• Title/Summary/Keyword: entropy change

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Exergy Analysis of Refrigeration Cycle With Mixed Refrigerants Considering The Heat Exchange Process (열교환 과정을 고려한 혼합매체 냉동사이클의 엑서지 해석)

  • Jeong Sang Kwon;Ro Sung Tack
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.16 no.3
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    • pp.305-314
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    • 1987
  • Thermodynamic analysis of a mixed refrigerant refrigeration cycle has been performed by computing thermodynamic properties of various refrigerants. The analyses are carried cut to identify the sources and distribution of the energy degradation by irreversible processes. Heat exchange process with the surroundings produces the entropy and the irreversible loss can be reduced by the mixed refrigerant whose phase change temperature varies during the phase change processes in the evaporator and the condenser. The concept has been applied to find the minimum compression work and thus the minimum energy loss in the overall system, specifically in the case of the mixed refrigerant of R12 and R114. Parametric studies have been added to recognize the various factors affecting the system performance.

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Analysis of Change Detection Results by UNet++ Models According to the Characteristics of Loss Function (손실함수의 특성에 따른 UNet++ 모델에 의한 변화탐지 결과 분석)

  • Jeong, Mila;Choi, Hoseong;Choi, Jaewan
    • Korean Journal of Remote Sensing
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    • v.36 no.5_2
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    • pp.929-937
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    • 2020
  • In this manuscript, the UNet++ model, which is one of the representative deep learning techniques for semantic segmentation, was used to detect changes in temporal satellite images. To analyze the learning results according to various loss functions, we evaluated the change detection results using trained UNet++ models by binary cross entropy and the Jaccard coefficient. In addition, the learning results of the deep learning model were analyzed compared to existing pixel-based change detection algorithms by using WorldView-3 images. In the experiment, it was confirmed that the performance of the deep learning model could be determined depending on the characteristics of the loss function, but it showed better results compared to the existing techniques.

A Thermodynamic Investigation into the Stabilization of Poly(dA).[poly(dT)]2 Triple Helical DNA by Various Divalent Metal Ions

  • Choi, Byung-Hoon;Yeo, Ga-Young;Jung, Jin-Ah;Lee, Bae-Wook;Han, Sung-Wook;Cho, Tae-Sub
    • Bulletin of the Korean Chemical Society
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    • v.30 no.11
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    • pp.2691-2696
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    • 2009
  • Effects of representative group II and transition metal ions on the stability of the $poly(dA){\cdot}[poly(dT)]_2$ triplex were investigated by the van’t Hoff plot constructed from a thermal melting curve. The transition, $poly(dA){\cdot}[poly(dT)]_2\;{\rightarrow}\;poly(dA){\cdot}poly(dT)\;+\;poly(dT)$, was non-spontaneous with a positive Gibb’s free energy, endothermic (${\Delta}H^{\circ}$ > 0), and had a favorable entropy change (${\Delta}S^{\circ}$ > 0), as seen from the negative slope and positive y-intercept in the van’t Hoff plot. Therefore, the transition is driven by entropy change. The $Mg^{2+}$ ion was the most effective at stabilization of the triplex, with the effect decreasing in the order of $Mg^{2+}\;>\;Ca^{2+}\;>\;Sr^{2+}\;>\;Ba^{2+}$. A similar stabilization effect was found for the duplex to single strand transition: $poly(dA){\cdot}poly(dT)\;+\;poly(dT)\;→\;poly(dA)\;+\;2poly(dT)$, with a larger positive free energy. The transition metal ions, namely $Ni_{2+},\;Cu_{2+},\;and\;Zn_{2+}$, did not exhibit any effect on triplex stabilization, while showing little effect on duplex stabilization. The different effects on triplex stabilization between group II metal ions and the transition metal ions may be attributed to their difference in binding to DNA; transition metals are known to coordinate with DNA components, including phosphate groups, while group II metal ions conceivably bind DNA via electrostatic interactions. The $Cd_{2+}$ ion was an exception, effectively stabilizing the triplex and melting temperature of the third strand dissociation was higher than that observed in the presence of $Mg_{2+}$, even though it is in the same group with $Zn_{2+}$. The detailed behavior of the $Cd_{2+}$ ion is currently under investigation.

The Ecological View of Robert Smithson's Reclamation Project (로버트 스미슨의 "개간 프로젝트"에 나타나는 생태학적 세계관)

  • Lee, Jaeeun
    • The Journal of Art Theory & Practice
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    • no.15
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    • pp.7-30
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    • 2013
  • This is a study on the ecological view of Robert Smithson's reclamation projects. Smithson was a pioneer of Earth art in the late 1960's. Robert Smithson believed that he could transform industrial wastelands, such as an abandoned oil rig and a no longer used quarry, into "Earth Art." In the early seventies, he conceived of land reclamation as a new art form and called this art "Reclamation Projects." His attention regarding industrial ruin started from the American political and social situations in the 1960's. In the late 1960's, American society was in chaos from the right of movement of African Americans, the women's rights movement and from the strike for renunciation of the Vietnam War. The intellectual class seemed to believe that it was the destiny of a closed system's society to run in the direction of entropy. Smithson, who was skeptical about the system of American society, also thought that entropy was the proper diagnosis to describe America's situation in the 1960's. The 1960's civic movements like the civil rights movement and antiwar movements expanded into the environmental movements based on ecological views of the 1970's. The government had also started to worry about environmental pollution. Thus, the reclamation act was also established in 1972. Smithson believed that the relation between art and social background are closely related and affect each other. He was concerned with how art can join society, and the result was reclamation projects. Such reclamation projects lie on man-made wastelands, like abandoned oil rigs and no longer used quarries, which was an allegory of entropy. He also thought that Frederick Law Olmsted was a pioneer of earth art. The aesthetic category of Olmsted's view of landscape is to be based on the picturesque of Uvedale Price and William Gilpin. So Smithson, who considered Olmsted as his touchstone, also accepted the picturesque. Such reclamation projects aim to change with nature by adapting the creative power of artists to the ruin which has the highest level of entropy in industrial society. Smithson wanted this to become the bridge between man and nature. His reclamation project's aim, which shows the system interacting between man and nature as a network, is not different from the ecological view of the 1970's environmental movement.

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Comparison of Sampling Techniques for Passive Internet Measurement: An Inspection using An Empirical Study (수동적 인터넷 측정을 위한 샘플링 기법 비교: 사례 연구를 통한 검증)

  • Kim, Jung-Hyun;Won, You-Jip;Ahn, Soo-Han
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.45 no.6
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    • pp.34-51
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    • 2008
  • Today, the Internet is a part of our life. For that reason, we regard revealing characteristics of Internet traffic as an important research theme. However, Internet traffic cannot be easily manipulated because it usually occupy huge capacity. This problem is a serious obstacle to analyze Internet traffic. Many researchers use various sampling techniques to reduce capacity of Internet traffic. In this paper, we compare several famous sampling techniques, and propose efficient sampling scheme. We chose some sampling techniques such as Systematic Sampling, Simple Random Sampling and Stratified Sampling with some sampling intensities such as 1/10, 1/100 and 1/1000. Our observation focused on Traffic Volume, Entropy Analysis and Packet Size Analysis. Both the simple random sampling and the count-based systematic sampling is proper to general case. On the other hand, time-based systematic sampling exhibits relatively bad results. The stratified sampling on Transport Layer Protocols, e.g.. TCP, UDP and so on, shows superior results. Our analysis results suggest that efficient sampling techniques satisfactorily maintain variation of traffic stream according to time change. The entropy analysis endures various sampling techniques well and fits detecting anomalous traffic. We found that a traffic volume diminishment caused by bottleneck could induce wrong results on the entropy analysis. We discovered that Packet Size Distribution perfectly tolerate any packet sampling techniques and intensities.

The Applicability of Minimum Entropy Deconvolution Considering Spatial Distribution of Sampling Points (지하수 함양량 추정시 공간상에서의 자료 Sampling 방법에 따른 Minimum Entropy Deconvolution의 적용성에 관한 검토)

  • Kim Tae-Hee;Kim Yong-Je;Lee Kang-Keun
    • Journal of Soil and Groundwater Environment
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    • v.11 no.3
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    • pp.52-58
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    • 2006
  • Kim and Lee (2005) suggested Minimum Entropy Deconvolution (MED) to estimate the temporal sequence of the relative recharge. However this study by Kim and Lee (2005) was just related to the verification of the conceptual approach with MED. In this study, we try to characterize the applicability of MED in the case of spatially heterogeneous recharge (distance from recharge area). Simulated results were recorded with some specific sampling points. Estimated results from this study show higher than 0.8 in cross-correlation with the original recharge sequence. In addition, the physical and mathematical meanings of the applied filter length was also investigated. It was revealed that the length of filter is highly related to the spatial distance between recharge area and the monitoring site, and the apparent shape of hydraulic head change.

Potential impact of climate change on the species richness of subalpine plant species in the mountain national parks of South Korea

  • Adhikari, Pradeep;Shin, Man-Seok;Jeon, Ja-Young;Kim, Hyun Woo;Hong, Seungbum;Seo, Changwan
    • Journal of Ecology and Environment
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    • v.42 no.4
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    • pp.298-307
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    • 2018
  • Background: Subalpine ecosystems at high altitudes and latitudes are particularly sensitive to climate change. In South Korea, the prediction of the species richness of subalpine plant species under future climate change is not well studied. Thus, this study aims to assess the potential impact of climate change on species richness of subalpine plant species (14 species) in the 17 mountain national parks (MNPs) of South Korea under climate change scenarios' representative concentration pathways (RCP) 4.5 and RCP 8.5 using maximum entropy (MaxEnt) and Migclim for the years 2050 and 2070. Results: Altogether, 723 species occurrence points of 14 species and six selected variables were used in modeling. The models developed for all species showed excellent performance (AUC > 0.89 and TSS > 0.70). The results predicted a significant loss of species richness in all MNPs. Under RCP 4.5, the range of reduction was predicted to be 15.38-94.02% by 2050 and 21.42-96.64% by 2070. Similarly, under RCP 8.5, it will decline 15.38-97.9% by 2050 and 23.07-100% by 2070. The reduction was relatively high in the MNPs located in the central regions (Songnisan and Gyeryongsan), eastern region (Juwangsan), and southern regions (Mudeungsan, Wolchulsan, Hallasan, and Jirisan) compared to the northern and northeastern regions (Odaesan, Seoraksan, Chiaksan, and Taebaeksan). Conclusions: This result indicates that the MNPs at low altitudes and latitudes have a large effect on the climate change in subalpine plant species. This study suggested that subalpine species are highly threatened due to climate change and that immediate actions are required to conserve subalpine species and to minimize the effect of climate change.

Study on Equilibrium, Kinetic and Thermodynamic for Adsorption of Quinoline Yellow by Granular Activated Carbon (입상 활성탄에 의한 Quinoline Yellow의 흡착에 대한 평형, 동력학 및 열역학에 관한 연구)

  • Lee, Jong-Jib
    • Clean Technology
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    • v.20 no.1
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    • pp.35-41
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    • 2014
  • Batch adsorption studies were carried out for equilibrium, kinetic and thermodynamic parameters for quinoline yellow adsorption by granular activated carbon ($8{\times}30mesh$, $1,578m^2/g$) with varying the operating variables like initial concentration, contact time and temperature. Equilibrium adsorption data were fitted into Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms. From estimated Langmuir constant ($R_L=0.0730{\sim}0.0854$), Freundlich constant (1/n = 0.2077~0.2268), this process could be employed as effective treatment for removal of quinoline yellow. From calculated Temkin constant (B = 15.759~21.014 J/mol) and Dubinin-Radushkevich constant (E = 1.0508~1.1514 kJ/mol), this adsorption process is physical adsorption. From kinetic experiments, the adsorption process were found to confirm to the pseudo second order model with $r^2$ > 0.99 for all concentrations and temperatures. Thermodynamic parameters like activation energy, change of free energy, enthalpy, and entropy were also calculated to predict the nature adsorption. The activation energy value (+35.137 kJ/mol) and enthalpy change (35.03 kJ/mol) indicated endothermic nature of the adsorption process. Entropy change (+134.38 J/mol K) showed that increasing disorder in process. Free energy change found that the spontaneity of process increased with increasing adsorption temperature.

Projection of climate change effects on the potential distribution of Abeliophyllum distichum in Korea (기후변화에 따른 우리나라 미선나무의 분포변화 예측)

  • Lee, Sang-Hyuk;Choi, Jae-Yong;Lee, You-Mi
    • Korean Journal of Agricultural Science
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    • v.38 no.2
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    • pp.219-225
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    • 2011
  • Changes in biota, species distribution range shift and catastrophic climate influence due to recent global warming have been observed during the last century. Since global warming affects various sectors, such as agriculture and vegetation, it is important to predict more accurate impact of future climate change. The purpose of this study is to examine the observed distribution of Abeliophyllum distichum in the Korean peninsula. For this purpose, two period (present and future) climate data were used. Mean data between 1950 and 2000, were used as the present value and the year 2050 and 2080 data from A1B senario in IPCC SRES were used for the future value. Potential habitation is analyzed by MaxEnt(Maximum Entropy model), and Abeliophyllum distichum's coordinates data were used as a dependent variable and independent variables are composed of environmental data such as BioClim, altitude, aspect and slope. The result of six types GCM mean calculation, the potential habitability decreased by 40-60% of the average existing distribution. The methodogies and results of this research can be applicable to the climate changing adaptation stratiegies for the biodiversity conservation.

Spatial Planning of Climate Adaptation Zone to Promote Climate Change Adaptation for Endangered Species (생물다양성 보전을 위한 기후적응지역 설정 연구 -삵의 서식지를 중심으로-)

  • Lee, Dongkun;Baek, Gyounghye;Park, Chan;Kim, Hogul
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.14 no.6
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    • pp.111-117
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    • 2011
  • This study attempts to facilitate climate change adaptation in conservation area by spatial planning of climate adaptation zone for endangered species. Spatial area is South Korea and select leopard cat (Prionailurus bengalensis) as a target species of this study. In order to specify the climate adaptation zone, firstly, Maximum entropy method (Maxent) was used to identify suitable habitat, and then core habitat was selected for leopard cat. Secondly, land use resistance index was evaluated and least cost distance was analyzed for target species. In this step we choose dispersal capacity of leopard cat to reflect species ecological characteristic. Finally, climate adaptation zone is described and adaptation measures are suggested. The presented approach could be generalized for application into conservation planning and restoration process. Furthermore, spatial planning of climate adaptation zone could increase heterogeneity of habitat and improve adaptive capacity of species and habitat itself.