• Archives of Pharmacal Research
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• v.6 no.2
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• pp.109-114
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• 1983

A mechanism of taurine transfer across the rat small intestine was elucidated by using the in situ recirculation perfusion or loop method. Taurine uptake was saturable, Km= 39.9 mM, and energy dependent, and required sodium. The close structural analogues, aminomethane sulfonic acid, .gamma.-amino-butyric acid, hypotaurine, and .betha.-alanine, reduced significantly taurine uptake when present in 10-fold excess. The .alpha.-amino acid, glycine, did not inhibit uptake. Hence, all of these findings lead to a conclusion that a carrier-mediated transport system for taurine exists in the small intestine.

• Bulletin of the Korean Chemical Society
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• v.28 no.4
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• pp.607-612
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• 2007

Relationship between charge transfer mechanism and quantum coherence has been investigated using a realtime quantum dynamics approach. In the on-the-fly filtered propagator functional path integral simulation, by separating paths that belong to different mechanisms and by integrating contributions of correspondingly sorted paths, it was possible to accurately obtain quantitative contribution of different transport mechanisms. For a 5'-GAGGG-3' DNA sequence, we analyze charge transfer processes quantitatively such that the governing mechanism alters from coherent to incoherent charge transfer with respect to the friction strength arising from dissipative environments. Although the short DNA sequence requires substantially strong dissipation for completely incoherent hopping transfer mechanism, even a weak system-environment interaction markedly destroys the coherence within the quantum mechanical system and the charge transfer dynamics becomes incoherent to some degree. Based on the forward-backward path deviation analysis, the coherence variation depending on the environment is investigated numerically.

• Bulletin of the Korean Chemical Society
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• v.22 no.9
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• pp.1005-1008
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• 2001

The lanthanide complexes have been anticipated to exhibit high efficiency along with a narrow emission spectrum. Photoluminescence for the lanthanide complex is characterized by a high efficiency since both singlet and triplet excitons are involve d in the luminescence process. However, the maximum external electroluminescence quantum efficiencies have exhibited values around 1% due to triplet-triplet annihilation at high current. Here, we proposed a new energy transfer mechanism to overcome triplet-triplet annihilation by the Eu complex doped into phosphorescent materials with triplet levels that were higher than singlet levels of the Eu complex. In order to show the feasibility of the proposed energy transfer mechanism and to obtain the optimal ligands and host material, we have calculated the effect depending on ligands as a factor that controls emission intensity in lanthanide complexes. The calculation shows that triplet state as well as singlet state of anion ligand affects on absorption efficiency indirectly.

• Korean Chemical Engineering Research
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• v.47 no.5
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• pp.587-592
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• 2009

Heat transfer model and energy dissipation rate were investigated to examine the heat transfer mechanism in bubble columns with continuous operation. The energy dissipation rate($E_D$) obtained from the unsteady state heat transfer model based on the surface renewal theory was significantly small, comparing with the hydrodynamic energy dissipation rate($P_v$) calculated from the overall hydrodynamic energy balance based on the behaviors and holdups of gas and liquid phases in the column. It was found from these results that the energy dissipation rate based on the surface renewal theory is independent of the hydrodynamic energy dissipation rate obtained from the overall hydrodynamic energy balance in the bubble column, in considering their mechanism. The different two energy dissipation rates were correlated in terms of operating variables within this experimental conditions, respectively.

• Nuclear Engineering and Technology
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• v.36 no.2
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• pp.127-141
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• 2004

Various types of integrated steam generators, which integrate IHTS and a steam generator into a single unit of equipment for an LMR, were analyzed using an analytic solution with some simplification. The analysis showed that the undesirable reversed heat transfer, of which occurrence was previously observed only in an integrated single-region bundle type, can also occur in an integrated double-region bundle type. The mechanism of the reversed heat transfer occurrence in the double-region type is explained and it is shown the mechanism in the double-region type is completely different from that in the single-region type. Based on this finding, a method for preventing the aforementioned heat transfer is suggested. The performance of the four types of the integrated steam generators is assessed. For this assessment, a SG is actually designed for each type and the optimization in the geometric parameters and flow rate are optimized.

• Korean Journal of Radiology
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• v.24 no.6
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• pp.522-528
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• 2023

• Journal of the Korean Chemical Society
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• v.28 no.4
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• pp.251-258
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• 1984

The mechanism of photosensitization and the affect of binder on dye-sensitized ZnO have been studied by surface photovoltage spectroscopy. It has been found that the value of energy trapping level $E_{t1}$ on ZnO is 1.12eV (${\lambda$ = 1,100nm) and that of energy trapping level $E_{t2}$ on dye-sensitized ZnO is 0.99eV (${\lambda$ = 1,250nm) which is shifted towards a longer wavelength. The effect of binder on ZnO has been increased the efficiency of surface photovoltage, but it does not effect the values of energy trapping level. The acid-type dyes agree well with the prediction based on an electron transfer mechanism. The desensitization of the Na salt-type dyes for the intrinsic photoresponse of zinc oxide can be explained by energy transfer mechanism. It has been obtained that the dye-sensitized ZnO indicates the possibility of electrophotographic photosensitizer for the infrared range of light.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.25 no.7
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• pp.511-515
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• 2012

A road energy harvester was designed and fabricated to convert mechanical energy from the vehicle load to electrical energy. The road energy harvester is composed of 24 piezoelectric cantilevers and a vehicle load transfer mechanism. Applying a vehicle load transfer mechanism rather than directly installing energy harvesters under roads decreases the area of road construction and allows more energy harvesters to be installed on the side of the road. The power generation amount with respect to the vehicular velocity change was assessed by installing the vehicle load transfer mechanism and the energy harvester in the form of speed bumps and underground. The energy harvester installed in a speed bump form generated power of 7.61 mW at the vehicular velocity of 20 km/h. Also, power generation of the energy harvester installed in the underground form was 63.9 mW at the vehicular velocity of 28 km/h. Although the number of piezoelectric cantilevers was reduced by 1/3 to 24 in comparison to the previous research results with 72 piezoelectric cantilevers, similar power generation characteristic value was obtained within the vehicular velocity of 20 km/h by altering the vehicle load transfer mechanism and cantilever vibration method.

• Journal of the Semiconductor & Display Technology
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• v.18 no.1
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• pp.48-52
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• 2019

The blue emitting fluorescence of $SrAl_{12}O_{19}:Ce_{0.09}{^{3+}}$, $Eu_{0.01}{^{2+}}$ phosphor includes two kinds of independent energy transfer mechanism through electric multipole interactions between donor and acceptor ions. The first energy transfer takes place between the $Ce^{3+}$ ion and the $Eu^{2+}$ion which strongly depends on the concentration $Eu^{2+}$ions. The second energy transfer occurs between the $Ce^{3+}$ ion and the $O_{Me}-Ce^{3+}$ complexes. Both energy transfer mechanisms of blue emitting peak at 410 nm were investigated by fitting of Gaussian functions. The result shows that the peak at 410 nm is two overlapping emissions originated by $Eu^{2+}$ions and $O_{Me}-Ce^{3+}$ complexes and as time elapses $Eu^{2+}$peak remains whereas $O_{Me}-Ce^{3+}$ related peak disappears.

• Rapid Communication in Photoscience
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• v.4 no.2
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• pp.41-44
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• 2015

Biomolecular photo-damaging activity of a water-soluble cationic porphyrin was examined using human serum albumin (HSA), a water-soluble protein as a target biomolecule model by a fluorometry. Dichlorophosphorus(V) tetraphenylporphyrin ($Cl_2P(V)TPP$), was synthesized and used as a photosensitizer. This porphyrin could bind to HSA and cause the photosensitized oxidation of HSA through the singlet oxygen generation and the oxidative photo-induced electron transfer (ET). Near infrared emission spectroscopy demonstrated the photosensitized singlet oxygen generation by this porphyrin. Decrement of the fluorescence lifetime of $Cl_2P(V)TPP$ by HSA supported the ET mechanism. Furthermore, the estimated Gibb's energy indicated that the ET mechanism is possible in the terms of energy. Because oxygen concentration in cancer cell is relatively low, ET mechanism is considered to be advantageous for photosensitizer of photodynamic therapy.