• Journal of Korean Society for Atmospheric Environment
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• v.15 no.5
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• pp.667-676
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• 1999

The roles of ceria on three-way catalyst is to improve the noble metal dispersion and thermal stability of support ${\gamma}$-$Al_2O_3$. And, ceria has a oxygen storage capacity(OSC) under fuel rich/lean conditions to improve the operating windows of NOx, THC and CO conversion. However, ceria has weak thermal stability under high temperature due to the crystallite growth. So that, the OSC of ceria is decreased, and then the conversions of NOx, THC and CO is decreased. One way of enhancing the thermal stability and NOx, THC and CO conversion Pd-only catalyst is to improve as well as its thermal stability and oxygen storage capacity of the ceria. Especially, the appropriate mixing ratios of bulk and stabilized ceria are very important for designing principles of Pd-only three-way catalysts. In this paper, we discussed the thermal properties of stabilizedand unstabilized (bulk) ceria, and the oxygen storage capacity (OSC) of catalysts, and found the correlation between activity and the OSC of Pd-only catalysts with various different mixing ratios of bulk and stabilized ceria. Finally, we propose the design principles to improve the thermal stability of washcoated Pd-only catalysts.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.26 no.1
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• pp.199-212
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• 2000

A series of novel ascorbic acid derivatives, polyethoxylated ascorbic acid (PEAA) were synthesized by coupling ascorbic acid with polyethylene glycol (PEG) of two molecular weights (MW: 350 and 550) at the C-2 or C-3 hydroxyl group (2PEAA350, 3PEAA350, 2PEAA550, 3PEAA550) to increase the stability and retain the activity, as a skin whitening agent. Their stability, scavenging activity against free radical, inhibitory activity against tyroxinase and inhibitory activity of melanin synthesis in Bl6 melanoma cell of PEAAs were evaluated in viかo and compared with those of ascorbic acid and 3-O-ethyl ascorbic acid (3OEAA), a Con stable vitamin C derivative. Among PEAAs, 2PEAA350 and 2PEAA550 tad high scaveniging activity against See radical, inhibitory activity against tyrosinase and inhibitory activity if melanogenesis but low stability, 3PEAA350 had high stability and moderate scavenging activity against free radical, infibitory activity against tyrosinase and inhibitory activity of melanogenesis. The stability, scavenging activity against free radical and inhibitory activity of melanogenesis of 3PEAA350 were higher than those of 30EAA. The most stable 3PEAA350 among PEAAs was nontoxic in various toxicological tests. These results suggest that PEAA would be a good whitening agent far enhancing stability and bioavailability.

• Geomechanics and Engineering
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• v.31 no.1
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• pp.71-86
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• 2022

In Taiwan, an efficient approach for enhancing the stability of colluvium slopes is the drilled shaft method. For slopes with drilled shafts, the soil arching effect is one of the primary factors influencing slope stability and intertwines to the failure mechanism of the pile-soil system. In this study, the contribution of soil arching effect to slope stability is evaluated using the FEM software (Plaxis 3D) with the built-in strength reduction technique. The result indicates the depth of the failure surface is influenced by the S/D ratio (the distance to the diameter of piles), which can reflect the contribution of the soil arching effect to soil stability. When α (rock inclination angles)=β (slope angles) is considered and the S/D ratio=4, the failure surface of the slope is not significantly influenced by the piles. Overall, the soil arching effect is more significant on α=β, especially for the steep slopes. Additionally, the soil arching effect has been included in the proposed stability charts. The proposed charts were validated through two case studies, including that of the well-known Woo-Wan-Chai field in Taiwan. The differences in safety factor (FoS) values between the referenced literature and this study was approximately 4.9%.

• KDI Journal of Economic Policy
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• v.38 no.3
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• pp.53-77
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• 2016

Financial soundness in the household sector matters for financial stability and for the real economy. The level of household debt in Korea raises concern about the financial soundness of the household sector due to its size, growth rate and quality. Against this backdrop, we assess the financial vulnerability of borrowers based on an analysis of credit bureau (CB) data, in which the actual credit activities of most individuals are recorded at a high frequency in Korea. We construct over-indebtedness indicators from the CB data and then assess the predictability of forthcoming defaults. Based on the over-indebtedness indicators, we show how borrowers are distributed in terms of over-indebtedness and how the over-indebted differ from average borrowers in terms of their characteristics. Furthermore, we show how the aggregate credit risk in the household sector would change under macroeconomic distress by analyzing how each borrower's credit quality would be affected by adverse shocks. The findings of this paper may contribute to assessing household debt vulnerability and to enhancing regulatory and supervisory practices for financial stability.

• Proceedings of the KIEE Conference
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• 2002.07a
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• pp.90-92
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• 2002

The SVC(Static Var Compensator) resulted from the FACTS technology can generate or absorb reactive power rapidly so as to increase the transient and voltage stability. In this paper, the SVC is applied to the power system in order to improve the total transfer capability from a viewpoint of static voltage stability and the effects of application of the SVC to the power system are analyzed. The IPLAN, which is a high level language used with PSS/E program, is employed for determining the total transfer capability.

• Journal of Electrochemical Science and Technology
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• v.7 no.3
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• pp.199-205
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• 2016

We present the electrochemical performance of electric double layer capacitors (EDLCs) assembled with pyrrolidinium (Pyr)-based ionic liquid electrolytes at 55 ℃. Cations with various alkyl chain lengths were employed in Pyr-based ionic liquids to investigate the effect of cation structure on the cycling stability of EDLCs. The EDLCs exhibited initial specific capacitances ranging from 122.4 to 131.6 F g⁻¹ based on activated carbon material at 55 ℃. Cycling data and XPS results demonstrate that Pyr-based ionic liquid with longer alkyl chain is more effective for enhancing the cycling stability of EDLC by suppressing the reductive decomposition of pyrrolidinium cations during cycling at high temperatures.

• Journal of the Korean institute of surface engineering
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• v.37 no.1
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• pp.64-70
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• 2004

Cryogenic characteristics of austenitic stainless steel based on 304 steel with nickel and nitrogen were investigated at room temperature and $-196^{\circ}C$. The alloys were fabricated by vacuum arc furnace and cold working after homogenization treatment. The addition of nickel and nitrogen decreased the stability of $\delta$-ferrite and induced the stability against the formation of martensite to result significantly in enhancing ductility at $-196^{\circ}C$. Nitrogen reduced Md temperature, which was beneficial to the tensile strength and elongation at $25^{\circ}C$ and -196$^{\circ}C$.

• Steel and Composite Structures
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• v.50 no.4
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• pp.459-474
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• 2024

Classical and first-order nonlocal beam theory are employed in this study to assess the thermal buckling performance of a small-scale conical, cylindrical beam. The beam is constructed from functionally graded (FG) porosity-dependent material and operates under the thermal conditions of the environment. Imperfections within the non-uniform beam vary along both the radius and length direction, with continuous changes in thickness throughout its length. The resulting structure is functionally graded in both radial and axial directions, forming a bi-directional configuration. Utilizing the energy method, governing equations are derived to analyze the thermal stability and buckling characteristics of a nanobeam across different beam theories. Subsequently, the extracted partial differential equations (PDE) are numerically solved using the generalized differential quadratic method (GDQM), providing a comprehensive exploration of the thermal behavior of the system. The detailed discussion of the produced results is based on various applied effective parameters, with a focus on the potential application of nanotubes in enhancing sports bikes performance.

• Journal of the Korean Society of Marine Environment & Safety
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• v.23 no.3
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• pp.301-312
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• 2017

CE RCD (Recreational Craft Directive) is a certification for the design and construction of small vessels, including pleasure yachts, which are widely used not only in the countries within the European Union, but also in Japan and Southeast Asia. Recently, South Korean leisure craft shipyards have developed interest in exporting to foreign leisure craft markets such as Europe; however, they have encountered difficulties because of the CE RCD regulations, which are relatively complex and difficult to understand. The requirements for buoyancy and stability, which are essential properties that must be understood within the early stage of ship design, are defined based on ISO 12217. However, preparing this assessment according to ship classification regulations is an exceedingly complex task, even with knowledge of naval architecture. In this research, we have developed design support tools to systematically support assessments and preemptively define design information so that buoyancy and stability assessments based on ISO 12217 can be systematically prepared. Our research results were applied to actual examples of yacht design to confirm validity. We believe that the improved yacht design process presented in this research can act as a foundational reference for enhancing the effectiveness and systematic buoyancy and stability assessments.

• Journal of Pharmaceutical Investigation
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• v.29 no.4
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• pp.337-341
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• 1999

We have studied the stability and transdennal flux of prostaglandin $E_1\;(PGE_1)$ from various donor solutions through hairless mouse skin. Stability in HEPES buffer or in propylene glycol (PG) solution where enhancer (oleic acid (OA), propylene glycol monolaurate (PGML), transcutol (TC), ethanol (EtOH))s dissolved was investigated. $$PGE_1 was not stable in HEPES buffer. The concentration of $$PGE_1 decreased continuously for 7 days, and the degradation rate constant was $0.0028\;h^{-1}$, assuming first order reaction. The effect of current or penetration enhancer on the degradation was minimal. Percutaneous transport from HEPES buffer by passive or iontophoretic delivery without enhancer was close to nil. When OA or PGML was used together with PG, both passive and iontophoretic flux increased. PGML showed better enhancing effect than OA. Flux by cathodal delivery was about 2 times larger than that by passive delivery. Flux by anodal delivery was lower than that by passive delivery. TC and EtOH also increased the transdermal flux, but the effect was not as good as that observed when OA or PGML was used. These stability and flux data provide important information on how to formulate the patch, which will be the next step of this work, and on the polarity of current to use during iontophoresis.