• Elastomers and Composites
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• v.45 no.2
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• pp.100-105
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• 2010

An EPDM article was aged in air, distilled water, tap water, NaCl/$CaCl_2$ solution, and $CaCl_2/FeCl_3$ solution for 7 days. The aging temperature was $90^{\circ}C$. The samples aged in air and distilled water did not appear the whitening, those aged in tap water, NaCl/$CaCl_2$ solution, and $CaCl_2/FeCl_3$ solution showed the whitening. Soluble organic materials were analyzed using GC/MS to identify the whitening materials, surface morphology of the aged sample surface was examined using image analyzer and SEM, and elemental analysis of the materials accumulated on the sample surface was performed using EDX. Principal reason to cause whitening might be formation of metal salt of fatty acid by reaction between metal cation and fatty acid.

• Elastomers and Composites
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• v.44 no.3
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• pp.315-322
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• 2009

Influence of blend mode of extender oil on the properties of thermoplastic vulcanizates (TPVs), based on an ethylene-propylene-diene copolymer (EPDM) and a polypropylene (PP), was studied. The EPDM/PP TPVs were prepared in an open roll mill using two different modes in blending sequence of paraffinic oil and phenolic curative, i.e., Oil-Cure and Cure-Oil modes. Degree of cross-linking by gel fraction and properties such as hardness, tensile strength, elongation at break, and melt flow rate were investigated as a function of extender oil content for the two modes. Little influence of the blend mode of extender oil on the degree of cross-linking and mechanical behaviors was observed. However, the use of Cure-Oil mode in the preparation of EPDM/PP TPVs resulted in a marked increase in the level of processability as reflected by melt flow index, as compared to the use of Oil-Cure mode.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.31 no.9
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• pp.915-923
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• 2007

Rubber hoses for automobile radiators are apt to be degraded and thus failed due to the influence of contacting stresses of air and coolant liquid under thermal and mechanical loadings. The aging behaviors of the skin part of the hoses due to thermo-oxidative and electro-chemical stresses were experimentally analyzed. Through the thermo-oxidative aging test, it was shown that the surface hardness IRHD(International Rubber Hardness Degrees) of the rubber increased with a considerable reduction of failure strain as the aging time and temperature increased. On account of the penetration of coolant liquid into the skin part influenced by the electro-chemical degradation(ECD) test the weight of the rubber hose increased, whereas their failure strain and IRHD hardness decreased. The hardness of the hose in the side of the negative pole was the most deteriorated at the test site of the hose skin just below the coolant surface.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.1045-1047
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• 2017

In this study, we focused on development of the all-in-one case insulation for end-burning solid rocket motors. Material of insulation used unvulcanized rubber based on EPDM/kevlar. In case of boots insulation, preforms was made by using hot press molding, and then the tape was inserted between two preforms for all-in-one curing in the case. Finally bladder method was applied for curing of insulation.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2012.05a
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• pp.92-95
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• 2012

The dual pulse rocket motor is a pressure vessel containing two pulse grains separated by a pulse separation device such as a fragile bulkhead. One of the important things in this systems is case insulation design using the excellent materials in the 1st stage pulse motor. We investigated manufacturing process of fabric/EPDM chamber insulations in order to protect the 1st stage pulse motor case with high intensity gas flow. Simulation motor connected with extension tube having FRP disc was designed to study ablation characteristics of insulation.

• Transactions of Materials Processing
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• v.16 no.1 s.91
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• pp.31-35
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• 2007

Automotive weather strip should have good weather ability, sealability, durability, etc. to perform its duty as body sealing for vehicles under different harsh environments. Due to its comprehensive properties, thermoplastic vulcanizate(TPV) is widely employed in weather strip as alternative for ethylene propylene diene rubber(EPDM). In this study, the influences of the recycled TPV on the tensile strength and hardness were investigated. As results of the injection molding experiment, the recycled TPV's tensile strength and hardness were higher than the virgin TPV and recycled TPV's extension was improve. The morphology showed that recycled TPV's rubber particles became smaller than virgin TPV's rubber particles.

• Bulletin of the Korean Chemical Society
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• v.31 no.10
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• pp.2913-2917
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• 2010

When rubber dissolved in toluene was used as a binding material of graphite powder, the mechanical robustness of the carbon paste was guaranteed by the fast volatility of the solvent immediately after electrode construction. This characteristic of the rubber solution met qualifications for practical use of carbon paste electrodes and enabled the design of a new enzyme electrode bound with EPDM. In order to confirm whether the electrode shows quantitative electrochemical behaviors or not, its kinetic parameters, e. g. the symmetry factor (0.2), the exchange current density ($3.66\;{\mu}A/cm^2$), the capacity of the double layer ($2.0{\times}10^{-5}\;F$), the Michaelis constant ($4.39{\times}10^{-3}\;M$), the diffusion coefficient of substrate ($2.58{\times}10^{-12}\;cm^2/sec$), the time constant (0.018 sec) and other factors were investigated.

• Clean Technology
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• v.15 no.3
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• pp.172-179
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• 2009

The thermoplastic polyurethane waste (TPU-S) with good tensile properties, hardness, NBS abrasion resistance, specific gravity and low wet coefficient of kinetic friction was melt-blended with ethylene propylene diene monomer rubber (EPDM) with high wet slip resistance and low mechanical properties to form EPDM/TPU-S blend films, and their composition-property relationship was investigated to find the optimum composition for shoe outsole material. The properties except the wet slip resistance increased with increasing TPU-S contents in the blend. All the properties except elongation at break, specific gravity and the wet coefficient of kinetic friction in the range of $0{\sim}65\;wt%$ of TPU-S did not attain the values predicted by the simple additive rule. The optimum weight ratio of EPDM/TPU-S for the application to the typical shoe outsole material was found to be 30/70.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.33 no.2
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• pp.135-140
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• 2020

An experimental study was conducted using the tracking wheel test (IEC 62217) method for evaluating the performance of insulator materials, in particular ethylene propylene diene monomer (EPDM) and silicone rubber. In addition, we studied the tracking characteristics resulting from applying the same method for the shape of the insulator housing, that is, the performance of regular and alternating sheds. The evaluation parameters were leakage current, surface characteristics, SEM, EDX, hydrophobicity, and temperature distribution; likewise, we applied the commercial frequency dry (and wet) flashover voltage test. We found that the regular shed had a greater leakage current than the alternating shed and that the recovery of the hydrophobicity in terms of rest time was greater than that of the EPDM in terms of leakage current. All of the regular-shed insulators of silicone rubber had tracking traces and choking on the sheath parting line, while the alternating shed showed only choking at the interface but no tracking traces. Therefore, it can be concluded that the commercial frequency wet flashover voltage of the silicone rubber with regular shed before and after the tracking wheel test is higher than that of the alternating shed.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.11a
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• pp.193-198
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• 2010

In solid propellant rocket motors, $Al_2O_3$, one of combustion products, can be accumulated inside a combustion chamber. A special rocket motor was designed and tested to simulate thermal reaction of rubber insulator affected by the deposited slag. We successfully demonstrated through a dynamic radioscopy that the slag was deposited at the location as designed. In this paper we present a new test method which can simulate a high temperature and pressure environment in combustion chamber to evaluate material characteristics of rubber insulator and can provide design data to decide its thickness for a new solid rocket motor. The solid rocket motor, which has an average chamber pressure of 770 psia and a burning time of 50 seconds, was tested. The results show that erosion of EPDM insulator is more affected by a gas velocity rather than by the thermal reaction of slag with a high thermal capacity.