• Title/Summary/Keyword: epoxy

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Effects of early prepubertal exposure to bisphenol A on the onset of puberty, ovarian weights, and estrous cycle in female mice

  • Nah, Won-Heum;Park, Mi-Jung;Gye, Myung-Chan
    • Clinical and Experimental Reproductive Medicine
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    • v.38 no.2
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    • pp.75-81
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    • 2011
  • Objective: Bisphenol A (BPA) is a chemical used extensively to manufacture plastics and epoxy resin liners for food and beverage cans. BPA, with properties similar to estrogen, has endocrine-disrupting effects. In the present study, we examined the effects of early prepubertal BPA exposure on the onset of puberty and reproductive parameters such as estrous cycle and reproductive organ weights in female mice. Methods: Female mice were injected subcutaneously at postnatal day (PND) 8 with BPA (0.1, 1, 10, 100 mg/kg) in sesame oil or with sesame oil alone. Body weight was measured from PND 10 to 70. Vaginal opening and estrous cycle were monitored from PND 20 to 29. Animals were sacrificed at PND 25, 30, and 70, and the ovary and uterus weights were measured. Results: Early prepubertal exposure to BPA (10 and 100 mg/kg) significantly decreased body weight from PND 18 to 30. BPA treated mice at testing dose levels showed early opening of the vagina compared to the control group. The number of estrous cycle and days of estrus were significantly decreased in high dose (100 mg/kg) BPA treated mice. The ovary weight at PND 25 and 30 was significantly decreased in all BPA treatment groups. Conclusion: Early prepubertal exposure to BPA accelerated the onset of puberty but decreased reproductive parameters in female mice.

Investigation on interlaminar shear stresses in laminated composite beam under thermal and mechanical loading

  • Murugesan, Nagaraj;Rajamohan, Vasudevan
    • Steel and Composite Structures
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    • v.18 no.3
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    • pp.583-601
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    • 2015
  • In the present study, the combined effects of thermal and mechanical loadings on the interlaminar shear stresses of both moderately thin and thick composite laminated beams are numerically analyzed. The finite element modelling of laminated composite beams and analysis of interlaminar stresses are performed using the commercially available software package MSC NASTRAN/PATRAN. The validity of the finite element analysis (FEA) is demonstrated by comparing the experimental test results obtained due to mechanical loadings under the influence of thermal environment with those derived using the present FEA. Various parametric studies are also performed to investigate the effect of thermal loading on interlaminar stresses generated in symmetric, anti-symmetric, asymmetric, unidirectional, cross-ply, and balanced composite laminated beams of different stacking sequences with identical mechanical loadings and various boundary conditions. It is shown that the elevated thermal environment lead to higher interlaminar shear stresses varying with the stacking sequence, length to thickness ratio, ply orientations under identical mechanical loading and boundary conditions of the composite laminated beams. It is realized that the magnitude of the interlaminar stresses along xz plane is always much higher than those of along yz plane irrespective of the ply-orientation, length to thickness ratios and boundary conditions of the composite laminated beams. It is also observed that the effect of thermal environment on the interlaminar shear stresses in carbon-epoxy fiber reinforced composite laminated beams are increasing in the order of symmetric cross-ply laminate, unidirectional laminate, asymmetric cross-ply laminate and anti-symmetric laminate. The interlaminar shear stresses are higher in thinner composite laminated beams compared to that in thicker composite laminated beams under all environmental temperatures irrespective of the laminate stacking sequence, ply-orientation and boundary conditions.

Impact Behaviors of Ni-plated Carbon Fibers-reinforced Epoxy Matrix Composites (니켈도금된 탄소섬유 강화 에폭시 수지 복합재료의 충격 특성)

  • 박수진;김병주;이종문
    • Polymer(Korea)
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    • v.27 no.1
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    • pp.52-60
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    • 2003
  • In this work, two types of Ni-plating, namely electrolytical and electroless Ni-platings on carbon fiber surfaces, were carried out to enhance the impact resistance of composites. And the comparison between electrolytical and electroless methods on their impact properties of composite system was studied. The surface properties of carbon fibers were characterized using XRD, SEM, and contact angle measurements. The impact behaviors were investigated using an Izod type impact tester. As experimental results, it was observed that electrolessly plated Ni layers had Ni-P alloys on carbon fiber surfaces as revealed by XRD, and electrolytically Ni-plated carbon fibers showed higher surface free energies than those of the electrolessly Ni-plated carbon fibers. In particular, the impact strengths of electrolessly Ni-plated carbon fibers-reinforced plastics were strongly increased. These results were probably due to the difference of wettabilities according to the different types of Ni-plating methods.

Structural Behavior Evaluation of Mg-GFRP Composite Single-Lap Bonded Joints With Different End Shapes (한 끝단 형상에 따른 마그네슘 합금과 유리섬유 복합소재 단일겹치기 본드 조인트 거동 분석)

  • Kim, Jung-Seok;Im, Jae-Young;Lee, Woo-Geun
    • Journal of the Korean Society for Railway
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    • v.17 no.6
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    • pp.391-396
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    • 2014
  • In this study, the strength of magnesium-GFRP/epoxy single-lap bonded joints are experimentally evaluated with different end shapes. In order to achieve this, four different single-lap joints with different end shapes are fabricated and the failure load is measured under tensile loading tests. From the test results, the single-lap joint with a square end exhibits the lowest failure load while the single-lap joint with reverse tapering and a spew fillet has the highest stress values. It has 11.1% higher failure strength than the single-lap joint with a square end.

A comparison of surface hardness and microstructural characteristics between a type IV stone with and without die hardening treatment, and a polyurethane resin die material (IV형 경석고와 경화처리된 IV형 경석고 그리고 폴리우레탄 수지 치형재의 표면경도와 미세구조 특성의 비교)

  • Lee, Wan-Sun;Kim, Ji-Hwan;Kim, Tae-Suk;Kim, Nam-Sic;Yu, Chin-Ho
    • Journal of Technologic Dentistry
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    • v.34 no.3
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    • pp.227-235
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    • 2012
  • Purpose: This study compared the surface hardness (Vickers) and microstructural characteristics between a type IV stone with and without die hardening treatment, a polyurethane die material. Methods: Materials used were a type IV stone(MG Crystal Rock), two die hardeners (Hardening bath, Epox-it), and a polyurethane resin material(Polyluck). Six specimens per group were prepared according to manufacturer's directions. The prepared specimens were tested by means of hardness test, one-way ANOVA analysis, scanning electron microscopic(SEM) observations and energy dispersive spectroscopic(EDS) analysis. Results: In the hardness test and its statistical analysis, there was no significant difference in the surface hardness between a type IV stone and type IV stone with die hardener coating, type IV stone mixed with an epoxy like material instead of water. In contrast, polyurethane resin material exhibited significantly greater surface hardness than other specimen groups (p<0.05). Conclusion: By considering the results of the hardness test, SEM observations and EDS analysis, although the die hardeners on type IV stone did not show remarkable improvement in surface hardness, the die hardener coating on the surface of type IV stone material did show decrease of microporous and improvement of surface defects.

Effect of Heat Treatment Temperature and Coating Thickness on Conversion Lens for White LED (백색 LED용 색변환 렌즈의 열처리 온도 및 코팅 두께에 따른 영향)

  • Lee, Hyo-Sung;Hwang, Jong Hee;Lim, Tae-Young;Kim, Jin-Ho;Jung, Hyun-Suk;Lee, Mi Jai
    • Journal of the Korean Ceramic Society
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    • v.51 no.6
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    • pp.533-538
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    • 2014
  • Today, silicon and epoxy resin are used as materials of conversion lenses for white LEDs on the basis of their good bonding and transparency in LED packages. But these materials give rise to long-term performance problems such as reaction with water, yellowing transition, and shrinkage by heat. These problems are major factors underlying performance deterioration of LEDs. In this study, in order to address these problems, we fabricated a conversion lenses using glass, which has good chemical durability and is stable to heat. The fabricated conversion lenses were applied to a remote phosphor type. In this experiment, the conversion lens for white LED was coated on a glass substrate by a screen printing method using paste. The thickness of the coated conversion lens was controlled during 2 or 3 iterations of coating. The conversion lens fabricated under high heat treatment temperature and with a thin coating showed higher luminance efficiency and CCT closer to white light than fabricated lenses under low heat treatment temperature or a thick coating. The conversion lens with $32{\mu}m$ coating thickness showed the best optical properties: the measured values of the CCT, CRI, and luminance efficiency were 4468 K, 68, and 142.22 lm/w in 20 wt% glass frit, 80 wt% phosphor with sintering at $800^{\circ}C$.

A PHOTOELASTIC STRESS ANALYSIS ON THE SUPPOTING STRUCTURE IN THE MANDIBULAR DISTAL EXTENSION REMOVABLE PARTIAL DENTURE WITH VARIOUS DESINGS OF BACK-ACT10N CLASPS (하악 유리단 국소의치하에서 back-action 클래스프 설계 변화에 따른 광탄성 응력 분석)

  • Lim Soo-Lyoung;Kay Kee-Sung;Ko Yeong-Mu
    • The Journal of Korean Academy of Prosthodontics
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    • v.30 no.3
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    • pp.379-400
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    • 1992
  • The purpose of this study was to analyze the magnitude and distribution of stress using a photoelastic model from the mandibular distal extension removable partial dentures with the mesial or distal placement of the occlusal rest and the mesial or distal connection in the back-action clasp with the five various designs of the back-action clasp, that is, the mesial connection and the distal rest, the distal connection and mesial rest, the mesial connection and mesial rest, the distal connection and the mesial and distal rest, and the mesial connection, and the mesial and distal rest. A photoelastic model was made of the epoxy resin(PC-1) and the hardner(PLH-1) with the acrylic resin teeth used and was coated with the plastic cement-1 at the lingual surface of the model and then five kinds of the removable partial dentures on the photoelastic model were set. A unilateral vertical load of 12.5 kg was applied on the central fossa of the first molar with the use of specially designed loading device and the pattern and distribution of the stress of the photoelastic model under each condition was analyzed by the reflective circular polariscope. The following results were obtained. 1. In the back-action clasp with the mesial connection and mesial rest of the case 3, the effect of the stress distribution was the most favorable. 2. In the back-action clasp with the mesial and distal rest, of the case 4 and 5, the stress distribution was more greatly showed in the terminal abutment. 3. Generally, the stress distribution was more favarable in the mesial connection than in the distal connection. 4. In the back-action clasp with the mesial connection of the case 1, 3 and 5, the stress distribution was the most favorable in the mesial rest.

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The study on the properties of binary mixture(crystalline silica/AIN) filled EMC(Epoxy Molding Compounds) (결정성 실리카/질화 알루미늄 혼합충진에 따른 EMC의 물성 연구)

  • 김원호;홍용우;배종우;황영훈;김부웅
    • Journal of the Microelectronics and Packaging Society
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    • v.6 no.4
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    • pp.41-48
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    • 1999
  • Silica is the most popular materials as a filler of EMC for microelectronic packaging. However, because of its low thermal conductivity, the use of silica is restricted to parts requiring high thermal dissipation. The superior fluidity of EMC can be achieved with a combination of filler size distribution. In this study, physical properties of EMC filled with the crystalline silica(13$\mu\textrm{m}$) which have high fluidity and low cost and the AlN(2 $\mu\textrm{m}$) which have high thermal conductivity and low coefficient of thermal expansion were evaluated by changing the AlN/silica ratios. As a result of the evaluation of physical properties of EMC, the optimum mixing ratio of AlN/crystalline silica was 0.3/0.7. In this condition, binary mixture(AlN/crystalline silica) filled EMC showed superior properties, i.e., in the thermal conductivity, CTE, dielectric constant, flexural strength, and thermal shock resistance without reduction of fluidity.

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Study on the Reliability of COB Flip Chip Package using NCP (NCP 적용 COB 플립칩 패키지의 신뢰성 연구)

  • Lee, So-Jeong;Yoo, Se-Hoon;Lee, Chang-Woo;Lee, Ji-Hwan;Kim, Jun-Ki
    • Journal of the Microelectronics and Packaging Society
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    • v.16 no.3
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    • pp.25-29
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    • 2009
  • High temperature high humidity and thermal shock reliability tests were performed for the board level COB(chip-on-board) flip chip packages using self-formulated and commercial NCPs(non-conductive pastes) to ensure the performance of NCP flip chip packages. It was considered that the more smaller fused silica filler in prototype NCPs is more favorable for high temperature high humidity reliability. The failure of NCP interconnection was affected by the expansion of epoxy due to moisture absorption rather than the fatigue due to thermal stress. It was considered that the NCP having more higher adhesive strength seems to be more favorable to increase the thermal shock reliability.

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An Experimental Study on the Strength and Deformation of Reinforced Concrete Columns Strengthed with Epoxy-Bonded Steel Plate (강판접착으로 보강된 철근콘크리트 기둥의 내력 및 변형에 관한 실험적 연구)

  • Kim, Jin-Bai;Lee, Si-Woo;Jang, Hwa-Kyun;Cho, Chul-Ho
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.3 no.1
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    • pp.147-155
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    • 1999
  • The purpose of this study is to investigate the strength and ductility of reinforced concrete columns subject to axial load experimentally for several variables of reinforcements and propose foundational research date for reinforcement design of column. In the test a total of eleven specimens, which are all $20{\times}20{\times}60cm$ in size and differently reinforced with steel plate, has been used. The main variables of reinforcement considered in the test are the width of steel plate, the thickness of steel plate. Based on the test results, the effect of the main variables on the strength and ductility of reinforced concrete column have been scrutinized. The strength of reinforced concrete columns are that C-2 series on strengthed with 2mm thickness steel plate are smaller than C-4 series on strengthed with 4mm steel plate. Thick steel plate of reinforced expected utilizer than the other on strength increase and specimens to be large width steel plate of each system are the utiltzer on strength increase. Ductility of C-0 specimen is 1.60, C-2 series is 2.38, C-4 series 2.63 Compare efficiency of ductility increase with each specimens, in narrow width condition (2cm, 4cm) C-2 series is more efficiency, in wide width condition (8cm, 10cm) C-4 series is more efficiency.

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