• Title/Summary/Keyword: energy and mineral resources

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The Effect of NH3 Concentration during Co-precipitation of Precursors from Leachate of Lithium-ion Battery Positive Electrode Active Materials (리튬이차전지 양극활물질의 암모니아 침출액에서 공침법에 의한 활물질 전구체의 합성에 대한 암모니아 농도의 영향)

  • Park, Sanghyuk;Ku, Heesuk;Lee, Kyoung-Joon;Song, Jun Ho;Kim, Sookyung;Sohn, Jeongsoo;Kwon, Kyungjung
    • Resources Recycling
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    • v.24 no.6
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    • pp.9-16
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    • 2015
  • In a recycling scheme of spent lithium ion batteries, a co-precipitation process for the re-synthesis of precursor is essential after the leaching of lithium ion battery scraps. In this study, the effect of ammonia as impurity during the co-precipitation process was investigated in order to re-synthesize a precursor of Ni-rich cathode active material $LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$ (NCM 622). As ammonia concentration increases from 1 M (the optimum condition for synthesis of the precursors based on 2 M of metal salt solution) to 4 M, the composition of obtained precursors deviates from the designed composition, most notably for Ni. The Ni co-precipitation efficiency gradually decreases from 100% to 87% when the concentration of ammonia solution increases from 1 M to 4 M. Meanwhile, the morphological properties of the obtained precursors such as sphericity, homogeneity and size distribution of particles were also investigated.

Overview of Coffee Waste and Utilization for Biomass Energy Production in Vietnam

  • Thriveni, Thenepalli;Kim, Minsuk;Whan, Ahn Ji
    • Journal of Energy Engineering
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    • v.26 no.1
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    • pp.76-83
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    • 2017
  • In this paper, the carbon resources recycling of the overview of coffee waste generation in Vietnam. Since few years, there has been a significant research studies was done in the areas of coffee waste generation areas and also waste water generation from coffee production. The coffee residue (solid) and waste water (liquid) both are caused the underground water contamination and also soil contamination. These residues contain high organic matter and acid content leads to the severe threat to environment. In second stage of coffee production process, the major solid residue was generated. Various solid residues such as spent coffee grounds, defective coffee beans and coffee husks) pose several environmental concerns and specific problems associated with each type of residue. Due to the unlimited usage of coffee, the waste generation is high. At the same time, some researchers have been investigated the spent coffee wastes are the valuable sources for various valuable compounds. Biodiesel or biomass productions from coffee waste residues are the best available utilization method for preventing the landfill problems of coffee waste residues.

Development of AE/MS monitoring system and its application (AE/MS 모니터링시스템개발과 적용연구)

  • Cheon, Dae-Sung;Jung, Yong-Bok;Park, Chan;Synn, Joong-Ho;Jang, Hyun-Ick
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.199-210
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    • 2008
  • Acoustic emission(AE)/Microseimsic(MS) activities are low-energy seismic events associated with a sudden inelastic deformation such as the sudden movement of existing fractures, the generation of new fractures or the propagation of fractures. These events rapidly increase before major failure and happen within a given rock volume and radiate detectable seismic waves. The main difference between AE and MS signals is that the seismic motion frequencies of AE signals are higher than those of MS signals. As the failure of geotechnical structures usually happens as a high velocity and small displacement, it is not easy to determine the precursor and initiation stress level of failure in displacement detection method. To overcome this problem, AE/MS techniques for detection of structure failure and damage have recently adopt in civil engineering. In this study, AE/MS monitoring system, which consist of sensor, data acquisition and operation program, is constructed with domestic technology. To verify and optimize the developed system, we are now carrying out the field application at an underground research laboratory and the developed AE/MS monitoring will be used in detecting of seismic events with various scales.

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Non-isothermal Behavior of Calcium Carbonate (탄산칼슘의 비등온 열적거동)

  • Sohn, Yong-Un;Lim, Jae-Won;Choi, Good-Sun
    • Journal of Powder Materials
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    • v.16 no.3
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    • pp.167-172
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    • 2009
  • This study has been carried out to investigate the non-isothermal behaviors and kinetic parameter of calcium carbonate by different thermal analysis methods. At the heating rate of $10^{\circ}C$/min, the onset calcination temperature, the peak and final temperatures of calcium carbonate were $612^{\circ}C$, $748^{\circ}C$, and $890^{\circ}C$ respectively. As the heating rate of the calcium carbonate increased from $5^{\circ}C$/min to $20^{\circ}C$/min, the peak temperature increased from $719^{\circ}C$ to $782^{\circ}C$. The activation energies of the calcium carbonate calculated by the methods of Kissinger and Freeman-Carroll were 40.15 kcal/mol and 43.47 kcal/mol, respectively.

Time-lapse Resistivity Investigations for Imaging Subsurface Grout during Ground Stabilization

  • Farooq, Muhammad;Park, Sam-Gyu;Kim, Jung-Ho;Song, Young-Soo
    • 한국지구물리탐사학회:학술대회논문집
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    • 2007.06a
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    • pp.241-244
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    • 2007
  • Cement-grouts are injected into limestone cavities beneath the road in the project area, in order to improve strength and reduce permeability; the extent to which grout has penetrated in cavities need to be monitored in order to determined effectiveness of cement-grout. Geophysical approaches, offer great potential for monitoring the grout injection process in a fast and cost-effective way as well as showing whether the grout has successfully achieved the target. This paper presents the ability of surface electrical resistivity to investigate the verification of the grout placement. In order to image the cement-grout, time-lapse surface electrical resistivity surveys were conducted to compare electrical resistivity images before and after injection. Cement-grout was imaged as anomalies exhibiting low resistivity than the surrounding rocks. In accordance with field monitoring, laboratory study was also designed to monitor the resistivity changes of cement-grout specimens with time-lapse. Time-lapse laboratory measurements indicated that electrical methods are good tool to identify the grouted zone. Pre-and post grouting electrical images showed significant changes in subsurface resistivity at grouted zone. The study showed that electrical resistivity imaging technology can be a useful tool for detecting and evaluating changes in subsurface resistivity due to the injection of the grout.

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Remote monitoring technique for geotechnical structures using acoustic emission (미소파괴음을 이용한 지반구조물 원격계측기술)

  • Cheon, Dae-Sung;Jung, Yong-Bok;Park, Eui-Seob;Park, Chan;Jang, Hyun-Ick
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.10a
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    • pp.946-956
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    • 2008
  • Acoustic emission(AE) is low-energy seismic event associated with a sudden inelastic deformation such as the sudden movement of existing fractures, the generation of new fractures or the propagation of fractures. These events rapidly increase before major failure and happen within a given rock volume and radiate detectable seismic waves. Rock slopes are usually large in scale and there are many discontinuities in rock mass. AE waves are strongly attenuated when they propagate through joints. Thus we should resolve the attenuation problem to monitor large volume. In this study, we developed waveguide which is composed of two different materials, cement mortar and stainless steel rod. And several laboratory tests on developed waveguide are performed to obtain generalized AE parameters to predict the failure stage in rock slope. Comparing field data with experimental data in laboratory tests, failure stage of rock slope can be evaluated. To verify and optimize the developed monitoring method, we are now carrying out the field application at a rock slope.

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A Study of Hypocentral Depth of Pohang Earthquake (포항 지진의 진원 깊이 연구)

  • Chung, Tae Woong;Lee, Youngmin;Iqbal, Muhammad Zafar;Jeong, Jina
    • Geophysics and Geophysical Exploration
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    • v.21 no.2
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    • pp.125-131
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    • 2018
  • 2017 Pohang earthquake (M 5.4) was more disastrous than 2016 Gyeongju earthquake (M 5.8), partly because of its shallow focal depth. However, precise focal depth of Pohang earthquake is still controversial. Close crustal model showed 6 ~ 11.5 km in relocation depth, whereas other models showed almost surface range. Geothermal study indicated temperature of $300^{\circ}C$ at depth of 7.5 km. Related with observations of seismogenic layer, the focal depth of Pohang earthquake seems to be 7 km depth as obtained by close model.

Overview of Gas Hydrates as a Future Energy Source and Their Physical/Chemical Properties (미래 에너지로서 가스 하이드레이트의 개관 및 물리/화학적 특성)

  • Cha, Minjun;Min, Kyoung-Won
    • Journal of the Korean Society of Mineral and Energy Resources Engineers
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    • v.55 no.6
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    • pp.670-687
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    • 2018
  • This paper reviews the structures, physical and chemical properties, origins and global distribution, amount of energy resources, production technologies, and environmental impacts of gas hydrates to understand the gas hydrates as future energy sources. Hydrate structures should be studied to clarify the fundamentals of natural gas hydrates, hydrate distributions, and amount of energy sources in hydrates. Phase equilibria, dissociation enthalpy, thermal conductivity, specific heat, thermal diffusivity, and fluid permeability of gas hydrate systems are important parameters for the the efficient recovery of natural gas from hydrate reservoirs. Depressurization, thermal stimulation, inhibitor injection, and chemical exchange methods can be considered as future technologies to recover the energy sources from natural gas hydrates, but so far depressurization is the only method to have been applied in test productions of both onshore and offshore hydrates. Finally, we discuss the hypotheses of environmental impacts of gas hydrates and their contribution to global warming due to hydrate dissociation.

The Survey on Froth Floatation of Low Grade Copper Ore from the Australia (호주산 저품위 동광의 부유선별에 관한 특성조사)

  • Kim, Joon Soo;Kim, Woo Jin;Hwang, Ha;Kim, Myong Jun;Kim, Wantae
    • Resources Recycling
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    • v.25 no.6
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    • pp.98-104
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    • 2016
  • The purpose of this study is to obtain an optimum condition of the concentrate by floatation using Australian low grade copper ore of suitable particle size by crushing, grinding and sizing. The effect of the dosage of collector, activator, depressant and change of acidity on the floatation was investigated. The floatation conditions comprising of pH 9.0 acidity, 500g/t $CuSO_4{\cdot}5H_2O$ activator, 500g/t K.E.X. collector, 1500g/t $Na_2SO_3$ depressant and 25wt.% plup density were optimized. Grade and recovery of copper in the concentrate obtained by froth floatation under optimum conditions were 4wt.% and 65wt.% respectively.