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Synthesis of Nitrogen-Doped Porous Carbon Fibers Derived from Coffee Waste and Their Electrochemical Application (커피 폐기물 기반의 질소가 포함된 다공성 탄소 섬유의 제조 및 전기화학적 응용)

  • Dong Hyun Kim;Min Sang Kim;Suk Jekal;Jiwon Kim;Ha-Yeong Kim;Yeon-Ryong Chu;Chan-Gyo Kim;Hyung Sub Sim;Chang-Min Yoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.31 no.1
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    • pp.57-68
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    • 2023
  • In this study, coffee waste was recycled into nitrogen-doped porous carbon fibers as an active material for high-energy EDLC (Electric Double Layer Capacitors). The coffee waste was mixed with polyvinylpyrrolidone and dissolved into dimethylformamide. The mixture was then electrospun to fabricate coffee waste-derived nanofibers (Bare-CWNF), and carbonization process was followed under a nitrogen atmosphere at 900℃. Similar to Bare-CWNF, the as-synthesized carbonized coffee waste-derived nanofibers (Carbonized-CWNF) maintained its fibrous form while preserving the composition of nitrogen. The electrochemical performance was analyzed for carbonized coffee waste (Carbonized-CW)-, carbonized PAN-derived nanofibers (Carbonized-PNF)-, and Carbonized-CWNF-based electrodes in the operating voltage window of -1.0-0.0V, Among the electrodes, Carbonized-CWNF-based electrodes exhibited the highest specific capacitance of 123.8F g-1 at 1A g-1 owing to presence of nitrogen and porous structure. As a result, nitrogen-contained porous carbon fibers synthesized from coffee waste showed excellent electrochemical performance as electrodes for high-energy EDLC. The experimental designed in this study successfully demonstrated the recycling of the coffee waste, one of the plant-based biomass that causes the environmental pollution into high-energy materials, also, attaining the ecofriendliness.

Effects of Composition on the Memory Characteristics of (HfO2)x(Al2O3)1-x Based Charge Trap Nonvolatile Memory

  • Tang, Zhenjie;Ma, Dongwei;Jing, Zhang;Jiang, Yunhong;Wang, Guixia;Zhao, Dongqiu;Li, Rong;Yin, Jiang
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.5
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    • pp.241-244
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    • 2014
  • Charge trap flash memory capacitors incorporating $(HfO_2)_x(Al_2O_3)_{1-x}$ film, as the charge trapping layer, were fabricated. The effects of the charge trapping layer composition on the memory characteristics were investigated. It is found that the memory window and charge retention performance can be improved by adding Al atoms into pure $HfO_2$; further, the memory capacitor with a $(HfO_2)_{0.9}(Al_2O_3)_{0.1}$ charge trapping layer exhibits optimized memory characteristics even at high temperatures. The results should be attributed to the large band offsets and minimum trap energy levels. Therefore, the $(HfO_2)_{0.9}(Al_2O_3)_{0.1}$ charge trapping layer may be useful in future nonvolatile flash memory device application.

Case Study on the Target Products for Applicable Uni-materailization (적용 가능한 유니소재화 대상제품 발굴 및 사례 연구)

  • Ju, Hong-Shin;Yun, Hye-Ri;Yeon, Seong-Mo;Ko, Kwan-Tae
    • Clean Technology
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    • v.19 no.2
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    • pp.173-183
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    • 2013
  • A various methodologies like eco product design, recycling, remanufacturing have been proposed for the increase of resource recirculation and energy saving worldwide. Uni-materialization in this paper, one of measures is presented. Uni-materialization is defined as the unification or simplification of material that is easy resource recycling and reduce waste generation at source during product design, manufacturing, delivery, use and disposal. This study developed calculates the qualitative and quantitative of assessment index for evaluating target products applicable uni-materialization. There are 9 assessment articles considered economic performance, technological property and environmental property and a study on target product applied assessment indexes. As a result it is possible for 3 target products to apply uni-materialization product except for a window blind, and the concrete concept of uni-materialization for improving objectivity of assessment index and the consideration of industrial distinct character are needed.

Cyclic Behavior of Precast Slender Coupling Beams with Bundled Diagonally Reinforcement and High-Performance Fiber Reinforced Cementitious Composite(HPFRCC) (묶음 대각철근과 고성능 섬유보강 시멘트 복합체를 적용한 세장한 프리캐스트 연결보의 이력거동 평가)

  • Han, Sang Whan;Yu, Kyung Hwan;Kang, Dong Hun;Lee, Ki Hak;Shin, Myung Su
    • Journal of the Earthquake Engineering Society of Korea
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    • v.19 no.2
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    • pp.55-62
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    • 2015
  • Shear wall systems behave as individual wall because of openings like window and elevator cage. When coupling beams are installed in shear walls, they will have high strength and stiffness so that be less damaged by lateral loads like earthquake. However, coupling beam is difficult construction method. And arranging reinforcement of slender coupling beams are especially hard. It is because the details of coupling beam provided by ACI 318 are complex. In this paper, experiments were conducted using coupling beams with 3.5 aspect ratio to improve the details of slender coupling beams provided by ACI 318. Two specimens were proposed for this study. One specimen applied with bundled diagonally reinforcement only. Another specimen applied both bundled diagonally reinforcement and High-Performance Fiber Reinforced Cementitious Composite (HPFRCC) so that coupling beams have half of transverse reinforcement. All specimen were compared with a coupling beam designed according to ACI 318 and were evaluated with hysteretic behaviors. Test results showed that the performance of two specimen suggested in this study were similar to that of coupling beam designed according to current criteria. And it was considered that simplification of the details of reinforcement would be available if transverse reinforcement was reduced by using bundled diagonally reinforcement and HPFRCC.

Investigating InSnZnO as an Active Layer for Non-volatile Memory Devices and Increasing Memory Window by Utilizing Silicon-rich SiOx for Charge Storage Layer

  • Park, Heejun;Nguyen, Cam Phu Thi;Raja, Jayapal;Jang, Kyungsoo;Jung, Junhee;Yi, Junsin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.324-326
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    • 2016
  • In this study, we have investigated indium tin zinc oxide (ITZO) as an active channel for non-volatile memory (NVM) devices. The electrical and memory characteristics of NVM devices using multi-stack gate insulator SiO2/SiOx/SiOxNy (OOxOy) with Si-rich SiOx for charge storage layer were also reported. The transmittance of ITZO films reached over 85%. Besides, ITZO-based NVM devices showed good electrical properties such as high field effect mobility of 25.8 cm2/V.s, low threshold voltage of 0.75 V, low subthreshold slope of 0.23 V/dec and high on-off current ratio of $1.25{\times}107$. The transmission Fourier Transform Infrared spectroscopy of SiOx charge storage layer with the richest silicon content showed an assignment at peaks around 2000-2300 cm-1. It indicates that many silicon phases and defect sources exist in the matrix of the SiOx films. In addition, the characteristics of NVM device showed a retention exceeding 97% of threshold voltage shift after 104 s and greater than 94% after 10 years with low operating voltage of +11 V at only 1 ms programming duration time. Therefore, the NVM fabricated by high transparent ITZO active layer and OOxOy memory stack has been applied for the flexible memory system.

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Evaluation of Thermal and Visual Environment for the Glazing and Shading Device in an Office Building with Installed of Venetian Blind (베네시안 블라인드가 적용된 오피스 건물의 외피 투과체 계획을 위한 열·빛 환경 평가에 대한 연구)

  • Kim, Chul-Ho;Kim, Kang-Soo
    • KIEAE Journal
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    • v.15 no.6
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    • pp.101-109
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    • 2015
  • Purpose: Glazing and shading devices influence a lot on the thermal and visual environment in office buildings. Solar heat and daylight are contrary concept, therefore proper arrangement of thermal and optical performance is needed when designing a glazing and shading devices. The purpose of this study is to examine the conditions of the glazing and shading devices available for promoting the reduction of cooling loads + lighting loads and the improvement in thermal comfort and visual comfort for the summer season in an office building installed with venetian blind. Method: This study established 12 simulation cases which have different glazings and the positions of venetian blind for evaluating different thermal and optical performance. And by using EnergyPlus v8.1 and Window v7.2 program, we quantitatively analyzed cooling loads + lighting loads, thermal comfort and visual comfort in an office building installed with the glazing and shading devices. Result: Consequently, Case 9(Double Low-E+Exterior Blind) is the best arrangement of solar heat gain and daylight influx, thereby becomes the most excellent case of reducing cooling+lighting loads(46.8%) and simultaneously becomes the enhancement case in thermal comfort. Also, DGI(Daylight glare index) under clear sky conditions in summer was evaluated to be 19.6, and thereby satisfied the recommendation level of allowing visual comfort.

Patterning of ITO on Touch Screen Panels using a beam shaped femtosecond laser (빔 쉐이핑된 펨토초 레이저를 이용한 터치스크린 패널의 ITO 박막 패터닝)

  • Kim, Myung-Ju;Kim, Yong-Hyun;Yoon, Ji-Wook;Choi, Won-Seok;Cho, Sung-Hak;Choi, Jiyeon
    • Laser Solutions
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    • v.16 no.4
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    • pp.1-6
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    • 2013
  • Femtosecond laser patterning of ITO on a touch screen panel with a shaped fs laser beam was investigated. A quasi flat-top beam was formed using a variable mask and a planoconvex lens. The spatial profile of the original Gaussian beam and the shaped beam were monitored by a CCD beam profiler. The laser patterned ITO film was examined using an optical microscope, Scanning Electron Microscope (SEM) with Energy Dispersive X-ray Spectroscopy (EDS), and Atomic Force Microscope (AFM). It turned out that the quality of the ITO pattern fabricated by a shaped beam is superior to that of the pattern without beam shaping in terms of debris generation, height of the craters, and homogeneity of the bottom. Optimum processing window was determined at the laser irradiance exhibiting 100% removal of Sn. The removal rate of In was measured to be 83%.

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POSSIBILITY OF NONDESTRUCTIVE ANALYSIS OF CHOLESTEROL AND COLLAGEN IN ATHEROSCLEROTIC PLAQUES USING NIRS

  • Neumeister, Volker;Lattke, Peter;Schuh, Dieter;Knuschke, Peter;Reber, Friedemann;Steiner, Gerald;Jaross, Werner
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.4103-4103
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    • 2001
  • The aim of this study was to examine whether near infrared spectroscopy (NIRS) is an acceptable tool to determine cholesterol and collagen in human atherosclerotic plaque without destruction of the analyzed areas and without danger the endothelial cells - three preconditions for the development of a NIR-heart-catheter. The questions were: Can the cholesterol and collagen content of the arterial intima be estimated with acceptable precision in vitro by NIRS despite the matrix inhomogeneity of the plaques and their anatomic variability\ulcorner How deep can such NIR radiation penetrate into arterial tissue without danger for endothelial cells\ulcorner Is this penetration sufficient for information on the lipid and collagen accumulation\ulcorner Using NIRS, cholesterol and collagen can be determined with acceptable precision in model mixtures and human aortic specimens (r=0,896 to 0,957). The chemical reference method was HPLC. The energy dose was 71 mW/$cm^{-2}$ using a fiber optic strand with a length of 1.5m and an optical window of d=4mm. This dose appears to be not dangerous for endothelial cells, It will be attenuated to 50% by a arterial tissue of about 170-$200\mu\textrm{m}$ thickness. The results are also acceptable using a thin coronary catheter-like fiber optic strand (d=1mm).

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A Study on the Evaluation of Power Performance according to Temperature Characteristics of Amorphous Transparent Thin-Film (비정질 박막 투과형 태양전지모듈의 온도특성에 따른 발전성능 평가 연구)

  • An, Young-Sub;Song, Jong-hwa;Lee, Sung-jin;Yoon, Jong-ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.45-48
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    • 2009
  • This study evaluated the influence of temperature on the PV module surface on power output characteristics, especially for an amorphous transparent thin-film PV module which was applied to a full-scale mock-up model as building integrated photovoltaic system. The tested mock-up consisted of various slopes of PV module, facing to the south. The annual average temperature of the module installed with the slope of $30^{\circ}$ revealed $43.1^{\circ}C$, resulting in $7^{\circ}C$ higher than that measured in PV modules with the slope of $0^{\circ}$and $90^{\circ}$ did. This $30^{\circ}$ inclined PV module also showed the highest power output of 28.5W (measured at 2 PM) than other two modules having the power output of 20.4W and 14.9W in the same time for $0^{\circ}$ and $90^{\circ}$ in the slope, respectively. In case of the $30^{\circ}$ inclined PV module, it exhibited very uniform distribution of power output generation even under the higher temperature on the module surface. Consequently, the surface temperature of the PV module analyzed in this study resulted in 0.22% reduction in power output in every $1^{\circ}C$ increase of the module surface temperature.

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Characterization of Chemical Bath Deposited ZnS Thin Films and Its application to $Cu(InGa)Se_2$ Solar Cells (용액성장법에 의한 황화아연 박막층 분석 및 이의 CIGS 태양전지로의 응용)

  • Shin, Dong-Hyeop;Larina, Liudmila;Yun, Jae-Ho;Ahn, Byung-Tae
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.138-138
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    • 2009
  • Recently, thin-film solar cells of Cu(In,Ga)$Se_2$(CIGS) have reached a high level of performance, which has resulted in a 19.9%-efficient device. These conventional devices were typically fabricated using chemical bath deposited CdS buffer layer between the CIGS absorber layer and ZnO window layer. However, the short wavelength response of CIGS solar cell is limited by narrow CdS band gap of about 2.42 eV. Taking into consideration the environmental aspect, the toxic Cd element should be replaced by a different material. It is why during last decades many efforts have been provided to achieve high efficiency Cd-free CIGS solar cells. In order to alternate CdS buffer layer, ZnS buffer layer is grown by using chemical bath deposition(CBD) technique. The thickness and chemical composition of ZnS buffer layer can be conveniently by varying the CBD processing parameters. The processing parameters were optimized to match band gap of ZnS films to the solar spectrum and exclude the creation of morphology defects. Optimized ZnS buffer layer showed higher optical transmittance than conventional thick-CdS buffer layer at the short wavelength below ~520 nm. Then, chemically deposited ZnS buffer layer was applied to CIGS solar cell as a alternative for the standard CdS/CIGS device configuration. This CIGS solar cells were characterized by current-voltage and quantum efficiency measurement.

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