• Title/Summary/Keyword: equilibrium condition

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Studies on Packaging of Spray-dried Soy Sauce by Means of Flexible Films and Their Laminates (유연(柔軟) 포장재료(包裝材料)를 이용(利用)한 분말(粉末) 간장의 포장(包裝)에 관(關)한 연구(硏究))

  • Chang, K.S.;Yoon, H.K.;Kim, M.S.
    • Applied Biological Chemistry
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    • v.21 no.3
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    • pp.144-149
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    • 1978
  • Fermented soy sauce was dehydrated by spray drying to form powder, and moisture sorption properties of powdered soy sauce with or without cover of the flexible films were examined on different relative humidity by using saturated salt solutions at $30^{\circ}$. The results obtained were summarized as follows: The equilibrium moisture content of spray-dried soy sauce containing 18.3% moisture was determined to 52% by graphical interpolation method, and E.M.C. of powdered soy sauce covered with plastic films decreased at low relative humidity whereas sharply increased curves were seen at high relative humidity. The rate constant of moisture adsortion K for the power covered with films were $66.2{\times}10^{-5}\;to\;225{\times}10^{-5}/hr$., and K' became greater when film having higher water vapor transmission rate was used. The shelf-life of powdered soy sauce covered with Al. foil/P.E. film by Brown formula at the accelerated condition of $38^{\circ}$, 92% R. H. was the longest period, 164 days compared with any other films used, and the shortest period, 18 days in P.V.C. film.

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Innovative Technology for Removal of Dispersants used in Oil Spill Remediation Using the Magnetic Separation (자성 분리를 이용한 해상 유류오염제어에 사용되는 유화제를 제거하는 새로운 기술에 대한 연구)

  • Chun, Chan-Lan;Park, Jae-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.679-688
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    • 2000
  • Dispersants, which are used to break water-in-oil emulsions and to remediate oil-spills, are another water pollutants. In this study, magnetic separation technology was applied to remove dispersants from the sea. Magnetite and maghemite were used as magnetic sorbents and SDDBS, an anionic surfactant and Triton X-100, a nonionic surfactant, were employed as dispersants. Batch experiments were undertaken to study the sorption capacity and sorption equilibrium, and water-bath experiments were conducted to simulate the real situation and to describe the recovery of magnetic particles by the permanent magnet or electromagnet. Maghemite has rather constant removal efficiency for dispersants, regardless of surfactant species. On the other hand, removal efficiency by magnetite is higher for anionic surfactant than maghemite and is higher in distilled water than in seawater which contains more ions. The sorption of dispersants to magnetite is explained by electrostatic attraction and that of maghemite is described not only by electrostatic attraction, but also by structural characteristics that provide high sorption ability and surface condition. Water bath experimental results showed that recovery efficiency of magnetic particle after sorption for dispersants is nearly 100%. It is suggested that this magnetic separation technology is an effective way of dispersant removal because of short operating time, high sorption capacity, and high recovery efficiency of sorbents.

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Cooking Conditions and Textural Changes of Cooked Rice Added with Black Rice (흑미 혼용밥의 취반조건과 텍스쳐의 변화)

  • Kim, Du-Woon;Eun, Jong-Bang;Rhee, Chong-Ouk
    • Korean Journal of Food Science and Technology
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    • v.30 no.3
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    • pp.562-568
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    • 1998
  • Rice (Dongjin-byeo) added with black rices (Chindo and Suwon-415) was cooked and the changes of texture and color of this cooked rice were investigated by texture analyser and color & color difference meter. The hydration time to come to the equilibrium condition was at least 11 hr in black rices. The optimum ratio of water to cooked rice added with black rice was 1.6 (ratio of water to rice) and the hardness of cooked rice added with 5% Chindo black rice was $5.66\;kg_f$. Regardless of ratio of water to rice, Hunter a value increased as the ratio of black rice addition to rice increased, while L value decreased. The color elution rate of Suwon 415 was 4 times greater than that of Chindo black rice. The pH of the steep water of Suwon 415 at $20^{\circ}C$ during 120 min decreased from pH 6.40 to pH 6.16 as the steeping time increased. The optimum heating time by microwave oven of cooked rice added with black rice was between $90{\sim}120\;sec$ to recover the original texture after cold storage treatment of 7 days.

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The Effectiveness of Ink Foot Print Analysis by Using Pre-post Oriental Medicine Music Therapy on Patient One Case with Cerebral Infarction (뇌경색 환자에게 실행한 한방음악치료 전후(前後)의 Ink foot print analysis 1례)

  • Lee, Seung-Hyun;Park, Kyoung-Su;Shin, Hyun-Dae
    • Journal of Korean Medicine Rehabilitation
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    • v.18 no.3
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    • pp.147-156
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    • 2008
  • Objectives : Oriental Medicine Music Therapy is a new way of treating and preventing various diseases and promoting health by means of music specially picked and designed to produce Qi(氣) fitting to an individual person in the areas of the structure of human body, physiological function, pathological change, diagnosis and treatment. Therefore, it can facilitate the efficiency of the treatment much better and faster than only with herb or acupuncture. Equilibrium between body and mind is its originality. Methods : A 38-year old man came to hospital suffering from left side weakness, dysarthria because of cerebral infarction. After one week's medication in the part of neurology, he was sent to the oriental medicine music therapy center, and he took ten times' medical treatments once a day. Before and after the treatments, implementing 'Ink foot print analysis', as for the movement capacity and walking of left side weakness, these results are acquired. Results and Conclusions : 1. Before the oriental medicine music therapy, except the acceleration and deceleration section, within three meters, a right foot's step was measured 30.55 cm and a left foot was measured 15.2 cm, and the step distance was 15.2 cm. After the 10 times treatments, the right foot's step was 112.6 cm, the left foot's step was 113 cm, and the step distance improved to 51.8 cm. 2. The normal person's average step is about 38 cm, and it could be decreased owing to a decreptitude, pain, fatigue, and the weakness of the legs. In spite of all, from the increased 50 cm step measurement with the patient's body condition, it means that his movement capacity is recovered. 3. In the measurement of walking time, before 10 times treatments, it took 46.35 seconds within 6M, but after the treatments, it increased to 7.47 seconds as same as a normal person's walking speed. 4. In insomnia, and the abnormality of a facial muscle, it shows lots of improvement, and even the accuracy of a pronunciation, but despite of the 10 times treatments, the 'ㄹ(r)' sound placed under a vowel is unclear. 5. Before the 10 times' treatments, he can move the left side shoulder with pain and cannot move below the left elbow. After the treatments, the pain was disappeared, and he was able to move over 60 cm without pain. And improving of the movement of fingers, he can beat over 8 times with a drumstick.

Case Study on the Countermeasure Methods and Collapsed Sources of Segmental Retaining Wall Considering Site Conditions (시공환경을 고려한 블록식 보강토옹벽의 붕괴요인 분석 및 대책방안 사례연구)

  • Han, Jung-Geun;Cho, Sam-Deok;Jeong, Sang-Seom;Lee, Kwang-Wo;Kim, Ji-Sun
    • Journal of the Korean Geosynthetics Society
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    • v.4 no.3
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    • pp.35-43
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    • 2005
  • The geosynthetic reinforced segmental retaining walls(SRW) are improved that the disadvantage of existed retaining wall and the workability in field. Recently, the segmental retaining wall is replacing the exited wall because it is quickly advanced to using by the block in-situ. The use, therefore, is increasing. But, the trends of the large scaled construction was developed that the problems likely to crack and collapse, those are caused of careless in design and construction of SRW not considering about various surrounding conditions. In this study, the cause analysis on destructed SRW was carried out that based on the datum of measured displacement of walls, rainfall features and ground sounding conditions. Also, the analysis of the global slope stability was carried out on collapsed section and non-collapsed section using critical equilibrium method. For the rational stability and analysis of slope including SRW structure, the site conditions including situations of topography, ground and histories of construction and collapse etc should be considered. The rational countermeasure methods for non-collapsed and collapsed areas may be sustained as much as possible current state.

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Dynamic Optimization of a Reactive Distillation Column Producing Methyl Acetate (메틸 아세테이트 생산을 위한 반응증류 공정의 동적 최적화)

  • Kim, Jiyong;Kim, Junghwan;Moon, Il
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.739-746
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    • 2008
  • The aim of this study is finding the optimal design parameters and the optimal operation variables of a reactive distillation column. Different from steady state optimization, dynamic optimization makes it possible considering operation ability as well as design problems at process design step. For performing dynamic optimization, dynamic simulation should be done first. If dynamic simulation is already finished, dynamic optimization can be performed with less effort than that of dynamic simulation.Reactive distillation systems involving reaction and separation in a single unit have the potential to reduce capital and operating costs, particularly when reaction have conversion constraint or when azeotropes exist making conventional separation difficult and expensive. This study here present work on the continuous distillation process, the homogeneous catalyzed esterification of methanol and acetic acid, the synthesis of methyl acetate. Based on an equilibrium stage model of a reactive distillation column a dynamic optimization problem was formulated and solved. And the results were verified by performing dynamic simulation and showing the variation of conversion and purity as the variation of the operation variables. As the results of dynamic optimization, this study found optimal feed ratio, reflux ratio and reboiler duty of this system. And as this study applied it to dynamic simulations the dynamic characteristics of a reactive distillation column are showed under optimal operating condition.

Experimental analysis on the channel adjustment processes by weir removal (실내실험에 의한 기능을 상실한 보 철거로 인한 하도의 적응과정 분석)

  • Jang, Chang-Lae;Lee, Kyung Su
    • Journal of Korea Water Resources Association
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    • v.53 no.11
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    • pp.951-960
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    • 2020
  • This study investigates the adjustment processes of the rivers after weir removal through laboratory experiments. Delta upstream eroded rapidly by flow at the initial stage of the experiments and the knickpoint migrates upward. Moreover, the knickpoint moves fast upward on the condition of alternate bars. The head cutting in the bed is developed fast at the initial stage. However, the erosion speed in the bed decreases with time. The well developed alternate bars migrates with keeping their shape downstream, and the bars affect the channel downstream to adjust new environments after weir removal. Maximum scouring depth downstream and the migration speed decrease over time after removing the weir. The scouring depth in the channel without alternate bars migrates with speed. However, the depth in the channel with alternate bars migrates slow downstream. The channel with alternate bars, in turn, is adjusted well to the new equilibrium states. The maximum scouring depth migrates downstream with time, and the scouring depth and its migration speed decreases with time. The dimensionless maximum scouring depth decreases with the migration speed of dimensionless maximum scouring depth because the deeply scoured places capture the sediments from upstream and the migration speed is slow as the places are filled with them. The dimensionless maximum scouring depth is shallow as the dimensionless backfilling speed is high. The dimensionless maximum scouring depth decreases rapidly less than 5 of dimensionless backfilling speed. However, the depth decreases slow more than 5 of it.

Prediction of Tcv for Coal Slags under Reducing Condition (환원 조건에서 석탄 슬래그의 Tcv 예측)

  • Park, Yoonkyung;Oh, Myungsook
    • Korean Chemical Engineering Research
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    • v.44 no.6
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    • pp.623-630
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    • 2006
  • The slag viscosity is an important factor determining the operation temperature of entrained flow type of gasifiers. The temperature of critical viscosity, $T_{cv}$, for 5 crystalline slags was predicted by empirical models and FactSage equilibrium calculations, and the validity of each method was tested. Two empirical models were employed: one using $T_h$ from the ash fusion test, and the other using the concentrations of 5 major components. The first model using $T_h$ over-predicted $T_{cv}$ by $20{\sim}100^{\circ}C$, while the model based on the slag composition under-predicted $T_{cv}$ by $80{\sim}120^{\circ}C$. In the equlibrium calculations, $T_{cv}$ was obtained from the liquidus temperature. When the 4-major component concentrations were used in the calculation, the predicted temperatures were higher than the observed. The liquidus temperature was very sensitive to the concentrations of minor components, and the addition of MgO and $Na_2O$ lowered the liquidus temperature. The results with 4 major and 3 minor components most closely described experimentally observed $T_{cv}$. In the case that a chromia refractory was used, it was shown that $Cr_2O_3$ concentration in the slag also needs to be included for more accurate prediction of $T_{cv}$.

The Effect of Internal Row on Marine Riser Dynamics (Riser의 내부유체 흐름이 Riser 동적반응에 미치는 영향)

  • Hong, Nam-Seeg
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.7 no.1
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    • pp.75-90
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    • 1995
  • A mathematical model for the dynamic analysis of a riser system with the inclusion of internal flow and nonlinear effects due to large structural displacements is developed to investigate the effect of internal flow on marine riser dynamics. The riser system accounts fir the nonlinear boundary conditions and includes a steady flow inside the pipe which is modeled as an extensible or inextensible. tubular beam subject to nonlinear three dimensional hydrodynamic loads such as current or wave excitation. Galerkin's finite element approximation and time incremental operator are implemented to derive the matrix equation of equilibrium for the finite element system and the extensibility or inextensibility condition is used to reduce degree of freedom of the system and the required computational time in the case of a nonlinear model. The algorithm is implemented to develop computer programs used in several numerical applications. The investigations of the effect of infernal flow on riser vibration due to current or wave loading are performed according to the change of various parameters such as top tension, internal flow velocity, current velocity, wave period, and so on. It is found that the effect of internal flow can be controlled by the increase of top tension. However, careful consideration has to be given in the design point particularly for the long riser under the harmonic loading such as waves. And it is also found that the consideration of nonlinear effects due to large structural displacements increases the effect of internal flow on riser dynamics.

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Numerical Experiment for the Estimation of Equivalent Resistance Coefficient for the Simulation of Inundation over Densely Populated Structures (구조물 밀집지역 범람수치모의를 위한 상당저항계수 산정 수치실험)

  • Kim, Hyeong-Seok;Choi, Jun-Woo;Ko, Kwang-Oh;Yoon, Sung-Bum
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.20 no.6
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    • pp.532-539
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    • 2008
  • Kwon et al.(2008) carried out a hydraulic experiment in order to evaluate Manning coefficient, which implicates flow resistance due to bottom friction as well as drag caused by the squared piers higher than water depth and arranged with equal intervals, under the flow condition with a constant drag coefficient, $Re>10^4$. And, based on the equation of equilibrium, they proposed a formula for the equivalent resistant coefficient including empirical drag interaction coefficient obtained by using the experimental results. In this study, the hydraulic experiment was simulated using FLOW-3D, a 3-dimensional computational fluid dynamic code. The computations were compared with the experiment results as well as the semi-theoretical formula, and the comparisons show a good agreement. From the agreement, it was confirmed that when flow resistance bodies were higher than water depth, Manning n value increases with 2/3 power of water depth as shown in the theoretical formula and that drag interaction coefficient was dominated by their intervals.