellent to open of the side window and the skylight or the skylight only, to open of the side window only. 8. Temperature was varied as the equation of T=Tc+ (To-Tc)e-at, and the ranges of (a) values were limited within 0.34~0.68. 9. A variations of humidity were similar to that of temperature, s.

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