• Mass Spectrometry Letters
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• v.5 no.4
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• pp.120-123
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• 2014

The interference of water vapor on the chemical ionization (CI) of hydroxyl radicals (OH) by sulfur hexafluoride ion ($SF_6{^-}$) was investigated using a flow tube system coupled to a high-pressure CI mass spectrometer. Water vapor, which is required to study heterogeneous reactions of OH under real tropospheric conditions, transforms the reagent ion $SF_6{^-}$ into $SF_4O^-$ and $F^-(HF)_n$, resulting in a substantial loss in CI sensitivity. Therefore, under humid conditions, peaks corresponding to OH are drastically diminished, while those corresponding to OH-water complex ions ($[OH(H_2O)_n]^-$) are enhanced. $[OH(H_2O)_3]^-$ was observed as the major OH species. The obsercation of $[OH(H_2O)_n]^-$ by isolating humid conditions to the CI region and preliminary ab initio calculations suggested that $[OH(H_2O)_n]^-$ ions were produced from reactions between OH ions ($OH^-$) and water molecules. An additional helium buffer flow introduced into the CI region reduced loss of the reagent ion and resulted in a partial recovery of OH peak intensities under humid conditions.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.122.1-122.1
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• 2011

The motivation for this work was the potential of hydrophobic amino acids such as glycine, L-alanine, and L-valine to be applied as thermodynamic hydrate inhibitors (THIs). To confirm their capabilities in inhibiting the formation of gas hydrates, three-phase (liquid-hydrate-vapor) equilibrium conditions for carbon dioxide hydrate formation in the presence of 0.1 to 3.0 mol% amino acid solutions were determined in the range of 273.05 to 281.45 K and 14.1 to 35.2 bar. From quantitative analyses, the inhibiting effects of the amino acids (on a mole concentration basis) decreased in the following order: L-valine > L-alanine > glycine. The application of amino acids as THIs has several potential advantages over conventional methods. First, the environmentally friendly nature of amino acids as compared to conventional inhibitors means that damage to ecological systems and the environment could be minimized. Second, the loss of amino acids in recovery process would be considerably reduced because amino acids are non-volatile. Third, amino acids have great potential as a model system in which to investigate the inhibition mechanism on the molecular level, since the structure and chemical properties of amino acids are well understood.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.11 no.5
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• pp.2741-2761
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• 2017

With the purpose of copyright protection for digital video, a novel H.264/AVC watermarking algorithm based on JND model is proposed. Firstly, according to the characteristics of human visual system, a new and more accurate JND model is proposed to determine watermark embedding strength by considering the luminance masking, contrast masking and spatial frequency sensitivity function. Secondly, a new embedding strategy for H.264/AVC watermarking is proposed based on an analysis on the drift error of energy distribution. We argue that more robustness can be achieved if watermarks are embedded in middle and high components of $4{\times}4$ integer DCT since these components are more stable than dc and low components when drift error occurs. Finally, according to different characteristics of middle and high components, the watermarks are embedded using different algorithms, respectively. Experimental results demonstrate that the proposed watermarking algorithm not only meets the imperceptibility and robustness requirements, but also has a high embedding capacity.

• 한국신재생에너지학회:학술대회논문집
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• 2006.06a
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• pp.37-42
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• 2006

In this study, $20Nm^3/hr$ scale compact hydrogen generator which can be apply to the hydrogen station was tested for hydrogen station application. $20Nm^3/hr$ scale compact hydrogen generator was developed by upgrading concept of stacking plate reactor from former $20Nm^3/hr$ scale plate hydrogen generator. concepts for improving system efficiency and performance include such as idea of heat recovery from the exhaust, exhaust duct which is especially design for plate type reactor reinforcement of insulation, enlargement of heat exchange area of reactor, introduction of desulphurizer reactor and PROX rector in a compact design, introduction of back fire protection structure of plate burner and so on, We can learn that final prototype of scale-up $20Nm^3/hr$ scale compact hydrogen generator can be operated steadily in 100% road at which over 94% of methane conversion(S/C=3.75) was obtained. In case of making up the weak point, we expect that it is possible to apply to hydrogen station by way of showing an example.

• Journal of Power Electronics
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• v.17 no.6
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• pp.1391-1401
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• 2017

In this paper, a secondary resonance half-bridge dc-dc converter with an inductive output filter is presented. The primary side of such a converter utilizes asymmetric pulse width modulation (APWM) to achieve zero-voltage switching (ZVS) of the switches, and clamps the voltage of the switch to the input voltage. In addition, zero current switching (ZCS) of the output diode is achieved by a half-wave rectifier circuit with a filter inductor and a resonant branch in the secondary side of the proposed converter. Thus, the switching losses and diode reverse-recovery losses are eliminated, and the performance of the converter can be improved. Furthermore, an inductive output filter exists in the converter reduce the output current ripple. The operational principle, performance analysis and design equation of this converter are given in this paper. The analysis results show that the output diode voltage stress is independent of the duty cycle, and that the voltage gain is almost linear, similar to that of the isolation Buck-type converter. Finally, a 200V~380V input, 24V/2A output experimental prototype is built to verify the theoretical analysis.

• Journal of Korean Society for Atmospheric Environment
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• v.28 no.3
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• pp.306-315
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• 2012

In this study, storage stability of reduced sulfur compounds ($H_2S$, $CH_3SH$, DMS, $CS_2$, and DMDS) and $SO_2$ in sampling bags was investigated in terms of two contrasting storage approaches between forward (F) and reverse (R) direction. The samples for the F method were prepared at the same time and analyzed sequentially through time. In contrast, those of reverse (R) method were prepared sequentially in advance and analyzed all at once upon the preparation of the last sample. In addition, relative performance between two different bag materials (PVF and PEA) was also assessed by using 100 ppb standard. The response factors (RF) of gaseous RSC samples were determined by gas chromatography/pulsed flame photometric detector (GC/PFPD) combined with air server (AS)/thermal desorber (TD) system at storage intervals of 0, 1, and 3 days. There is no statistical difference in all RSCs between two storage methods. However, the results of relative recovery indicated 2.58~12.8% differences in compound type between the two storage methods. Moreover, loss rates and storage stability of $H_2S$ and $SO_2$ were considerably affected by bag materials than any other variables. Therefore, some considerations about storage methods (or bag material types) for sulfur compounds are needed if stored by sampling bag method.

• Journal of Energy Engineering
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• v.12 no.1
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• pp.35-41
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• 2003

Heat regenerator occupied by regenerative materials improves thermal efficiency of regenerative combustion system through the recovery of heat of exhaust gaset. By using one-dimensional two-phase fluid dynamics model, the unsteady thermal flow of heat regenerator with spherical particles, was numerically simulated to evaluate the heat transfer and pressure drop and thereby to suggest the parameter for designing heat regenerator. It takes about 7 hours for the steady state of the flow field in regenerator, in which heat absorption of regenerative particle is concurrent with the same magnitude of heat desorption. The regenerative particle experiences small temperature fluctuation below 10 K during the reversing process. The performance of thermal flow in heat regenerator varies with inlet velocity of exhaust gas and air, configuration of regenerator (cross-sectional area and length) and diameter of regenerative particle. As the gas velocity increases, the heat transfer between gas and particle enhances and with the increase the pressure losses. As particle diameter decreases, the air is preheated higher and the exhaust gases are cooled more with the increase of pressure losses.

• Journal of the Korean Society for Marine Environment & Energy
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• v.3 no.3
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• pp.34-40
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• 2000

A multisample extraction device was newly designed for efficient extraction of dissolved lipophillic organic compounds from sea water sample. This device allowed extraction of organic compounds from up to 96 sample at a time using 96 multifolder on the principle of solid phase extraction with commercially available octadecyl silane (ODS) cartridges. The recovery yield of the new divice was higher than 90 % while that of conventional liquid-liquid extraction process are only 60 - 70 %. The amount of solvent required for the new device could be reduced to less than 20㎖ per 1ℓ of sample while 1 - 2 ℓ of solvent were used in the conventional liquid-liquid extraction process. The usefulness of this novel method was demonstrated with sea water samples collected from Yellow sea, and the qualitative and quantitative analyses results of the dissolved hydrocarbon showed this method was superior to that of conventional liquid-liquid extraction process in efficiency and reliability.

• Proceedings of the Korean Environmental Health Society Conference
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• 2002.04a
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• pp.91-99
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• 2002

A recent survey investigated that there were over one thousand un-controlled closed landfills(1,072 sites) in Republic of Korea. Most of these landfills were constructed before 1986. Waste management act were not promulgated at that time, so they usually do not have dranage system and leachate treatment facility. Also, considerable attention has been received to landfill leachate pollution, leachate has an adverse impact on the surrounding environment such as soil, groundwater, and water supply source. According to the result of survey for closed landfill management, it was reported that 875 sites out of 1,072sites(81.6％) have no leachate treatment facility and 630 sites out of 1,072sites(58.7％) have been used for farm lands and residence. Consequently it is hard to do postclosure care continuously in most of cases and these uncontrolled landfills have contaminated farm lands and residence. The average age of these landfills are ranged mostly between 2 to 15 years. Much time and advanced technology are needed to remediate these uncontrolled landfills, therefore the survey for present status of closed landfill sites is required and suitable treatment processes should be prepared. With this point of view, We has been investigated to find out the present status of closed landfill, problems of post management and discussed plans for remediation and reuse. Remedial actions of un-controlled landfill have been carried out the many cities since 1997 upto now. Most frequently applied technology were reuse after excavation and there were several cases to capping in the surface of landfill and to construct subsurface barriers. It is considered that landfills in use have a possibility not to be controlled because of inadequate construction and improper management. Therefore remediation of uncontrolled landfills and recovery technology should be develop continuously Especially, it has been expected that resource technology of landfill gas as a energy has some advantages in controlling odors in the site area and accelerating stabilization of landfills with the energy.

• Transactions of Materials Processing
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• v.23 no.7
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• pp.405-412
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• 2014

As a major type of heat exchanger, the steam generator (SG) produces steam from heat energy of a nuclear power plant reactor. The steam produced by the steam generator flows into a turbine, and plays an important role in electric power generation. The heat transfer tubes in the steam generator consist of approximately 10,000 U-shaped tubes, which perform a structural role and act as thermal boundaries. The heat transfer tubes conduct the thermal energy between the primary coolant (about $320^{\circ}C$, $157kgf/cm^2$) obtained from the reactor and the secondary coolant (about $260^{\circ}C$, $60kgf/cm^2$) as part of the secondary system. Recently, the heat transfer tubes in the steam generator of the pressurized water reactor (PWR) are primarily produced from Alloy 600 and Alloy 690 seamless tubes. As a pilot study to find process parameters for the cold U-bending process using rotary draw bending, numerical and experimental investigations were conducted to produce U-shaped tubes from long straight SUS304L seamless tubes. 3D finite element simulations were run using ABAQUS Explicit with consideration of the elastic recovery. The process parameters studied were the angular speed, the operation period and the bending angle. Experimental verifications were conducted to insure the suitability of the final U-shaped configurations with respect to both ovality and wall thickness.