• Environmental Engineering Research
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• 제20권1호
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• pp.73-78
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• 2015

The aim of this study was to examine the phosphate (P) removal by quintinite from aqueous solutions. Batch experiments were performed to examine the effects of reaction time, temperature, initial phosphate concentration, initial solution pH and stream water on the phosphate adsorption to quintinite. Kinetic, thermodynamic and equilibrium isotherm models were used to analyze the experimental data. Results showed that the maximum P adsorption capacity was 4.77 mgP/g under given conditions (initial P concentration = 2-20 mgP/L; adsorbent dose = 1.2 g/L; reaction time = 4 hr). Kinetic model analysis showed that the pseudo second-order model was the most suitable for describing the kinetic data. Thermodynamic analysis indicated that phosphate sorption to quintinite increased with increasing temperature from 15 to $45^{\circ}C$, indicating the spontaneous and endothermic nature of sorption process (${\Delta}H^0=487.08\;kJ/mol$; ${\Delta}S^0=1,696.12\;J/(K{\cdot}mol)$; ${\Delta}G^0=-1.67$ to -52.56 kJ/mol). Equilibrium isotherm analysis demonstrated that both Freundlich and Redlich-Peterson models were suitable for describing the equilibrium data. In the pH experiments, the phosphate adsorption to quintinite was not varied at pH 3.0-7.1 (1.50-1.55 mgP/g) but decreased considerably at a highly alkaline solution (0.70 mgP/g at pH 11.0). Results also indicated that under given conditions (initial P concentration=2 mgP/L; adsorbent dose=0.8 g/L; reaction time=4 hr), phosphate removal in the stream water (1.88 mgP/g) was lower than that in the synthetic solution (2.07 mgP/g), possibly due to the presence of anions such as (bi)carbonate and sulfate in the stream water.

• 한국환경과학회지
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• 제20권5호
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• pp.555-564
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• 2011

This study examines the potential restoration of abandoned channels of the Mangyeong River in South Korea. To analyze the morphological changes and equilibrium conditions, a flow duration analysis was performed to obtain the discharge of 255 m3/s with a recurrence interval of 1.5 year. It is a gravel-bed stream with a median bed diameter of 36 mm. The reach-averaged results using HEC-RAS showed that the top width is 244 m, the mean flow depth is 1.11 m, the width/depth ratio is very high at 277, the channel velocity is 1.18 m/s, and the Froude number is also high at 0.42. The hydraulic parameters vary in the vicinity of the three sills which control the bed elevation. The total sediment load is 6,500 tons per day and the equivalent sediment concentration is 240 mg/l. The Engelund-Hansen method was closer to the field measurements than any other method. The bed material coarser than 33 mm will not move. The methods of Julien-Wargadalam and Lacey gave an equilibrium channel width of 83 m and 77 m respectively, which demonstrates that the Mangyeong River is currently very wide and shallow. The planform geometry for the Mangyeong River is definitely straight with a sinuosity as low as 1.03. The thalweg and mean bed elevation profiles were analyzed using field measurements in 1976, 1993 and 2009. The measured profiles indicated that the channel has degraded about 2 m since 1976. The coarse gravel material and large width-depth ratio increase the stability of the bed material in this reach.

• Geomechanics and Engineering
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• 제23권4호
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• pp.313-325
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• 2020

Slope displacement and factor of safety (FOS) of a slope are two aspects that reflect the stability of a slope. However, the traditional limit equilibrium (LE) methods only give the result of the slope FOS and cannot be used to solve for the slope displacement. Therefore, developing a LE method to obtain the results of the slope FOS and slope displacement has significance for engineering applications. Based on a force-displacement coupled mode, this work expands the LE Morgenstern-Price (M-P) method. Except for the mechanical equilibrium conditions of a sliding body adopted in the traditional M-P method, the present method introduces a nonlinear model of the shear stress and shear displacement. Moreover, the energy equation satisfied by a sliding body under a small slope displacement is also applied. Therefore, the double solutions of the slope FOS and horizontal slope displacement are established. Furthermore, the flow chart for the expanded LE M-P method is given. By comparisons and analyses of slope examples, the present method has close results with previous research and numerical simulation methods, thus verifying the feasibility of the present method. Thereafter, from the parametric analysis, the following conclusions are obtained: (1) the shear displacement parameters of the soil affect the horizontal slope displacement but have little effect on the slope FOS; and (2) the curves of the horizontal slope displacement vs. the minimum slope FOS could be fitted by a hyperbolic model, which would be beneficial to obtain the horizontal slope displacement for the slope in the critical state.

• 공업화학
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• 제27권6호
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• pp.590-598
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• 2016

본 연구는 흡착제로 야자각계 수증기 활성화 입상 활성탄을 사용하여 Acid Black 1 수용액에서의 흡착 거동과 동역학적, 열역학적 파라미터에 대해 회분식 반응을 통해 조사하였다. 흡착변수로는 pH, 초기농도, 접촉시간, 온도를 사용하였다. pH에 대한 영향을 조사하기 위해 pHpzc 값을 분석한 뒤 pH 3-11 범위에서 제거율을 조사하였다. 흡착평형자료로부터 Langmuir, Freundlich, Temkin, Dubinin-Radushkevich 등온 흡착식에 대한 적합성을 평가하였다. 흡착공정에 대한 동역학적 해석을 통해 유사 1차반응식과 유사 2차반응식에 대한 흡착반응의 일치도를 평가하였다. 열역학적 해석을 통해 엔탈피 변화 값과 활성화에너지 값을 조사하여 이를 통해 흡착공정이 흡열반응인지를 확인하였으며, 엔트로피 변화 값과 자유에너지 값을 통해 흡착공정의 자발성을 확인하였다.

• Nuclear Engineering and Technology
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• 제49권1호
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• pp.148-164
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• 2017

The focus on the issues surrounding spent nuclear fuel and lifetime extension of old nuclear power plants continues to grow nowadays. A transparent decision-making process to identify the best suitable nuclear fuel cycle (NFC) is considered to be the key task in the current situation. Through this study, an attempt is made to develop an equilibrium model for the NFC to calculate the material flows based on 1 TWh of electricity production, and to perform integrated multicriteria decision-making method analyses via the analytic hierarchy process technique for order of preference by similarity to ideal solution, preference ranking organization method for enrichment evaluation, and multiattribute utility theory methods. This comparative study is aimed at screening and ranking the three selected NFC options against five aspects: sustainability, environmental friendliness, economics, proliferation resistance, and technical feasibility. The selected fuel cycle options include pressurized water reactor (PWR) once-through cycle, PWR mixed oxide cycle, or pyroprocessing sodium-cooled fast reactor cycle. A sensitivity analysis was performed to prove the robustness of the results and explore the influence of criteria on the obtained ranking. As a result of the comparative analysis, the pyroprocessing sodium-cooled fast reactor cycle is determined to be the most competitive option among the NFC scenarios.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2001년도 봄 학술발표회 논문집
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• pp.257-264
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• 2001

This study presents the slope stability analysis results for the model slope test. The model slope was made of the soil reinforced by FPF(Fibrillated Polyprophylene Fiber). The shear strength properties of the soil reinforced by FPF fibers were evaluated through the direct shear tests. The model slope 1:1 and 1:1.5 were made and the load tests were performed. Back analysis using limit equilibrium method was carried out to evaluate the shear strength increase on the FPF reinforced slope. The factor of safety of the FPF reinforce slope increased about 23% over unreinforced slope.

• 한국주조공학회지
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• 제25권1호
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• pp.36-39
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• 2005

The thermodynamic analysis of deoxidation in molten coppyr by Fe has been made. Equilibrium oxygen solubility saturated with FeO in Cu-Fe-O system has been derived without and with consideration of the solute interaction between Fe and O. The derived relationship of oxygen contents with Fe has been compared with the experimental results done by Kulkarni and the minimum oxygen solubility could be predicted by a simple first order interaction method, Wagner model.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 1997년도 가을 학술발표회 논문집
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• pp.119-125
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• 1997

The finite element analysis of plate and shell structures has been one of the major research interests for many years because of the technological importance of such structures. Quite often these structures are constructed by laminated composites. This is due to the high specific stiffness and strength of composite structures. The main objective of this paper is to extend the use of an improved degenerated shell element to the large displacement analysis of plates and shells with laminated composites. The total Lagrangian approach has been chosen for the definition of the deformation and the solution to the nonlinear equilibrium equations is obtained by the Newton-Raphson method.

• 한국산학기술학회논문지
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• 제5권5호
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• pp.371-376
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• 2004

본 논문은 열평형 기술을 활용하여 다단계 조절이 가능한 유니베이커 오븐에 대하여 CFD(computational fluid dynamics) 해석을 수행하여 오븐내부의 열유동분포와 속도를 파악함으로서 오븐 내부의 열평형을 이룰 수 있는 최적 위치를 예상함으로서 유니베이커 오븐의 설계 자료로 이용하고자 한다.

• 한국전산유체공학회지
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• 제13권4호
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• pp.50-57
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• 2008

The prediction of hydrate pellet decomposition characteristics is required to design the regasification process of GTS (gas to solid) technology, which is considered as an economic alternative for LNG technology to transport natural gas produced from small and stranded gas wells. Mathematical model based on the conservation principles, the phase equilibrium relation, equation of gas state and phase change kinetics was set up and numerical solution procedure employing volume averaged fixed grid formulation and extended enthalpy method are implemented. Initially, porous methane hydrate pellet is at uniform temperature and pressure within hydrate stable region. The pressure starts to decrease with a fixed rate down to the final pressure and is kept constant afterwards while the bounding surface of pellet is heated by convection. The predicted convective heat and mass transfer accompanied by the decomposed gas flow through hydrate/ice solid matrix is reported focused on the comparison of spherical and cylindrical pellets having the same effective radius.