• Title/Summary/Keyword: equations of state

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Simulation and Control of the Molten Carbonate System using Aspen $Dynamics^{TM}$ and ACM (Aspen $Dynamics^{TM}$와 ACM을 이용한 용융탄산염 연료전지 시스템의 모사 및 제어)

  • Jeon, Kyoung Yein;Kwak, Ha Yeon;Kyung, Ji Hyun;Yoo, Ahrim;Lee, Tae Won;Lee, Gi Pung;Moon, Kil Ho;Yang, Dae Ryook
    • Korean Chemical Engineering Research
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    • v.49 no.4
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    • pp.423-431
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    • 2011
  • Recentincreasing awareness of the environmental damage caused by the $CO_2$ emission of fossil fuelsstimulated the interest in alternative and renewable sources of energy. Fuel cell is a representative example of hydrogen energy utilization. In this study, Molten Carbonate Fuel Cell system is simulated by using $Aspen^{TM}$. Stack model is consisted of equilibrium reaction equations using $ACM^{TM}$(Aspen Custom Modeler). Balance of process of fuel cell system is developed in Aspen $Plus^{TM}$ and simulated at steady-state. Analysis of performance of the system is carried out by using sensitivity analysis tool with main operating parameters such as current density, S/C ratio, and fuel utilization and recycle ratio.In Aspen $Dynamics^{TM}$, dynamics of MCFC system is simulated with PID control loops. From the simulation, we proposed operation range which generated maximum power and efficiency in MCFC power plant.

Gender Mechanism of Korean Welfare Politics: Gender Difference in Attitudes and Mediating Effects of Welfare Statuses (한국 복지정치의 젠더메커니즘: 태도의 성별차이와 복지지위 매개효과를 중심으로)

  • Kim, Eun-Ji;Ahn, Sang-Hoon
    • Korean Journal of Social Welfare Studies
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    • v.41 no.2
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    • pp.309-334
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    • 2010
  • This study explores gender mechanism of welfare politics in Korea from the perspective of welfare status theory. In the simplistic analysis, it is found that there is no gender difference in welfare attitudes. In the more sophisticated analysis of welfare-status-beased SEM, however, it is found that Korean welfare politics is to be understood in terms of gender-related politics. Three major findings of this study are as follows. Firstly, Korean women possess less pro-welfare attitudes in terms of the status of welfare beneficiary. This is due to the visible gender segregation in the Korean labor market on the one hand and due to the centrality of social insurance programs in the structure of Korean public welfare system on the other hand. Secondly, Korean women have relatively higher level of pro-welfare attitude when it comes to the status of welfare service provider. Thirdly, Korean women tend to be more supportive to pro-welfare parties as they have less chance to be a higher taxpayer. Based on the above mentioned findings, this study concludes that it is possible to make Korean women be more pro-welfare if the Korean welfare state expands more social services that tend to meet urgent needs of women.

Reliability Analysis of Plane Stress Element According to Limit State Equations (한계상태방정식에 따른 평면응력요소의 신뢰성해석)

  • Park, Seok Jae;Choi, Wae Ho;Kim, Yo Suk;Shin, Yeong-Soo
    • Journal of Korean Society of Steel Construction
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    • v.13 no.5
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    • pp.567-575
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    • 2001
  • In order to consider statistical properties of probability variables used in the structural analysis the conventional approach using the safety factor based on past experience usually estimated the safety of a structure Also the real structures could only be analyzed with the error in estimation of loads material characters and the dimensions of the members. But the errors should be considered systematically in the structural analysis Safety of structure could not precisely be appraised by the traditional structural design concept Recently new aproach based on the probability concept has been applied to the assessment of structural safety using the reliability concept Thus the computer program by the Probabilitstic FEM is developed by incorporating the probabilistic concept into the conventional FEM method. This paper estimated for the reliability of a plane stress structure by Advanced First-Order Second Moment method using von Mises, Tresca and Mohr-Coulomb failure criterions. Verification of the reliability index and failure probability of attained by the Monte Carlo Simulation method with the von Mises criterion were same as PFEM, but the Monte Carlo Simulation were very time-consuming. The variance of member thickness and load could influence the reliability and failure probability most sensitively among the design variables from the results of the parameter analysis. The proper failure criterion according to characteristic of materials must be used for safe design.

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Study on the Micellization of CPC/Brij 35 Mixed Surfactant Systems in Water (순수 물에서 CPC/Brij 35 혼합계면활성제의 미셀화에 대한 연구)

  • Gil, Han-Nae;Lee, Byung-Hwan
    • Journal of the Korean Chemical Society
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    • v.53 no.2
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    • pp.118-124
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    • 2009
  • The values of critical micelle concentration (CMC) and counter ion binding constants (B) in a micellar state of CPC (1-hexadecylpyridinium chloride) with Brij 35 (polyoxyethylene(23) lauryl ether) in water were determined as a function of ${\alpha}_1$ (the overall mole fraction of CPC) by the use of electric conductivity method. Various thermodynamic parameters ($X_i,\;{\gamma}_i,\;C_i,\;a_{i}^{M},\;\beta,\;and\;{\Delta}H_{mix}$) were calculated and analyzed by means of the equations derived from the non-ideal mixed micellar model. And thermodynamic parameters (${\Delta}{G^o}_m,\;{\Delta}{H^o}_m,\;and\;{\Delta}{S^o}_m$) for the micellization of CPC/Brij 35 mixtures were also calculated from the temperature dependence of the CMC values. The values of ${\Delta}{G^o}_m$ are all negative, but the values of ${\Delta}{S^o}_m$ and ${\Delta}{H^o}_m$ are positive or negative, depending on the measured temperature and ${\alpha}_1$.

Non-Destructive Prediction of Head Rice Ratios using NIR Spectra of Hulled Rice (정조 상태에서 백미에 대한 완전미율의 비파괴 예측)

  • Kwon, Young-Rip;Cho, Seung-Hyun;Lee, Jae-Heung;Seo, Kyoung-Won;Choi, Dong-Chil
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.53 no.3
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    • pp.244-250
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    • 2008
  • The purpose of this study was to measure fundamental data required for the prediction of milling ratios, and to develop regression models to predict the head rice ratio of milled rice using NIR spectra of hulled rice. A total of 81 rice samples used in this study were collected from Jeongeup, Jeonbuk province in 2006. NIR spectra were measured using one mode of measurement, reflection. The reflectance spectra were measured in the wavelength region of 400-2500 nm with an NIR spectrophotometer "NIRSystems 6500" (Foss, Silverspring, USA). Calibration equations were developed by the modified partial least squares (MPLS), partial least squares (PLS), and principal components regression (PCR). Math treatments were 1-4-4-1, 1-10-10-1, 2-4-4-1, and 2-10-10-1. The software used was WinISI (Infrasoft International, State College, USA). Automatic head rice production and quality checking system used was "SY2000-AHRPQCS" (Ssangyong, Korea). The calibration was made with the first derivative and the spectrum designated was in 8 nm interval. The determination coefficients of head rice ratios were 0.8353, 0.8416 and 0.5277 for the MPLS, PLS and PCR, respectively. Those obtained with 20 nm interval were 0.8144, 0.8354 and 0.6908 for the MPLS, PLS and PCR, respectively. The calibration was made with second derivative that spectrum designated was 8 nm in interval. The determination coefficients of head rice ratios were 0.7994, 0.8017 and 0.4473 for the MPLS, PLS and PCR, respectively. Those with 20 nm interval were 0.8004, 0.8493 and 0.6609 for the MPLS, PLS and PCR, respectively. These results indicate that the accuracy of determination coefficient for MPLS and PLS is higher than that of PCR.

The Roles of Wind Shadow Aspect Ratio upon the Behaviors of Transverse Dunes : A Dynamics Analysis on the Behavior Space (바람그늘의 기울기가 횡사구의 지형발달에서 담당하는 역할 -거동 공간상의 동역학적 분석을 중심으로-)

  • RHEW, Hosahng
    • Journal of the Korean association of regional geographers
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    • v.22 no.4
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    • pp.887-911
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    • 2016
  • The empirical law that transverse dunes migrate inversely with their heights leads logically to the prediction that multiple dune ridges will converse to a single huge dune by merging. This contradicts the existence of the steady state dune fields on the Earth. The recent studies have emphasized dune collisions as a key mechanism to the stability of dunefield. The roles of wind shadow aspect ratio, however, have yet to be fully explored. This research aims to investigate the potential roles of wind shadow aspect ratio in the dynamical behaviors of transverse dune field. The simplified model is established for this, based upon allometric properties of transverse dunes, wind speedup on the stoss slope and sand trapping efficiency. The derived governing equations can be transformed to the zoning criteria and vector field for dune evolution. The dynamics analysis indicates that wind shadow aspect ratios do not produce convergent areas on the behavior space; rather, they just act as one of the factors that affect the trajectories of dune evolution. Though the model cannot represent the stability of dune field, but seem to produce a reasonable exponent for dune spacing-height relations.

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A Study on the Flexural Minimum Reinforcement for Prevention of Brittle Failure Specified in KCI and EN Codes (유럽과 국내기준에 규정된 취성파괴 방지를 위한 휨 최소철근량 고찰)

  • Park, Sung-Jae;Kang, Tae-Sung;Moon, Do-Young
    • Journal of the Korea Concrete Institute
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    • v.26 no.2
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    • pp.211-218
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    • 2014
  • In the design of reinforced rectangular concrete beam structure, the minimum amount of flexural reinforcement is required to avoid brittle failure. KCI code is based on concept of ultimate strength and usually used as a model code. But bridge design code enacted by Ministry of land, transportation and maritime affairs in 2012 is based on concept of limit state and similar to Euro code EN 1992-2. This means that the minimum reinforcement presented in both design codes has different origination and safety margin. When rectangular concrete beams with minimum reinforcement are designed according to EN and KCI codes, the amount of minimum reinforcement specified in EN code is only 76% of that in KCI code. This makes the design engineers to be confused. In this study, flexural tests were conducted on nine beams with the two different minimum reinforcement specified in KCI and EN design codes. In results, the measured ratios of nominal strength to crack strength from the test were about 25% greater than those evaluated from the equations presented in KCI and EN codes. The EN beams having only 76% of the minimum reinforcement for the KCI beams were fractured by rupture of steel reinforcement but in ductile manner. It is confirmed that the minimum reinforcement concrete beams designed according to both codes have enough safety margin in flexural capacity and moreover in ductility.

A Three-Dimensional Galerkin-FEM Model with Density Variation (밀도 변화를 포함하는 3차원 연직함수 전개모형)

  • 이호진;정경태;소재귀;강관수;정종율
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.8 no.2
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    • pp.123-136
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    • 1996
  • A three-dimensional Galerkin-FEM model which can handle the temporal and spatial variation of density is presented. The hydrostatic approximation is used and density effects are included by means of conservation equation of heat and the equation of state. The finite difference grids are used in the horizontal plane and a set of linear-shape functions is used for the vertical expansion. The similarity transform is introduced to solve resultant matrix equations. The proposed model was first applied to the density-driven circulation in an idealized basin in the presence of the heat exchange between the air and the sea. The advection terms in the momentum equation were ignored, while the convection terms were retained in the heat equation. Coefficients of the vertical eddy viscosity and diffusivity were fixed to be constant. Calculation in a non-rotating idealized basin shows that the difference in heat capacity with depth gives rise to the horizontal gradient of temperature. Consequently, there is a steady new in the upper layer in the direction of increasing depth with compensatory counter flow .in the lower layer. With Coriolis force, geostrophic flow was predominant due to the balance between the pressure gradient and the Coriolis force. As a test in region of irregular topography, the model is applied to the Yellow Sea. Although the resultant flow was very complex, the character of the flow Showed to be geostrophic on the whole.

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Reliability-Based Assessment of Structural Safety of Steel-Concrete Hybrid Cable-Stayed Bridge Erected by the FCM and FSM during Construction (FCM과 FSM공법에 의한 강-콘크리트 복합사장교의 신뢰성에 기초한 시공간 구조안전도평가)

  • Yoon, Jung Hyun;Cho, Hyo Nam
    • Journal of Korean Society of Steel Construction
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    • v.19 no.5
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    • pp.515-526
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    • 2007
  • In this study, the models and methods for the safety assessment of Steel-Concrete Hybrid Cable-Stayed Bridge, which consists of steel composite girder and concrete girder erected by the FCM(Free Cantilever Method) and FSM(Full Staging Method) are proposed for the assurance of structural safety and the prevention against bridge collapse during construction. By the structural reliability approach that reasonably considers the uncertainties associated with the resistance and the load effect, the resistance and the load distribution characteristics of Steel-Concrete Hybrid Cable-Stayed Bridgeare defined and the strength limit state equations of permanent structures and temporary structures during construction are suggested. An AFOSM algorithm and MCS technique are used for the reliability analysis of cables, pylons, girders, steel-concrete conjunction part and temporary bents. Also, component reliability analyses are performed at the construction stages based on the structural system model. To demonstrate their rationality and practicality, the proposed models and approaches are applied to a real bridge. The sensitivity analyses of main parameters are performed in order to identify the critical factors that control the safety of similar bridges. As a result, it may be stated that the proposed models could be implemented as a rational and practical approach for the safety assessment of Steel-Concrete Hybrid Cable-stayed bridges erected by FCM and FSM during construction.

Flexural Behavior of High Performance Fiber Reinforced Cementitious Composites (HPFRCC) Beam with a Reinforcing Bar (휨 철근이 배근된 HPFRCC 보 부재의 휨 거동)

  • Shin, Kyung-Joon;Kim, Jae-Hwa;Cho, Jae-Yeol;Lee, Seong-Cheol
    • Journal of the Korea Concrete Institute
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    • v.23 no.2
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    • pp.169-176
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    • 2011
  • In this study, the flexural test for reinforced high performance fiber reinforced cementitious composites (R/HPFRCC) members has been conducted in order to investigate the flexural behavior including the effect of an ordinary tensile reinforcing bar. Through the test, it was observed that the flexural strength increased due to the stable tensile stress transfer of HPFRCC, even up to the ultimate state. In addition, no localized crack appeared until the yielding of the reinforcement. From the layered section analysis of the tested members, it was found that the analysis with the tensile model obtained from the tension stiffening test showed better agreement with the flexural test results, whereas the analysis with direct tension test results overestimated the flexural capacity. Through the experimental and analytical studies, two flexural failure modes have been defined in this paper; concrete crushing at the top compression layer or tensile failure at the bottom tensile layer of the beam section. Based on these two flexural failure modes, a simple formula that estimates the ultimate flexural strength of the member has been proposed in this paper. The proposed equations can be useful in a design and an analysis of R/HPFRCC members.