• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.358-358
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• 2012

The application of BZO (Boron-doped Zinc Oxide) films use as the TCO(Transparent Conductive Oxide) material for display and solar cell industries, where the conductivity of the BZO films plays a critical role for improvement of cell performance. Thin BZO films are deposited on glass substrates by using RF sputter system. Then charging flow rates of O2 gas from zero to 10 sccm, thereby controlling the impurity concentration of BZO. BZO deposited on soda lime glass and RF power was 300 W, frequency was 13.56 MHz, and working pressure was $5.0{\times}10-6$ Torr. The Substrate and glass between distance 200 mm. We measured resistivity, conductivity, mobility by hall measurement system. Optical properties measured by photo voltaic device analysis system. We measured surface build according to oxygen flow rate from XPS (X-ray Photoelectron Spectroscopy) system. The profile of the energy distribution of the electrons emitted from BZO films by the Auger neutralization is measured and rescaled so that Auger self-convolution arises, revealing the detail structure of the valence band. It may be observed coefficient ${\gamma}$ of the secondary electron emission from BZO by using ${\gamma}$-FIB (Gamma-Focused Ion Beam) system. We observed the change in electrical conductivity by correlation of the valence band structure. Therefore one of the key issues in BZO films may be the valence band that detail structure dominates performance of solar cell devices. Demonstrating the secondary electron emission by the Auger neutralization of ions is useful for the determination of the characteristics of BZO films for solar cell and display developments.

• Journal of Environmental Science International
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• v.24 no.10
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• pp.1273-1283
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• 2015

In present study, the temporal characteristics of nine selected volatile organic compounds (VOCs), including four alcohol, 2 aldehyde, and 3 ketone compounds, in high-stories urban apartments over a 2-y period were investigated. The indoor VOC concentrations had generally a decreasing trend over the 2-y follow-up period. For examples, the 2E1H indoor concentration decreased from $10.8{\mu}g/m^3$ for the first two months to $5.1{\mu}g/m^3$ for the last two months. In addition, the DCA and ACT indoor concentrations decreased from 5.0 and $14{\mu}g/m^3$ for the first two months to 2.2 and $6.4{\mu}g/m^3$, respectively, for the last two months. The indoor-to outdoor concentration ratios over the 2-y period were much greater than 1, indicating that indoor VOC concentrations were higher than the outdoor VOC concentrations. Similar to those of the individual VOCs, the indoor-to-outdoor concentration ratios of all three VOC groups were higher than 1 over the 2-y follow-up period, suggesting higher indoor concentrations of the three VOC groups than outdoor concentrations. In consistence with the results of VOC indoor concentrations, the VOC emission rates decreased gradually as time passed, due to the decreased VOC emission strengths of indoor sources. Finally, there was an initial sharp decrease in the indoor VOC concentrations followed by a slower decrease, indicating a multi-exponential decay model for the target VOCs, which was demonstrated by comparison of the residuals and the adjusted coefficient of determination associated with the one and two-exponential fits of each data set.

• Journal of Environmental Science International
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• v.18 no.7
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• pp.747-754
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• 2009

In this study, which aims to estimate the volume of greenhouse gas emitted by road transportation vehicles in Changwon City, the emission rate was calculated on the basis of the actual traffic volume measured at major crossroads and compared with the results obtained from the methodology used to estimate the greenhouse gas emissions of road transportation provided in the IPCC 2006 GL guidelines (Tier 1, Tier 3). Analysis of the results of the comparison showed that the Tier 1 methodology, which was applied in the estimation of the rate of greenhouse gas emissions, carries a high probability of underestimation, while the Tier 3 methodology carries a relatively high probability of overestimation. Therefore, when considering the assignment of permissible rates of emission to local governments, the application of the methodology, i.e. whether one uses Tier 1 or Tier 3, may result in a large difference in the rate of allowable emissions. It is suggested that a method based on the actual volume of traffic would be the most reasonable one with regard to the development of a realistic plan.

• International Journal of Automotive Technology
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• v.6 no.4
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• pp.333-340
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• 2005

In order to better quantify the contribution from nonroad sources to emission inventories, it is important to understand not only the emissions rates of these engines but also activity patterns that can be used to accurately portray their in-use operation. To date, however, very little information is available on the actual activity patterns of nonroad equipment. In this study, a total of 18 pieces of nonroad equipment were instrumented with collected data including intake manifold air pressure (MAP), exhaust temperature and, on a subset of vehicles, engine rpm and throttle position. The equipment included backhoes, compactors, dozers, motor graders, loaders and scrappers used in applications such as landfilling, street maintenance and general roadwork. The activity patterns varied considerably depending on the type of equipment and the application. Daily equipment operating time ranged from less than 30 minutes to more than 8 hours, with landfill equipment having the highest daily use. The number of engine starts per day ranged from 3-11 lover the fleet with an average of 5 starts per day. The average percent idle time for the fleet was approximately $25\%$ with a range from 11 to $65\%$ for individual pieces of equipment. Duty cycles based on exhaust temperature/throttle position profiles were also developed for two graders and one dozer.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.4 no.3
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• pp.697-703
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• 2000

As device dimensions are lastly scaled down, impact ionization(I.I.) events are very important to analyze hot carrier transport in high energy region, and the exact model of impact ionization is demanded on device simulation. We calculate full band model by empirical pseudopotential method and the impact ionization rate is derived from modified Keldysh formula. We calculate impact ionization coefficients by full band Monte Carlo simulator to investigate temperature dependent characteristics of impact ionization for GaAs as a function of field. Resultly impact ionization coefficients are in good agreement with experimental values at look. We how energy is increasing along increasing the field, while energy is decreasing along increasing the temperature since the phonon scattering rates for emission mode are very high at high temperature. The logarithmic fitting function of impact ionization coefficients is described as a second orders function of temperature and field. The residuals of the logarithmic fitting function are mostly within 5%. We Dow, therefore, the logarithm of impact ionization coefficients has quadratic dependence on temperature, and we can save time of calculating the temperature dependent impact ionization coefncients as a function of field.

• Environmental Analysis Health and Toxicology
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• v.25 no.1
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• pp.41-55
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• 2010

The aims of this study were to develop the suitable "system software" in chemical ranking and scoring (CRS) for the food hazardous chemicals associated with environmental emission and to suggest the priority lists of food contamination by environmental-origined pollutants. Study materials were selected with reference to the priority pollutants list for environment and food management from domestic and foreign research and the number of study materials is 103 pollutants (18 heavy metals, 10 PBTs, 10 EDs, and 65 organic compounds). The Food-CRS-Korea system consisted of the environmental fate model via multimedia, transfer environment to food model, and health risk assessment by contaminated food intake. We have established that health risks of excess cancer risks, hazard quotients (HQs) by chronic toxicity and HQs by reproductive toxicity convert to score, respectively. The creditable scoring system was designed to consider uncertainty of quantitative risk assessment based on VOI (Value-Of-Information). The predictability of the Food-CRS-Korea model was evaluated by comparing the presumable values and the measured ones of the environmental media and foodstuffs. The priority lists based on emissions with background-level-correction are 15 pollutants such as arsenic, cadmium, and etc. The priority lists based on environmental monitoring date are 17 pollutants including DEHP, TCDD, and so on. Consequently, we suggested the priority lists of 13 pollutants by considering the several emission and exposure scenarios. According to the Food-CRS-Korea system, arsenics, cadmium, chromes, DEHP, leads, and nickels have high health risk rates and reliable grades.

• Journal of Korean Society for Atmospheric Environment
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• v.23 no.2
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• pp.191-202
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• 2007

We developed an in-situ analyzer to understand the HONO levels in indoor environments. The in-situ measurement system utilizes a diffusion scrubber and luminol chemiluminescence to measure the HONO concentration with time resolution of 4-minute. Concentrations of NO, $NO_{2}$, and HONO were determined at an indoor air of an apartment for 9 days using the developed in-situ analyzer. Indoor HONO concentrations were highly elevated when a gas range was operated. Enhancements of the indoor NO, $NO_{2}$, and HONO concentrations during combustion indicate that the observed indoor HONO was formed by direct emission. In addition to the direct emission, the indoor HONO was partially generated from heterogeneous reactions of $NO_{2}$ on indoor surfaces, which was supported by strong relationships between peak NO, $NO_{2}$, and HONO concentrations, high HONO/$NO_{2}$ ratio and a weak correlation between NO and HONO concentrations. Additionally, three combustion experiments during the whole measurement period were performed to investigate the effects of unvented and vented gas burning on the HONO, NO, and $NO_{2}$ concentrations and their decay. The decay rate of the HONO concentration was significantly less than the NO and $NO_{2}$ decay rates for all the experiments, indicating that the lifetimes of trace nitrogen species in indoor environment varied in the order approximately HONO>$NO_{2}$>NO.

• Journal of the Korean Society of Combustion
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• v.7 no.1
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• pp.15-22
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• 2002

Flame spread experiments of a fuel droplet array were performed using a microgravity environment. N-decane, 1-octadecene, and the blends (50% : 50% vol.) of these fuels were used and the experiments were conducted at pressures up to 5.0 MPa, which are over the critical pressure of these fuels. Observations of the flame spread phenomenon were conducted for OH radical emission images recorded using a high-speed video camera. The flame spread rates were calculated based on the time history of the spreading forehead of the OH emission images. The flame spread rate of the n-decane droplet-array decreased with pressure and had its minimum at a pressure around half of the critical pressure and then increased again with pressure. It had its maximum at a pressure over the critical pressure and then decreased gradually. The pressure dependence of flame spread rate of 1-octadecene were similar to those of n-decan, but the magnitude of the spread rate was much smaller than that of n-decane. The variation of the flame spread for the blended fuel was similar to that of n-decane in the pressure range from atmospheric pressure to near the critical pressure of the blended fuel. When the pressure increased further, it approached to that of 1-octadecene. Numerically estimated gas-liquid equilibrium states proved that almost all the fuel gas which evaporated from the droplet at ordinary pressure consisted of n-decane whereas near and over the critical pressure, the composition of the fuel gas was almost the same as that of the liquid phase, so that the effects of 1-octadecene on the flame spread rate was significant.

• Journal of Korean Society of Water and Wastewater
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• v.23 no.5
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• pp.547-555
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• 2009

The objectives of this research were focused on the effects of various operating parameters on nitrous oxide emission such as C/N ratio, ammonia concentration and HRT in the hybrid and suspension reactors. With the decreasing of C/N ratios, $N_2O$ emission rates in the both processes were increased because organic carbon source for denitrification was depleted. In case of biofilm reactor operated using medium, $N_2O$ release from the nitrification was not affected by the variation of ammonia concentration. But in the suspension reactor, $N_2O$ production from the nitrification was rapidly increased with the increase of ammonia. Nitrite accumulation caused by undesirable nitrification conditions could be a important reason for the increase in the $N_2O$ production from the aerobic reactor. And rapid increase in $N_2O$ production was reflected by the decrease of HRT, similar to the results observed in the results of ammonia loading changes. So it could be said that it is very important to put in consideration both its optimum conditions for wastewater treatment efficiency and suitable conditions for $N_2O$ diminish, simultaneously, in order to development an eco-friendly and advanced wastewater treatment, especially in BNR process.

• KIEAE Journal
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• v.14 no.2
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• pp.37-46
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• 2014

University buildings are energy-guzzling facility that consume more than 10,000TOE within a campus annually. Even the consumption is on an upswing trend. Behind such high consumption are there cheap power rates for education facility, lack of high-efficiency equipment and ever-increasing use of various information equipment. Being keenly aware that greenhouse gas emission increases due to such rise of energy consumption, the present study carried out a case study. In the case study, the study chose the buildings of E university from top 10 universities that consume energy most in Seoul and examined the current status of their energy consumption and greenhouse gas emission. And then it set the reduction target of greenhouse gas by year. Putting aside a middle and long-termed strategy for later endeavor, it first established the 1st year's implementation plan (2014) for energy saving and greenhouse gas reduction with limited budget and according to greenhouse gas reduction target. The plan is specified as follows. Targets for energy saving are mainly divided into two sectors: machine equipment and electric equipment. 7 ideas were proposed. Three ideas to improve machine equipment are to replace with high-efficiency boilers and chillers and to adjust the position of the cooling tower. By doing so, it was estimated that energy could be saved by 176.34TOE in total and greenhouse gas could be reduced by 370.771t$CO_2$-eq. Four ideas to improve electric equipment include the replacement with LED lights, LED emergency lights and high-efficiency motors and the installation of motion sensors. It was calculated that such replacement could conserve 1,076.08TOE (electric energy) and reduce 2,181.420t$CO_2$-eq (greenhouse gas).