• Asian Journal of Atmospheric Environment
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• v.5 no.1
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• pp.29-40
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• 2011

In this study, the effects of an urban thermal environment on air quality were investigated using hourly surface weather observation data and air quality data over six summers from 2000 to 2005 in two cities on the Korean Peninsula. One, the city of Daegu, is representative of basin topography and the other, the city of Busan, represents a coastal area. It is known that the characteristics of an urban thermal environment are represented as an "urban heat island". Here, we focus on the nighttime urban thermal environment, which is called a "tropical night", during the summer. On tropical nights in Busan, the temperature and cloud cover levels were higher than on non-tropical nights. Wind speed did not appear to make a difference even on a tropical night. However, the frequency of southwestern winds from the sea was higher during tropical nights. The prevailing southwest winds in all areas meant an inflow of air from the sea. So at most of the air quality stations, the ozone concentration during tropical nights was lower than during non-tropical nights. In Daegu, the tropical nights had higher temperatures and cloud covers. Despite these higher temperatures, the ozone concentration during the tropical nights was lower than that on non-tropical nights at most of the air quality stations. This feature was caused by low irradiance, which in turn caused an increased cloud cover. Wind speed was stronger during the tropical nights and dispersed the air pollutants. These meteorological characteristics of the tropical nights reduced ozone concentrations in the Daegu Basin.

• Applied Chemistry for Engineering
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• v.17 no.3
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• pp.296-302
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• 2006

The kinetics of the thermal-oxidative decomposition of waste polyurethane (PU) according to oxygen concentration has been studied using a non-isothermal thermogravimetric technique at several heating rates from 10 to $50^{\circ}C/min$. A kinetic model accounting for the effects of the oxygen concentration by the differential and integral method based on Arrhenius equation was proposed to describe the thermal-oxidative decomposition of waste PU. To obtain the information on the kinetic parameters such as activation energy, reaction order, and pre-exponential factor, the thermogravimetric analysis curves and its derivatives have been analyzed using the kinetic analysis method proposed in this work. From this work, it was found that reaction orders for oxygen concentration had a negative sign, and activation energy decreased as the oxygen concentration increased. It was also found that the kinetic parameters obtained from the integral method using the single heating rate experiments varied with heating rates. Therefore, it is thought that the differential method using the multiple heating rate experiments more effectively represents the thermal-oxidative decomposition of waste polyurethane.

• Macromolecular Research
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• v.15 no.7
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• pp.676-681
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• 2007

A process designed to synthesize rigid polyurethane foam (PUF) with insulative properties via the modulation of PUF cell size via the addition of clay and the application of ultrasound was assessed. The blowing agents utilized in this study include water, cyclopentane, and HFC-365mfc, all of which are known to be environmentally-friendly blowing agents. The rigid PUFs were prepared from polymeric 4,4'-diphenylmethane diisocyanate (PMDI) and polyether polyol with a density of $50kg/m^3$. In addition, rigid PUFs/clay nanocomposites were synthesized with clay modified by PMDI with and without the application of ultrasound. The PUF generated using water as a blowing agent evidenced the highest tensile strength. The tensile strength of the PUF/nanocomposites was higher than that of the neat PUF and the strength was even higher with the application of ultrasound. The cell size of the PUF/clay nanocomposites was less than that of the neat PUF, regardless of the type of blowing agent utilized. It appears that the higher tensile strength and lower cell size of the PUF/clay nanocomposites may be attributable to the uniform dispersion of the clay via ultrasonic agitation. The thermal conductivity of the PUF/clay nanocomposites generated with HCFC-141b evidenced the lowest value when PUF/clay nanocomposites were compared with other blowing agents, including HFC-365mfc, cyclopentane, and water. Ultrasound has also proven effective with regard to the reduction of the thermal conductivity of the PUF/clay nanocomposites with any of the blowing agents employed in this study. It has also been suggested that the uniformly dispersed clay particles in the PUF matrix function as diffusion barriers, which prevent the amelioration of the thermal insulation property.

• Journal of the Korean Geotechnical Society
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• v.33 no.2
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• pp.35-47
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• 2017

Thermal behavior of soils is mainly focused on thermal conduction, and the study of natural convection is very limited. Increase of soil temperature causes natural convection due to buoyancy from density change of pore water. The limitations of the analysis using fluid dynamics for natural convection in the porous media is discussed and a new numerical analysis is presented for natural convection in porous media using THM governing equations fully coupled in the macroscopic view. Numerical experiments for thermal probe show increase in the uncertainty of thermal conductivity estimated without considering natural convection, and suggest appropriate experimental procedures to minimize errors between analytical model and numerical results. Burial of submarine power cable should not exceed the temperature changes of $2^{\circ}C$ at the depth of 0.2 m under the seabed, but numerical analysis for high permeable ground exceeds this criterion. Temperature and THM properties of the seafloor are important design factors for the burial of power cable, and in this case effects of natural convection should be considered. Especially, in the presence of heat sources in soils with high permeability, natural convection due to the variation of density of pore water should be considered as an important heat transfer mechanism.

• Smart Structures and Systems
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• v.20 no.3
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• pp.369-383
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• 2017

In this work, the effects of moisture and temperature on free vibration characteristics of functionally graded (FG) nanobeams resting on elastic foundation is studied by proposing a novel simple trigonometric shear deformation theory. The main advantage of this theory is that, in addition to including the shear deformation influence, the displacement field is modeled with only 2 unknowns as the case of the classical beam theory (CBT) and which is even less than the Timoshenko beam theory (TBT). Three types of environmental condition namely uniform, linear, and sinusoidal hygrothermal loading are studied. Material properties of FG beams are assumed to vary according to a power law distribution of the volume fraction of the constituents. Equations of motion are derived from Hamilton's principle. Numerical examples are presented to show the validity and accuracy of present shear deformation theories. The effects of hygro-thermal environments, power law index, nonlocality and elastic foundation on the free vibration responses of FG beams under hygro-thermal effect are investigated.

• Journal of Korean Society of Steel Construction
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• v.10 no.2 s.35
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• pp.201-209
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• 1998

The presence of elevated temperature can alter significantly the structural response of fibre-reinforced laminated composites. A thermal environment causes degradation in both strength and constitutive properties, particularly in the case of fibre-reinforced polymeric composites. Furthermore, associated thermal expansion, either alone or in combination with mechanically induced deformation, can result in buckling, large deflections, and excessively high stress levels. Consequently, it is often imperative to consider environmental effects in the analysis and design of laminated systems. Exact analytical solutions of higher-order shear deformation theory is developed to study the thermal buckling of cross-ply and antisymmetric angle-ply rectangular plates. The buckling behavior of moderately thick cross-ply and antisymmetric angle-ply laminates that are simply supported and subject to a uniform temperature rise is analyzed. Numerical results are presented for fiber-reinforced laminates and show the effects of ply orientation, number of layers, plate thickness, and aspects ratio on the critical buckling temperature and compared with those obtained using the classical and first-order shear deformation theory.

• Advances in nano research
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• v.7 no.4
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• pp.249-263
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• 2019

In the current paper, an exact solution method is carried out for analyzing the thermo-mechanical vibration of curved FG nano-beams subjected to uniform thermal environmental conditions, by considering porosity distribution via nonlocal strain gradient beam theory for the first time. Nonlocal strain gradient elasticity theory is adopted to consider the size effects in which the stress for not only the nonlocal stress field but also the strain gradients stress field is considered. It is perceived that during manufacturing of functionally graded materials (FGMs) porosities and micro-voids can be occurred inside the material. Material properties of curved porous FG nanobeam are assumed to be temperature-dependent and are supposed to vary through the thickness direction of beam which modeled via modified power-law rule. Since variation of pores along the thickness direction influences the mechanical and physical properties, porosity play a key role in the mechanical response of curved FG nano-structures. The governing equations and related boundary condition of curved porous FG nanobeam under temperature field are derived via the energy method based on Timoshenko beam theory. An analytical Navier solution procedure is utilized to achieve the natural frequencies of porous FG curved nanobeam supposed to thermal loading. The results for simpler states are confirmed with known data in the literature. The effects of various parameters such as nonlocality parameter, porosity volume fractions, thermal effect, gradient index, opening angle and aspect ratio on the natural frequency of curved FG porous nanobeam are successfully discussed. It is concluded that these parameters play key roles on the dynamic behavior of porous FG curved nanobeam. Presented numerical results can serve as benchmarks for future analyses of curve FG nanobeam with porosity phases.

• Journal of Environmental Health Sciences
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• v.36 no.2
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• pp.136-140
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• 2010

The integrated gasification combined cycle (IGCC) is one of the most promising proposed processes for advanced electric power generation that is likely to replace conventional coal combustion. This emerging technology will not only improve considerably the thermal efficiency but also reduce or eliminate the environmentally adverse effects normally associated with coal combustion. The IGCC process gasifies coal under reducing conditions with essentially all the sulfur existing in the form of hydrogen sulfide ($H_2S$) in the product fuel gas. The need to remove $H_2S$ from coal derived fuel gases is a significant concern which stems from stringent government regulations and also, from a technical point of view and a need to protect turbines from corrosion. The waste seashells were used for the removal of hydrogen sulfide from a hot gas stream. The sulphidation of waste seashells with $H_2S$ was studied in a thermogravimetric analyzer at temperature between $600^{\circ}C$ and $800^{\circ}C$. The desulfurization performance of the waste seashell sorbents was experimentally tested in a fixed bed reactor system. Sulfidation experiments performed under reaction conditions similar to those at the exit of a coal gasifier showed that preparation procedure and technique, the type and the amount of seashell, and the size of the seashell affects the $H_2S$ removal capacity of the sorbents. The pore structure of fresh and sulfided seashell sorbents was analyzed using mercury porosimetry, nitrogen adsorption, and scanning electronmicroscopy.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.2
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• pp.137-150
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• 2010

A meso-urban meteorological model (Urbanized MM5; uMM5) with urban canopy parameterization (UCP) was applied to the high-resolution simulation of meteorological fields in a complex coastal urban area and the assessment of urban impacts. Multi-scale simulations with the uMM5 in the innermost domain (1-km resolution) covering the Busan metropolitan region were performed during a typical sea breeze episode (4~8 August 2006) with detailed fine-resolution inputs (urban morphology, land-use/land-cover sub-grid distribution, and high-quality digital elevation model data sets). An additional simulation using the standard MM5 was also conducted to identify the effects of urban surface properties under urban meteorological conditions. Results showed that the uMM5 reproduced well the urban thermal and dynamic environment and captured well the observed feature of sea breeze. When comparison with simulations of the standard MM5, it was found that the uMM5 better reproduced urban impacts on temperature (especially at nighttime) and urban wind flows: roughness-induced deceleration and UHI (Urban Heat Island)-induced convergence.

• Journal of the Korean housing association
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• v.24 no.3
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• pp.45-53
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• 2013

It is important to secure green spaces to solve the urban heat island phenomenon, which is among problems resulted by high-density developments in metropolitan areas. However, it is hard to secure such green spaces in established urban areas so Green Rooftop development approaches have recently been highlighted and introduced as a solution to the situation. The present study conducts a simulation on residential areas in urbanized regions to quantitatively evaluate the effects of green rooftop developments through a comparison of changes in the air temperatures before and after relevant development projects. According to the evaluation results, when the green roof top development is conducted in the available areas, the temperature is reduced by 0.14 degree. The extension of green project to the entire building showed the reduction of the temperature by 0.29 degree. Based on these results, it can be concluded that the green rooftop development is a practically solution for reducing the air temperature of urbanized areas.