• Title/Summary/Keyword: energy transfer mechanism

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A Study on the Generation and Transmission of a Pressure Wave Induced by Rapid Heating of Compressible Fluid (압축성 유체의 급속 가열에 기인한 압력파의 생성 및 전달특성에 관한 연구)

  • 황인주;김윤제
    • Journal of Energy Engineering
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    • v.12 no.1
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    • pp.29-34
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    • 2003
  • Thermo-acoustic waves can be generated in a compressible fluid by rapid heating and cooling near the boundary walls. These phenomena are very important mechanism of heat transfer in the space environment in which natural convection does not exist. In this study, the generation and transmission characteristics of thermo-acoustic waves in an air filled enclosure with rapid wall heating are studied numerically. The governing equations were discretized using control volume method, and were solved using PISO algorithm and second-order upwind scheme. For the stable solution time step were considered as t=1$\times$$10^{-9}$ order, and grids are 50$\times$800. The induced thermo-acoustic wave propagates through the fluid until it decays due to viscous and heat dissipation. The wave showed sharp front shape and decreased with long tail.

A New Approach to Short-term Price Forecast Strategy with an Artificial Neural Network Approach: Application to the Nord Pool

  • Kim, Mun-Kyeom
    • Journal of Electrical Engineering and Technology
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    • v.10 no.4
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    • pp.1480-1491
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    • 2015
  • In new deregulated electricity market, short-term price forecasting is key information for all market players. A better forecast of market-clearing price (MCP) helps market participants to strategically set up their bidding strategies for energy markets in the short-term. This paper presents a new prediction strategy to improve the need for more accurate short-term price forecasting tool at spot market using an artificial neural networks (ANNs). To build the forecasting ANN model, a three-layered feedforward neural network trained by the improved Levenberg-marquardt (LM) algorithm is used to forecast the locational marginal prices (LMPs). To accurately predict LMPs, actual power generation and load are considered as the input sets, and then the difference is used to predict price differences in the spot market. The proposed ANN model generalizes the relationship between the LMP in each area and the unconstrained MCP during the same period of time. The LMP calculation is iterated so that the capacity between the areas is maximized and the mechanism itself helps to relieve grid congestion. The addition of flow between the areas gives the LMPs a new equilibrium point, which is balanced when taking the transfer capacity into account, LMP forecasting is then possible. The proposed forecasting strategy is tested on the spot market of the Nord Pool. The validity, the efficiency, and effectiveness of the proposed approach are shown by comparing with time-series models

Synthesis and photovoltaic performance of novel ionic dyes for the dye-sensitized solar cells (신규 유기염료를 적용한 염료감응 태양전지의 광전변환거동)

  • Jung, Mi Ran;Lee, Jeong Gwan;Kim, Sang Ah;Kim, Jae Hong
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.120.2-120.2
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    • 2011
  • The improvement of solar energy-to-electricity conversion efficiency has continued to be an important research area of dye-sensitized solar cells (DSSCs). The mechanism of DSSCs is based on the injection of electrons from the photoexcited dye into the conduction band of nanocrystalline TiO2 or ZnO. Thus, the electronic structures, such as HOMO, LUMO, and HOMO-LUMO band gaps of dye moleculed in DSSC are deeply related to the electron transfer by photoexcitation and redox potential. Organic dyes, because of their many advantages, such as high molar extinction coefficients, convenience of customized molecular design for desired photophysical and photochemical properties, inexpensiveness with no transition metals contained, and environment-friendliness, are suitable as photosensitizers for DSSC. We believe that practically useful organic dye photosensitizers can be produced by exploiting electron donor/acceptor system with proper length of ${\pi}$-conjugation in a chromophore to control the absorption wavelength and enhance the photovoltaic performance. In this research, We designed and synthesized organic dyes also investigated the photoelectrochemical properties of a series of ionic dyes in DSSCs.

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Various Sensor Applications Based on Conjugated Polymers

  • Lee, Chang-Lyoul
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.103.1-103.1
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    • 2014
  • Due to their excellent optical and electrochemical properties, conjugated polymers have attracted much attention over the last two decades and employed to opto-electrical devices. In particular, conjugated polymers possess many attractive features that make them suitable for a variety of sensing task. For example, their delocalized electronic structures can be strongly modified by varying the surrounding environment, which significantly affected molecular energy level. In other word, conjugated polymers can detect and transduce the environmental information into a fluorescence signal. Conjugated polymers also display amplified quenching compared to small molecule counterparts. This amplified fluorescence quenching is attributed to the delocalization and migration of the excitons along the conjugated polymer backbones. Long backbones of conjugated polymer provide the transporting path for electron as a conduit, allowing that excitons migrate rapidly into quencher site along the backbone. This is often referred to as the molecular wire effect or antenna effect. Moreover, structures of conjugated polymers can be easily tailored to adjust solubility, absorption/emission properties, and regulation of electron/energy transfer. Based on this versatility, conjugated polymers have been utilized to many novel sensory platforms as a promising material. In this tutorial, I will highlight a variety of fluorescence sensors base on conjugated polymer and explain their sensory mechanism together with selected examples from reference literatures.

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The Study of Charge Transfer Mechanism in Single Crystal Iron Perovskite (단결정 철 페롭스카이트의 전하전이 연구)

  • Uhm Young-Rang;Rhee Chang-Kyu;Kim Chul-Sung
    • Journal of Powder Materials
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    • v.13 no.2 s.55
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    • pp.112-118
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    • 2006
  • [ $R_{1/3}Sr_{2/3}FeO_{3}$ ](R=Pr, Nd, and Sm) was synthesized and their magnetic properties and charge ordering(CO) transition related with lattice dynamics and oxygen vacancy were systematically investigated. The charge disproportion ation(CD) in $R_{1/3}Sr_{2/3}FeO_{3}$(R=Pr,Nd) was in which two kins of iron with valence state $Fe^{3+}$ and $Fe^{5+}$ were found with ratio of 2:1. In this charge ordering state a sequence of $Fe^{3+}Fe^{3+}Fe^{5+}Fe^{3+}Fe^{3+}Fe^{5+}$ exists aligned along the [111] direction of the pseudocubic perovskite structure. The charge ordering exist in distorted structure involving $t_{pd}$ hybridization. The disordering phases coexist in distorted structure as temprature in creases that is controlled amount of oxygen vacancy. The magnetic hyperfine fields indicate charge tranfering temperature as it dissapeared drastically.

Study of Deep Blue Organic Light-Emitting Diodes Using Doped BCzVBi with Various Blue Host Materials

  • Kim, Tae-Gu;Oh, Hwan-Sool;Kim, You-Hyun;Kim, Woo-Young
    • Transactions on Electrical and Electronic Materials
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    • v.11 no.2
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    • pp.85-88
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    • 2010
  • Deep blue organic light emitting diodes (OLEDs) were fabricated using 5 wt.% doped BCzVBi with various blue host materials such as NPB, DPVBi, MADN and TPBi. A blue OLED device, using DPVBi as host material, was constructed via NPB ($500\;{\AA}$) / DPVBi:BCzVBi ($200\;{\AA}$) / Bphen ($300\;{\AA}$) / LiF ($20\;{\AA}$) / Al ($1,000\;{\AA}$) and it shows a maximum luminescence of $4,838\;cd/m^2$, a current density of $32.7\;mA/cm^2$, a luminous efficiency of 3.3 cd/A and CIExy coordinates of (0.19, 0.15) at 4.5 V whereas the luminous efficiencies and CIExy coordinates of other blue OLEDs using NPB, MADN and TPBi as host materials have 1.1, 2.6 and 2.0 cd/A and (0.15, 0.11), (0.15, 0.10) and (0.15, 0.10), respectively. Energy transfer mechanisms between BCzVBi and its host materials were discussed with an energy band structure of host materials.

Analysis of Passive Cooling Effect of Membrane Shading Structure and the Tree by Field Observations in the Summer (하절기 복사환경 관측을 통한 수목과 일사차폐 막 구조물의 자연냉각효과)

  • Choi, Dong-Ho;Lee, Bu-Yong
    • Journal of the Korean Solar Energy Society
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    • v.27 no.4
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    • pp.137-146
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    • 2007
  • This study is about the passive cooling effects of three outdoor solar shading facilities as trees, pergola with wistaria vine and membrane shading structure, which are expected to provide cool spots in the summer. Field observations of measuring thermal environment of selected facilities is executed. Thermal environment measuring was categorized as short wave radiation, long wave radiation, net radiation, globe temperature, surface temperature measured by infrared camera. Heat transfer mechanism is analyzed with overall data from field measurement. Results from this study are as below; 1) Radiation balance measured on shaded surface under membrane shading structure was 17%($86W/m^2$) of the unshaded surface radiation balance($511W/m^2$). 2) Surface temperature comparison between vegetation and membrane of the shading structure is performed at 3 o'clock in the afternoon. Surface temperature of vegetation was same as air temperature and that of membrane was $5^{\circ}C$ higher than air temperature. Vegetation transpiration is considered as the causing factor which make those differences. 3) Results from this study could be used as fundamental data for reducing heat island phenomena and continuos research on this subject would be needed.

Rationale and Definition of The Criteria of The Efficiency of The Biological Activity of Optical Radiation on Animal Organism.

  • Chervinsky, Leonid S.
    • The Korean Journal of Food & Health Convergence
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    • v.4 no.3
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    • pp.1-5
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    • 2018
  • In today's technological development of human society more and more influence on the lives of biological organisms different electromagnetic radiation. Therefore, the study and analysis of the mechanisms of their effects is an urgent task. The purpose of research - the study of the primary mechanisms of interaction of photons of optical radiation with the structures of biological objects, using the laws of quantum mechanics and biophysics. Photobiological basis of the mechanism of action of EMR optical range is the energy absorption of light quanta (photons) by atoms and molecules of biological structures (law Grotgus-Draper), which resulted in the formation of electronically excited states of these molecules with the transfer of photon energy (internal photoeffect). This is accompanied by electrolytic dissociation and ionization of biological molecules. The degree of manifestation of photobiological effects in the body depends on the intensity of the optical radiation, which is inversely proportional to the square of the distance from the source to the irradiated surface. Accordingly, in practice, determine not the intensity and irradiation dose at a certain distance from the source of exposure by the exposure time.

Detection of flaw in steel anchor-concrete composite using high-frequency wave characteristics

  • Rao, Rajanikant;Sasmal, Saptarshi
    • Steel and Composite Structures
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    • v.31 no.4
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    • pp.341-359
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    • 2019
  • Non-monolithic concrete structural connections are commonly used both in new constructions and retrofitted structures where anchors are used for connections. Often, flaws are present in anchor system due to poor workmanship and deterioration; and methods available to check the quality of the composite system afterward are very limited. In case of presence of flaw, load transfer mechanism inside the anchor system is severely disturbed, and the load carrying capacity drops drastically. This raises the question of safety of the entire structural system. The present study proposes a wave propagation technique to assess the integrity of the anchor system. A chemical anchor (embedded in concrete) composite system comprising of three materials viz., steel (anchor), polymer (adhesive) and concrete (base) is considered for carrying out the wave propagation studies. Piezoelectric transducers (PZTs) affixed to the anchor head is used for actuation and the PZTs affixed to the surrounding concrete surface of the concrete-anchor system are used for sensing the propagated wave through the anchor interface to concrete. Experimentally validated finite element model is used to investigate three types of composite chemical anchor systems. Studies on the influence of geometry, material properties of the medium and their distribution, and the flaw types on the wave signals are carried out. Temporal energy of through time domain differentiation is found as a promising technique for identifying the flaws in the multi-layered composite system. The present study shows a unique procedure for monitoring of inaccessible but crucial locations of structures by using wave signals without baseline information.

Hydrophobic Surface Treatment with Anisotropic Characteristics Using Laser Selective Deposition (레이저 선택적 증착을 통한 이방특성의 소수성 표면처리)

  • Kim, Ji-Hun;Kwon, Ye-Ji;Yang, Hoon-Seok;Kim, Joohan
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.11
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    • pp.109-115
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    • 2020
  • Surfaces with various roughnesses were produced through laser processing, and the anisotropy and hydrophobicity of the surfaces were examined in the context of the microstructures. The fine particles transferred to the glass surface exhibited different sizes, and the roughness increased. Due to the change in the roughness, the liquid could not penetrate the space between the fine particles, and it was thus exposed to the air. We analyzed this phenomenon using the combined Wenzel and Cassie-Baxter models. Excessive fine particle formation on the substrate tended to increase the roughness and surface energy. The silver-glass-air contact analysis could clarify the mechanism of the reduction of the contact angle and differences in the metastable and stable states when the particles did not completely cover the glass substrate. The formation of microstructures with fine particles through the laser selective deposition led to the generation of an anisotropic surface as the water droplets diffused toward the glass substrate with a relatively high surface energy level.