• Journal of Powder Materials
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• v.30 no.6
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• pp.509-515
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• 2023

Lead-free perovskite ceramics, which have excellent energy storage capabilities, are attracting attention owing to their high power density and rapid charge-discharge speed. Given that the energy-storage properties of perovskite ceramic capacitors are significantly improved by doping with various elements, modifying their chemical compositions is a fundamental strategy. This study investigated the effect of Zn doping on the microstructure and energy storage performance of potassium sodium niobate (KNN)-based ceramics. Two types of powders and their corresponding ceramics with compositions of (1-x)(K,Na)NbO₃-xBi(Ni_2/3Ta_1/3)O₃ (KNN-BNT) and (1-x)(K,Na)NbO₃-xBi(Ni_1/3Zn_1/3Ta_1/3)O₃ (KNN-BNZT) were prepared via solid-state reactions. The results indicate that Zn doping retards grain growth, resulting in smaller grain sizes in Zn-doped KNN-BNZT than in KNN-BNT ceramics. Moreover, the Zn-doped KNN-BNZT ceramics exhibited superior energy storage density and efficiency across all x values. Notably, 0.9KNN-0.1BNZT ceramics demonstrate an energy storage density and efficiency of 0.24 J/cm³ and 96%, respectively. These ceramics also exhibited excellent temperature and frequency stability. This study provides valuable insights into the design of KNN-based ceramic capacitors with enhanced energy storage capabilities through doping strategies.

• Ceramist
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• v.21 no.2
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• pp.49-58
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• 2018

Metal oxide based materials have been widely used to fields of electrochemical applications. Recently, various type of defects from microstructures of metal oxides and their nanocomposites have been raised as the important material design factors for realizing highly improved electrochemical properties. Previous experimental and theoretical works have suggested that controlling the reaction activity and kinetics of the key electrochemical reactions by activated interfaces originating from the defect sites can play an important role in achieving the robust energy storage and conversion. Therefore, this paper focuses on the role of defect-controlled metal oxide materials such as doping, edge-sites, grain boundaries and nano-sized pores for the high performances in energy storage devices and electrocatalysts. The research approaches demonstrated here could offer a possible route to obtain noble ideas for designing the metal oxide materials for the energy storage and conversion applications.

• Transactions on Electrical and Electronic Materials
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• v.2 no.3
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• pp.1-6
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• 2001

A simulation method is proposed to study the amorphous structure of carbon nitride. The material properties of a non-uniform nitrogen distribution in an amorphous CN matrix can be studied. The cohesive energy of a group of randomly generated atoms can be minimized to find the relative positions of atoms. From the calculated configuration of atoms, many properties of amorphous carbon nitride can be calculated such as bulk modulus, P-V curve, sp$^3$/sp$^2$ ratio of carbon, and vibrational spectra. The calculation shows that the cohesive energy of non-uniform nitrogen distribution is lower than that of a uniform distribution. This may suggest that the regular structure of carbon nitride can at most be metastable. It is not easy to incorporate nitrogen atoms into a carbon matrix.

• Journal of Biosystems Engineering
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• v.19 no.3
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• pp.211-221
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• 1994

In this study, to maximize the solar energy utilization for greenhouse heating during the winter season, solar energy-underground latent heat storage system was constructed, and the thermal performance of the system has been analyzed to obtain the basic data for realization of greenhouse solar heating system. The results are summarized as follows. 1. $Na_2SO_4{\cdot}10H_20$ was selected as a latent heat storage material, its physical properties were stabilized and the phase change temperature was controlled at $13{\sim}15^{\circ}C$. 2. Solar radiation of winter season was the lowest value in December, and Jinju area was the highest and the lowest value was shown in Jeju area. 3. The minimum inner air temperature of greenhouse with latent heat storage system(LHSS) was $7.0{\sim}7.5^{\circ}C$ higher than that of greenhouse without LHSS and was $7.0{\sim}11.2^{\circ}C$ higher than the minimum ambient air temperature. 4. Greenhouse heating effect of latent heat storage system was getting higher according to the increase of solar radiation and was not concerned with the variation of minimum ambient air temperature. 5. The relative humidity of greenhouse with latent heat storage system was varied from 50 to 85%, but that of greenhouse without LHSS was varied from 30 to 93%. 6. The heating cost of greenhouse with solar energy-latent heat storage system was about 24% of that with the kerosene heating system.

• Proceedings of the Korean Magnestics Society Conference
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• 2011.12a
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• pp.14-14
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• 2011

Limited understanding of the surface properties of $Pt_3Ni$ for the oxygen reduction reaction (ORR) in polymer electrolyte membrane fuel cell (PEMFC) has motivated the study of magnetic properties and electronic structures of Pt segregated $Pt_3Ni$ (111) surface during adsorption of oxygen molecule on it. The first principle method based on density functional theory (DFT) is carried out. Nonmagnetic Pt has induced magnetic moment due to strong hybridization between Ni 3d and Pt 5d. It is found that an oxygen molecule prefers bridge site with Pt rich subsurface environment for adsorption on the surface of Pt segregated $Pt_3Ni$ (111). It is seen that there is very small charge transfer from $O_2$ to Pt. The curve of energy versus magnetic moment of the oxygen explains the magnetic moments in transition states. We found the dissociation barrier of 1.07eV significantly higher than dissociation barrier 0.77eV on Pt (111) suggesting that the dissociation is more difficult on Pt segregated $Pt_3Ni$ (111) surface. The spin polarized densities of states are presented in order to understand electronic structures of Pt and $O_2$ during the adsorption in detail.

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.2
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• pp.184-193
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• 2020

One of the technical methods to increase the volumetric energy density of hydrogen is to pressurize the gaseous hydrogen and then contain it in a rigid vessel. Especially for automotive systems, the compressed hydrogen storage can be found in cars as well as at refueling stations. During the charging the pressurized hydrogen into a vessel, the temperature increases with the amount of stored hydrogen in the vessel. The temperature of the vessel should be controlled to be less than a limitation for ensure stability of material. Therefore, the accurate estimation of temperature is of significance for safely storing the hydrogen. In this work, three well-known cubic equations of state (EOSs) were adopted to examine the accuracy in regenerating thermodynamic properties of hydrogen within the temperature and pressure ranges for the compressed hydrogen storage. The formulations representing molar volume, internal energy, enthalpy, and entropy were derived for Redlich-Kwong (RK), Soave-Redlioch-Kwong (SRK), and Peng-Robinson (PR) EOSs. The calculated results using the EOSs were compared with literature data given by NIST. It was revealed that the accuracies of RK and SRK EOSs were satisfactorily compatible and better than the results by PR EOS.

• Journal of Soil and Groundwater Environment
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• v.26 no.3
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• pp.14-24
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• 2021

Aquifer thermal energy storage (ATES) system uses groundwater thermal energy for cooling and heating of buildings, and it is also often utilized to provide warm water to crops and plants for the purpose of enhancing agricultural yields. This study investigated the potential influences of a ATES system on the geochemical properties of groundwater by simulating the variation of hydrochemistry and saturation index of groundwater during ATES operation. The test bed was installed at an agricultural field, which is mainly composed of an groundwater-rich alluvial plain. The simulation results showed no significant precipitation of mineral phases such as manganese-iron oxide, carbonate and sulfate around the ATES test bed, as well as no debasement of other important water quality parameters. The implementation of ATES system in the study area was appropriate and effective for utilizing the thermal energy of groundwater for agricultural use.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.10 no.10
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• pp.4681-4702
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• 2016

Recently, Massive energy consumption in Cloud Storage System has attracted great attention both in industry and research community. However, most of the solutions utilize single method to reduce the energy consumption only in one aspect. This paper proposed an energy effective gear-shifting mechanism (E2GSM) in Cloud Storage System to save energy consumption from multi-aspects. E2GSM is established on data classification mechanism and data replication management strategy. Data is classified according to its properties and then be placed into the corresponding zones through the data classification mechanism. Data replication management strategies determine the minimum replica number through a mathematical model and make decision on replica placement. Based on the above data classification mechanism and replica management strategies, the energy effective gear-shifting mechanism (E2GSM) can automatically gear-shifting among the nodes. Mathematical analytical model certificates our proposed E2GSM is energy effective. Simulation experiments based on Gridsim show that the proposed gear-shifting mechanism is cost effective. Compared to the other energy-saved mechanism, our E2GSM can save energy consumption substantially at the slight expense of performance loss while meeting the QoS of user.

• Elastomers and Composites
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• v.52 no.1
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• pp.17-21
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• 2017

The optimum mixing conditions of silica and silane containing rubber composites were evaluated by investigating the properties of rubber composites prepared with a silica composition of 10, 20, 40, 60, and 80 g, respectively. The crosslinking rate decreased with increasing silica content, with he promoters being adsorbed on the silica surface with in the rubber composite. As a result, the increase in crosslinking time resulted in the destruction of the silica structure. The increase of the bound rubber content due to the destruction of the silica structure inhibited the chain motion of the polymer molecules and reduced the cohesion of the silica itself. Finally, the increase of silica content showed the increase of hardness, tensile strength, and storage modulus of rubber composites.

• Elastomers and Composites
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• v.39 no.3
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• pp.186-192
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• 2004

Compression and rebounding properties of IP(injection phylon), PH(phylon) and PU(polyurethane) foams were studied. The compression stress, rebounding stress, loss compression energy and storage compression energy of foams were decreased with increasing hardness of foams. The compression stress, loss compression energy of IP foams were lower than those of PH and PU. Rebounding stress and storage compression energy of PU foams were higher than those of IP and PH. The compression stress and rebounding of PH foam were lower than those of IP and PU.