• Journal of the Korean GEO-environmental Society
• /
• v.15 no.12
• /
• pp.15-24
• /
• 2014

This study was performed to investigate the removal characteristics of heavy metals in Acid Mine Drainage (AMD) using pellet-type Zeolite-StarFish ceramics (ZSF ceramics), in which natural zeolite and starfish were mixed and calcined with wood flour. Kinetic experiment showed the removal reaction of heavy metals by ZSF ceramics reached the equilibrium status within 3 hours. The optimal calcination temperature range for removal of heavy metals was measured to be $800{\sim}1,000^{\circ}C$. The calcination time had little effect on the removal of heavy metal in AMD. The adequate dose of ceramics was shown to be 1.0~1.2 % for removal of heavy metals in AMD. High removal efficiencies of heavy metals (Al, As, Cd, Cu, Fe, Mn, Zn) in AMD, more than 95 % except for Pb, were obtained under the condition of dose of ceramics more than 1.0 %. The removal efficiencies of heavy metals increased with increasing mixing concentration of wood flour. The adequate mixing concentration of wood flour was observed to be 10 %. The batch experimental results exhibited that the ZSF ceramics could act as an efficient ceramics for removal of heavy metals in AMD and the wood flour could provide porous ZSF ceramics with enhanced removal efficiency of heavy metals.

• Journal of the Korean Wood Science and Technology
• /
• v.45 no.1
• /
• pp.107-115
• /
• 2017

In this study, the surface check reduction effect of preservative-treated Korean larch round-wood was investigated by applying three physical treatments, such as incising, kerfing, and kiln-drying. Moreover, the possibility of long-term service life was also checked by comparing the depth of surface check and the penetration depth of preservative. A rapid gradient of wood moisture content between surface and center causes a surface check. Thus, the effect of reducing surface check was carried out at the lowest equilibrium moisture content (EMC) condition, temperature ($2^{\circ}C$), humidity (44.6%), in outdoor locations in Korea until the test specimens reach to the 8.6% EMC. As a result, the preservative-treated specimens without incising, kerfing, kiln-drying (Type C) could not ensure the long-term service life due to a large surface check. Because the surface check depth of all specimens was deeper than the penetration depth of preservative. In case of the incising treated specimens (Type I), 80% of them, the depth of surface check was not deeper than the penetration depth of preservative. However, when a kerfing was additionally treated (Type B), a possibility of happening deeper surface check than penetration depth of preservative was increased rather than Type I.

• Journal of the Korean Institute of Gas
• /
• v.24 no.5
• /
• pp.56-64
• /
• 2020

This study presents the hydrate induction time of PVCap according to subcooling temperature, salt concentration, and MEG concentration in order to analyze the inhibition effect of PVCap in various production environments of offshore gas fields. A high-pressure hydrate generator was made for the hydrate formation experiments. It was verified that the apparatus had sufficient reliability by comparing the results of hydrate equilibrium conditions and induction time from the apparatus with published reference data. As the subcooling temperature increased from 6.1℃ to 12.1℃, the induction time of PVCap concentration of 0.1~1 wt% decreased. When the salt concentration increased from 3 wt% to 7 wt%, the induction time was reduced by up to 78% under the condition of 0.5 wt% PVCap due to polymer structure degradation by salt effect. In the case of HHI (hybrid hydrate inhibitor) made by mixing MEG 10 wt% and PVCap, the change in induction time was not large compared to PVCap 1 wt% due to the under-inhibition effect. On the other hand, the hydrate inhibition efficiency of HHI with MEG 20wt% increased 1.7 times compared to PVCap.

• Journal of Korean Society of Environmental Engineers
• /
• v.31 no.8
• /
• pp.663-672
• /
• 2009

In this studies, the adsorption test using Chlorella pyrenoidosa was conducted to examine the effect of Pb adsorption according to various immobilized methods such as Ca-alginate, K-carrageenan, and Polyacrylamide. From the results, the duration to need to reach adsorption equilibrium was delayed according to the immobilization. And, the higher adsorption capacity of immobilized Chlorella pyrenoidosa was represented in the higher concentration of Pb, the smaller amount of immobilizing agent, and the higher pH of solution. The maximum adsorption capacity of Pb was shown in the adsorption test using Chlorella pyrenoidosa immobilized with Ca-alginate even though it was sensitive pH. The adsorption results properly represented with Freundlich isotherm equations. And, pseudo second-order chemisorption kinetic rate equation was applicable to all the biosorption data over the entire time range. The FT-IR analysis showed that the mechanism involved in biosorption of Pb by Chlorella pyrenoidosa was mainly attributed to Pb binding of carbo-acid and amide group. Adsorbed Pb on immobilized Chlorella prenoidosa was easily desorbed in the higher concentration of desorbents(NTA, HCl, EDTA, $H_2SO_4,\;Na_2CO_3$). Among the several desorbents, NTA showed the maximum desoption capacities of Pb from Chlorella pyrenoidosa immobilized with Ca-alginate and K-carrageenan and EDTA was the most effective in Chlorella pyrenoidosa immobilized with polyacrylamide. The desoprtion efficiency in the optimum condition was 90.0, 83.0, and 80.0%, respectively.

• Journal of Korean Society of Environmental Engineers
• /
• v.36 no.9
• /
• pp.641-647
• /
• 2014

In this study, sludge waste which has a difficulty in treating it was used to manufacture a fiber type of biosorbent. To solve the problems such as the release of organic pollutants and the difficulty in separating solid from treated water, entrapment method using Ca-alginate was used to immobilize sludge waste. Considering ease of manufacture as well as improvement of adsorptive ability, the biosorbent was manufactured in the form of fiber type. Optimum immobilization condition for minimizing the amount of alginate used and maximizing the performance of biosorbent was determined to be 10 g/L alginate concentration, 40 g/L sludge concentration, and 0.3-0.4 mm fiber diameter. The maximum Cd(II) uptake of the biosorbent was 60.73 mg/g. Pseudo-second-order kinetic model and Langmuir isotherm model adequately described the dynamic and equilibrium behaviors of Cd(II) biosorption onto the biosorbent, respectively. In conclusion, sludge waste generated from wastewater treatment process is a cheap raw material for the manufacture of biosorbent which can be used to remove toxic heavy metals from industrial wastewaters efficiently.

• Journal of Korea Technology Innovation Society
• /
• v.10 no.1
• /
• pp.47-72
• /
• 2007

Ideas do not become exhausted, and there are no diminishing returns in the creation of knowledge. Nonetheless, growth ultimately ceases in this simplest model of endogeneous innovation. The reasons are similar to those that are discussed in the context of the neoclassical model of capital accumulation. Even if the resource cost of creating new goods does not rise, the economic return to invention may decline as the number of available products increases. When the rate of return to R&D falls to the level of the discount rate, private agents cease to be willing to defer consumption in order to invest in product development. But, if we treat knowledge capital as a public capital considering of its non-appropriable benefits, economic growth can be sustained in the economy. Romer(1986) has pointed out that growth might be sustainable if the accumulation of knowledge is not subject to long-run diminishing returns. Actually Romer assumed diminishing returns in the production of private knowledge from available resources, but increasing returns in the production of output from labor and total (public and private) knowledge. His condition for the sustainability of long-run growth amounts to an assumption that the diminishing returns in the former activity do not outweigh the increasing returns in the latter. The Johansen(1988) cointegration test method is used for finding long-run equilibrium relationship between R&D input and the product innovation. Test results indicate the existence of cointegrating equation between each pair of regression variables including dependent variable in the knowledge production function. And, the signs of cointegrating vectors are well accord to the prediction of sustainable growth. In the empirical analysis, from all cases of the form for the knowledge production function, we could not reject the null hypothesis that R&D spillover effect is significant($H_{0}:\;{\gamma}=1$). In summary, we showed that considering goodness of fit of regression model, we can see that the empirical evidence is strongly in favor of the character of knowledge as the public knowledge capital. So, we can expect that by product innovation, economic growth can be sustained in the Korean economy.

• Korean Journal of Agricultural Science
• /
• v.29 no.2
• /
• pp.53-66
• /
• 2002

This study was performed to evaluation the consolidation behavior of agricultural reservoir in the very soft ground. The final settlement prediction methods by Terzaghi, Hyperbolic and Asaoka methods were used to compare with the degree of consolidation estimated by exess pore water pressure. The dissipated excess pore water pressure during embankment construction and peak excess pore water pressure on the completed embankment were suggested for the estimation of the degree of consolidation. It was concluded that the degree of consolidation estimated from dissipated excess pore water pressure was more reliable than that from the peak excess pore water pressure. The stability methods for agricultural reservoir was used to compare and analyze with various condition by limit equilibrium method.

• Journal of the Korean Electrochemical Society
• /
• v.2 no.3
• /
• pp.150-155
• /
• 1999

The Electrochemical stabilities of the Brewer-Engel type intermetallic compounds of Co-Mo $(35 wt\%)$ and Ni-Mo$(35 wt\%)$ manufactured by the arc-melting method for the hydrogen electrode of $H_2-O_2$ alkaline fuel cell were investigated. Effects of temperature and concentration on the electrochemical behavior of the electrodes in the $80^{\circ}C$ 6 N KOH solution deaerated with $N_2$ gas were studied by electrochemical methods. The effect of overpotential on the electrochemical stabilities of Co-Mo and Ni-Mo intermetallic compounds was also discussed under the normal operation condition of AFC. It was shown that Co-Mo electrode had lower electrochemical stability as compared to Ni-Mo. In the case of Co-Mo electrode, a simultaneous dissolution of cobalt and molybdenum has occurred at low anodic overpotential form equilibrium hydrogen electrode potential, but the dissolution of cobalt was serious, and Co(OH)l layer on the electrode surface formed at the high anodic overpotential. In contrast the Ni-Mo electrode had high electrochemical stability because formation of the dense and thin protective $Ni(OH)_2$ layer prevented the dissolution of molybdenum.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.3 no.1
• /
• pp.16-24
• /
• 1998

In this study, Ocean General Circulation Model (OGCM) has been developed as a counterpart of Atmospheric General Circulation (AGCM) for the study of coupled ocean-atmosphere climate system. The oceanic responses to given atmospheric boundary conditions have been investigated using the OGCM. In an integration carried out over 100 simulated years with climatological monthly mean data (EXP 1), most parts of the model reached a quasi-equilibrium climate reproducing many of the observed large-scale oceanic features remarkably well. Some observed narrow currents, however, such as North Equatorial Counter Current, were inevitably distorted due to the model's relatively coarse resolution. The seasonal changes in sea ice cover over the southern oceans around Antarctica were also simulated. In an experiment (EXP 2) under boundary condition of 10-year monthly data (1982-1991) from NCEP/NCAR Reanalysis Project model properly reproduced major oceanic changes during the period, including El Ni$\tilde{n}$os of 1982-1983 and 1986-87. During the ENSO periods, the experiment showed eastward expansion of warm surface waters and a negative vertical velocity anomalies along' the equator in response to expansion of westerly current velocity anomalies as westerly wind anomalies propagated eastward. Simulated anomalous distribution and the time behavior in response to El Ni$\tilde{n}$o events is consistent with that of the observations. These experiments showed that the model has an ability to reproduce major mean and anomalous oceanic features and can be effectively used for the study of ocean-atmosphere coupling system.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.8 no.4
• /
• pp.365-375
• /
• 2006

The structural analysis for the secondary lining of tunnels is generally performed by a frame analysis model. This model requires a ground loosening load estimated by some empirical methods, but the load is likely to be subjective and too large. The ground load acting on the secondary lining is due to the loss of the supporting function of the first support members such as shotcrete and rockbolts. Therefore, the equilibrium condition of the ground and the first support members should be considered to estimate the ground load acting on the secondary lining. Ground-lining interaction model, shortly GLI model, is developed on the basis of the concept that the secondary lining supports the ground deformation triggered by the loss of the support capacity of the first support members. Accordingly, the GLI model can take into account the ground load reflecting effectively not only the complex ground conditions but the installed conditions of the first support members. The load acting on the secondary lining besides the ground load includes the groundwater pressure and earthquake load. For the structural reinforcement of the secondary lining based on the ultimate strength design method, the factored load and various load combination should be considered. Since the GLI model has difficulty in dealing with the factored load, introduced in this study is the superposition principle in which the section moment and force of the secondary lining estimated for individual loads are multiplied by the load factors. Finally, the design method of the secondary lining using the GLI model is applied to the case of a shallow subway tunnel.