• Applied Chemistry for Engineering
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• v.10 no.1
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• pp.166-172
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• 1999

Fixed-bed adsorption of metal ions on chitosan bead was studied to remove heavy metal ions in waste water. Chitin was extracted from carb shell and chitosan was prepared by deacetylation of the chitin. The chitosan in bead was used as an adsorbent for heavy metal ions. Freundlich and Langmuir isotherm was determined from the experimental results of equilibrium adsorption for individual metal ion ($Cu^{2+}$, $Co^{2+}$, $Ni^{2+}$) on chitosan bead. Adsorption strength of metal ions decreased in the order of $Cu^{2+}$>$Co^{2+}$>$Ni^{2+}$ ion. Breakthrough curves of single and multicomponent adsorption for metal ions were obtained from the experimental results of fixed-bed adsorption. The breakthrough curves were analyzed by simulation with fixed-bed adsorption equation based on LDFA (linear driving force approximation) adopted LAS (ideal adsorbed solution) theory which can predict multi-component adsorption isotherm from individual adsorption isotherm. The behavior of fixed bed adsorption for single and multi-component system could be nicely simulated by the equation.

• Polymer(Korea)
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• v.27 no.1
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• pp.61-68
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• 2003

In this study, we have investigated the preparation of mixed bead and fiber type hybrid ion-exchanger for recovering nickel ion from plating rinse water. There was little dependence of adsorption capacity for nickel ion on the mixing ratio of resin type and fiber type of ion exchangers. However, it increased with increasing the resin content in the mixed bed. It was shown that the data Langmuir and Freundlich's adsorption isotherm model were well fitted to the linear. Affinity between the functional groups in the ion exchanger and nickel ion in the process was confirmed. The pressure drop decreased with increasing the number of stage in the multistage bed, but it increased with increasing the resin content in the mixing bed. The initial breakthrough time in the multistage bed was short due to the increase of number of stage in the continuous process. It was found that the final breakthrough time of the multistage bed was little changed. The breakthrough time decreased with increasing the amount of fibrous ion exchanger in the mixed bed. The maximum adsorption capacities of the mixed and multistage beds were 2.51 meq/g and 2.69 meq/g, respectively. The desorption time for the nickel ion with $1N H_2SO_4$ solution was lower than 10 minutes and the yield of desorption was greater than 98 percent.

• Journal of Korea Water Resources Association
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• v.35 no.1
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• pp.77-90
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• 2002

The condition of initial movement for the river bed revetment using rip rap is a limit condition beyond which the lining is progressively destroyed as the separate elements are removed by the flow. In the case of the river bed revetment using mattress, however, after the initial movement the containment offered by the mesh remains. A new situation of equilibrium with a deformed river bed revetment using mattress is obtained, allowing it to withstand more severe conditions without compromising the resistance and without further bed deformation. Shield's coefficient for the river bed revetment using mattress is twice the value of that for the river bed revetment using rip rap. This means that with the same hydraulic behavior conditions, the average dimension of the rocks to be used in the river bed revetment using mattress is half that of the river bed revetment using rip rap rock. When the same size rocks are used the allowable velocity for the river bed revetment using mattress is more than twice, even as much as 3 or 4 times that for the river bed revetment using rip rap.

• Journal of the Korean Society of Safety
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• v.7 no.1
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• pp.13-19
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• 1992

Supercritical fluid technology was applied to the regeneration of industrial catalyst contaminated with toxic materials. The regeneration process of activated loaded with phenol was proposed, then the adsorphon tower was packed with the activated carbon-bed. Phenol diffuses into supercritical carbon dioxide(SCC) through the micro-pore and voldge of the activated carbon. The saturated solubility of phenol in SCC depended on the density of SCC varing with temperature and pressure conditions. Therefore, the fasile phase equilibrium calculation model of dxpanded liquid One was proposed, and equilibrium solubility of phenol in SCC was calculated using the model theoretically. The regeneration mechanism of activated carbon was analysed by degree of saturation of phenol and diffusion in SCC. The solubility prediction was more satisfactory for the wide range of SCC density than the dense gas model and the desorption of phenol depended on the degree of saturation of phenol in SCC.

• Journal of Environmental Health Sciences
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• v.24 no.3
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• pp.41-47
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• 1998

The purpose of this research is evaluation of adsorption capacity of the cast for TCE comparing with the yellow clay. Furthermore, the experimental data was fitted with the Langmuir and Freundlich isotherm and was found to be apllicable to the adsorption isotherm equation. The soil bed reactor used in this study was made of glass(10 cm in diameter, 100 cm in depth). The cast and yellow clay used as adsorbents were screened with 8-20 mesh mecanically. Results from Equilibrium test with adsorbents showed that the equibrium time of the cast and yellow clay was 9min independent of the amount of the adsorbents. The adsorption efficiencys of the cast and yellow clay for TCE was 66.3% and 56.2%, respectively. In the application of Freundlich isotherm, 1/n of the cast and yellow clay were 0.786 and 0.704, respectively. These results showed that the cast was more available than the yellow clay as TCE adsorbent. The best adsorption capacity was showed at 0% moisture content, 70 ppm inlet concentration and 25$^{\circ}$C temperature.

• 한국해양학회지
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• v.10 no.2
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• pp.67-75
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• 1975

Tidal Flushing at the entrance channels of tidal bay or estuary in the central western coast of Korea; Gum River Estuary, Garorim Bay, Asan Bay, and Yeomha Estuary were studied with the recent data of current surveys measured by curret meter at three or five anchored stations along the section for one or two tidal periods at mean spring tide. Equilibrium relationship between tidal prism at mean spring tide and minimum flow area below the mean sea level of the channel in alluvial material was found as of O'Brien's (1931, 1969) study. Bed load transport in the tidal channel is balanced with the tidal flushing ability having a mean velocity of about 0.75m/sec or maximum velocity of about 1.25m/sec for a half tidal cycle over the section at mean spring tide which fairly agree with Brunn's study(1955, 1957). flushing actions for different hydraulic depth( mean depth) and bed material size in the channel were reviewed and found that it depend to a minor extent on the factors.

• Korean Journal of Hydrosciences
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• v.1
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• pp.61-71
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• 1990

The characteristics of radial thickness of ice jam at the center part of channel bends were analyzed briefly in this paper. Jam thickness in channel bends increases both toward the inner bank, and dowmstream. For this study, slope at the jam's underside was assumed to be liner with similarity of radial slope of bed in alluvial bends. Radial slope at the jam's underside in floating ice elements was estimated using the force equilibrium theory in the radial direction. The eqution which can be estimated the radial slope of ice jam was suggested using Falcon and Kennedy's bed layer theory. Experimental data, which were measured at the center part of cross-section in a single 180-degree bend, were compared to the calculated values using the suggested equtions. The result shows that the calcultated values were smaller than the measured ones. Ot is considered that the estimated value of shear stress in the radial direction may be smaller than the actual and two-layer model may be not suibable for alluvial bend flow.

• Journal of Korean Society on Water Environment
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• v.25 no.4
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• pp.568-572
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• 2009

The adsorption characteristics of tartrazine by granular activated carbon were experimentaly investigated in the batch adsorber and the packed column. The adsorptivity of activated carbon for tartrazine was largely improved by pH control, and 98 percent of initial concentration could be removed at pH 3. It was estabilished that the adsorption equilibrium of tartrazine on granular activated carbon was sucessfully fitted by Freundlich isotherm equation in the concentration range from 50 mg/L to 1,000 mg/L. The characteristics of breakthrough curve of activated carbon packed column, which depend on the design variables such as initial concentration, bed height, and flow rate, were studied.

• Magazine of the Korean Society of Agricultural Engineers
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• v.23 no.1
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• pp.64-74
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• 1981

The stream morphological characteristics of watershed have important influence upon the analysis of runoff. In this study, the effect of the map scale on the stream morphological characteristics was used on the data taken from 15'(1:50, 000) and 7'30"(1 :25,000) topographic maps which could cover the whole Miho River basin This basin are the first tributary of the Geum. River. Otherwise, the longitudinal stream bed profile was calculated by Yang's theoretical stream bed profile, equilibrium profile and actual profile. In the result of this investigation the conclusion is that the resultant relationship obtained from different topographic maps in the scale on the same stream system has come upon the same result as the stream morphological characteristics. Therefore, the great amount of time and effort can be saved in studing the stream morphological charecteristics by using the 15' instead of the 7'30"map system excluding the first order streams.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2003.11a
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• pp.73-77
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• 2003

In order to predict the dynamic behaviors of uranium and cobalt in a fixed bed at various influent pH values of liquid waste, the adsorption system was regarded as multi-component adsorption between each ionic species in a solution. Langmuir isotherm parameters of each species were extracted by incorporating equilibrium data with the solution chemistry of uranium and cobalt using IAST. Prediction results were in good agreement with the experimental data, except for a high concentration and pH. Although there was some limitations in predicting the cobalt adsorption, this method may be useful in analyzing a complex adsorption system where various kinds of ionic species exist in a solution.