• 한국수소및신에너지학회논문집
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• 제25권6호
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• pp.594-601
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• 2014

Rare-earth (RE) nitrides can be used as magnetocaloric materials in low temperature. They exhibit ferromagnetism and have Curie temperature in the region from 6 to 70 K. In this study, Holmium nitride (HoN) nano particles were prepared through plasma arc discharge technique and their magnetocaloric properties were studied. Nitrogen gas ($N_2$) was employed as an active element for arc discharge between two electrodes maintained at a constant current. Also, it played an important role not only as a reducing agent but also as an inevitable source of excited nitrogen molecules and nitrogen ions for the formation of HoN phase. Partial pressure of $N_2$ was systematically varied from 0 to 28,000 Pa in order to obtain single phase of HoN with minimal impurities. Magnetic entropy change (${\Delta}S_m$) was calculated with data set measured by PPMS (Physical Property Measurement System). The as-synthesized HoN particles have shown a magnetic entropy change ${\Delta}S_m$) of 27.5 J/kgK in applied field of 50,000 Oe at 14.2 K thereby demonstrating its ability to be applied as an effective magnetic refrigerant towards the re-liquefaction of hydrogen.

• 한국수자원학회논문집
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• 제51권9호
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• pp.761-768
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• 2018

기후변화와 기후변화 외적인 요인으로 인해 지하수자원은 고갈되어가고 있다. 지하수자원의 효율적인 관리를 위해 유역 단위의 지하수자원 관리 취약시기 평가 방법을 개발하였다. 유역 단위의 취약시기 평가는 취약 지역 평가와 소유역에 대한 취약시기 평가를 독립적으로 진행하여 각각의 지수를 산정하였다. 취약 지역 평가 지수를 표준화하여 독립적으로 진행한 취약시기 평가 지수에 적용하여 유역 단위의 취약시기 평가 방법을 개발하였으며, 개발한 방법을 낙동강 상류 지역인 봉화군, 안동시, 예천군, 문경시, 상주시에 적용하였다. 그 결과 상주의 8월이 0.278로 가장 취약한 것으로 나타났으며, 안동시는 1년 중 8개월간 5개 지역 중 지하수자원 관리에 취약한 것으로 나타났다. 개발된 방법을 이용하여 지하수자원의 시공간을 고려한 효율적인 관리방안을 모색할 수 있을 것이다.

• 한국인쇄학회지
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• 제14권1호
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• pp.115-131
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• 1996

The PVT(pressure-volume-temperature) relation of main-chain dimer liquid crystals having structures such as $\alpha$,$\omega$-bis[(4,4`-cyanobiphenyl) oxy] alkane(CBA-n with=9, 10) were studied. these dimer liquid crystals are known to form an enantiotropic nematic mesophase. In this work, we have determined the volume change as a function of temperature and pressure by using a GNOMIX PVT apparatus. In the V-Tcurves obtaind from isobaris mearements on various pressures, volume changes were observed at the nematic-isotropiz and nematic-crystal phase transitions. The volume changes at the transition exhibit slight odd-even effect with respect to the number of methylene unit n. The values of the (S)v obtained at the NI transition for CBA-9 and -10 were 6.9 and 12.6J/mol k. The valuesof (S)v for the CN transition were estimated on the basis of DSC(differential scanning calorimetry) data: 58.8(CBA-9) and 65.3J/mol k (CBA-10). For both transition, it was found that the correction about the volume change is significant, ranging from 40% to 60% of the total transition entropy observed under constant pressure.

• 한국세라믹학회지
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• 제24권6호
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• pp.593-601
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• 1987

A thermodynamic model to predict the stability of the water-in-oil type emulsion and the size of the droplets in stable emulsions was developed. Using this model, the effects of various factors government the droplet size in the metal salt solution-kerosene-span 80 system for the preparation of Al2O3-ZrO2 composite powders were investigated. It was shown that the given emulsion systems were thermodynamically unstable in every case but could be kinetically meta stable. When radius ofthe droplet was below nm, the increase in entropy change due to the configurational contribution of small droplets dominated the total free energy change for emulsification. The optimum conditions under which smaller deoplet was obtained were proposed and the validity of the model was proved with diameters of the droplet and composite powders experimentally determined.

• 한국세라믹학회지
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• 제28권2호
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• pp.109-118
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• 1991

Steady-state sublimation vapour pressures of anhydrous bismuth triiodide have been measured by the torsion-effusion method from 488.8 to 570.5 K and equilibrium sublimation pressures were obtained from the steady-state data. The standard sublimation enthalpy changes derived by both second(modified sigma function) and third(average enthalpy method) law methods were 159.316${\pm}$0.055, 137.67${\pm}$1.43 kJ$.$mol-1 respectively. The standard sublmation entropy change derived by modified sigma function was 232.88${\pm}$0.10 J$.$K-1$.$mol-1. The reliable standard sublimation enthalpy change based on a correlation of {{{{ { TRIANGLE }`_{cr } ^{g } }} H{{{{ { 0} atop {m } }}(298.15K) and {{{{ { TRIANGLE }`_{cr } ^{g } }} S{{{{ { 0} atop {m } }}(298.15K), a recommended p(T) equation has been obtained for BiI3(cr) ; lg(p/Pa)=-(C$.$K/T)+5.071lg(T/K)-2.838${\times}$10-3(T/K)-7.758${\times}$103(K/T)2+1.4519 where C={{{{{ { TRIANGLE }`_{cr } ^{g } }} H{{{{ { 0} atop {m } }}(298.15K)/0.019146 kJ$.$mol-1}-456.27.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2003년도 하계학술연구발표회 및 한.일 공동심포지엄
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• pp.140-141
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• 2003

Recently, a large magneto-caloric effect (MCE) in perovskite materials has generated growing interests among scientists and manufacturers, because of its assessable and practical potential for the field of magnetic refrigeration. Nevertheless, further efforts of seeking a proper material that has a large magnetic-entropy change (ΔS$\sub$M/) or a large adiabatic temperature change (ΔT$\sub$ad/), i.e. a large MCE, in a vast variety of temperatures have been extensively devoted, but no theoretical treatments are satisfactorily made.

• 설비공학논문집
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• 제16권4호
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• pp.383-389
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• 2004

Magnetic refrigeration is based on the magnetocaloric effect (MCE) - the ability of some materials to heat up when magnetized and cool down when removed from the magnetic field. The available techniques for studying the MCE we: (1) direct measurements by monitoring the change in the material's temperature during the application or removal of the magnetic field; and (2) indirect calculations from the experimental data of magnetization and/or specific heat as a function of the temperature and magnetic field. The MCE of gadolinium (Gd) has been demonstrated by direct measurements of temperature change, and isothermal magnetic entropy changes and adiabatic temperature changes have been calculated.

• Journal of Photoscience
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• 제12권3호
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• pp.113-117
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• 2005

Spectroscopic investigations on the interaction of gabapentin (GBP) with bovine serum albumin (BSA) were reported. The association constant of GBP-BSA system was determined at different temperatures (298, 302, 306 and 311 K) based on the fluorescence quenching results. The GBP was found to quench the fluorescence of BSA through static mechanism. Thermodynamic parameters, the standard enthalpy change, $({\Delta}H^o)$ and the standard entropy change $({\Delta}S^o)$ were observed to be $-9.61{\pm}0.008\;kJ\;mol^{-1}$ and $3.58{\pm}0.011\;Jmol^{-1}K{-1}$ respectively. These indicated that the hydrophobic and electrostatic forces played a role in the interaction of GBP with BSA. The negative value of ${\Delta}G^o$ revealed that the binding reaction is spontaneous. The circular dichroism studies indicated the conformational changes in BSA upon interaction with GBP. The effect of some metal ions on the binding constant was also investigated.

• 한국염색가공학회지
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• 제14권2호
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• pp.85-85
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• 2002

The interaction between berberine and tannin in aqueous solution was investigated spectrophotometerically. The dyeing mechanism of silk fabrics (control and tannin treated silk fabrics) with berberine was based on thermodynamic parameters obtained from equilibrium adsorption experiments. In adsorption spectra of aqueous solution of berberine and tannin mixture two isosbestic points (328nm, 357nm) were found and the mole fraction of reaction of components was 1:1. Initial dyeing rates were increased and the diffusion of dye was more effective by tannin treatment. Without regard to tannin treatment the adsorption isotherm of berberine was the langmuir type except high temperature, 80℃. By tannin treatment the saturation dye uptake was increased, the increase of dye uptake appeared to be a result of entropy change rather than enthalpy change. All these results can be interpreted by the hydrophobic interaction between berberine and silk treated with tannin and it is reasonable to conclude that not only the ionic force, but also the hydrophobic interaction contributes to the binding of berberine and tannin treated silk treated with tannin.

• 한국염색가공학회지
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• 제14권2호
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• pp.9-17
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• 2002

The interaction between berberine and tannin in aqueous solution was investigated spectrophotometerically. The dyeing mechanism of silk fabrics (control and tannin treated silk fabrics) with berberine was based on thermodynamic parameters obtained from equilibrium adsorption experiments. In adsorption spectra of aqueous solution of berberine and tannin mixture two isosbestic points (328nm, 357nm) were found and the mole fraction of reaction of components was 1:1. Initial dyeing rates were increased and the diffusion of dye was more effective by tannin treatment. Without regard to tannin treatment the adsorption isotherm of berberine was the langmuir type except high temperature, $80^\circ{C}$. By tannin treatment the saturation dye uptake was increased, the increase of dye uptake appeared to be a result of entropy change rather than enthalpy change. All these results can be interpreted by the hydrophobic interaction between berberine and silk treated with tannin and it is reasonable to conclude that not only the ionic force, but also the hydrophobic interaction contributes to the binding of berberine and tannin treated silk treated with tannin.