• Journal of Environmental Health Sciences
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• v.42 no.4
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• pp.246-254
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• 2016

Objectives: This study evaluated the odor emission characteristics from fundamental environmental facilities at an industrial complex area in Daegu City. Methods: The odor samples were collected from May 2015 to January 2016 and were analyzed for specified offensive odor substances. The odor quotient and the odor contribution was calculated. Results: Ammonia was detected in all samples monitoring specified odor compounds, followed by hydrogen sulfide and acetaldehyde. According to contribution analysis, hydrogen sulfide shows the highest contribution in all facilities. At wastewater treatment plants A and B and sewage treatment plant F, it was followed by acetaldehyde. At wastewater treatment plant C, it was followed by imethyl sulfide. Conclusion: The major component of odor can be determined by evaluating the degree of contribution to the odor intensity rather than the concentration of the individual odor components. To increase the effectiveness of odor reduction, policies focused on materials with a high odor contribution are needed rather than focusing on high-concentration odor compounds.

• Journal of Environmental Health Sciences
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• v.43 no.4
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• pp.314-323
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• 2017

Objectives: This study evaluated the odor emission characteristics from a wastewater treatment plant in an industrial complex area in Daegu City. Methods: Odor samples were collected from March 2016 to December 2016 and were analyzed for specified offensive odor substances. The odor quotient and the odor contribution was calculated. Results: Ammonia, hydrogen sulfide, acetaldehyde, and toluene were detected in all samples for monitoring specified odor compounds. The result of contribution analysis is that hydrogen sulfide had the highest contribution in all processes, followed by acetaldehyde. Conclusion: The major components of odor can be determined by evaluating the degree of contribution to the odor intensity and the concentration of the individual odor component. To increase the effectiveness of odor reduction, rather than addressing high-concentration odor compounds, policies focused on materials with a high odor contribution are necessary.

• Journal of Environmental Health Sciences
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• v.44 no.2
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• pp.178-187
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• 2018

Objectives: This study evaluated the odor emission characteristics from a sewage treatment plant near an industrial complex area in Daegu City. Methods: Odor samples were collected from March 2017 to December 2017 and analyzed for specified offensive odor substances. The odor quotient and the odor contribution were calculated. Results: Ammonia, methyl mercaptane, hydrogen sulfide, dimethyl sulfide, acetaldehyde, propionylaldehyde, toluene, xylene, and methylethylketone were detected in all samples for monitoring the specified odor compounds. The result of contribution analysis is that hydrogen sulfide made the highest contribution in all processes, followed by acetaldehyde. Conclusion: The major components of odor can be determined by evaluating their degree of contribution to the odor intensity and the concentration of the individual odor component. To increase the effectiveness of odor reduction, rather than addressing high-concentration odor compounds, policies focused on materials with a high odor contribution are necessary.

• Journal of Radiopharmaceuticals and Molecular Probes
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• v.8 no.2
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• pp.63-70
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• 2022

The development of myocardial perfusion imaging (MPI) agents has been motivated because coronary artery disease has been one of the leading causes of death worldwide since the 1960s. Several positron emission tomography (PET) MPI agents were developed, and ¹⁸F-labeled phosphonium cations were reported actively among them. In this study, we synthesized novel ¹⁸F-labeled phosphonium cations, (5-[¹⁸F]fluoropentyl)diphenyl(pyridin-2-yl)phosphonium and (2-(2-[¹⁸F]fluoroethoxy)ethyl)diphenyl(pyridin-2-yl)phosphonium, and evaluated potential as MPI agents. Two labeled compounds were synthesized via nucleophilic substitution reactions of ¹⁸F-fluoride with the appropriate tosylate precursor in the presence of Kryptofix 2.2.2 and K₂CO₃. MicroPET studies were performed in normal rats to evaluate in vivo distribution of radiolabeled phosphonium cations for 60 min. The radiolabeled compounds were synthesized with 5%-10% yield. The radiochemical purity of labeled compounds was > 98% by analytical HPLC, and the specific activity was > 11.8 GBq/µmol. The result of microPET studies of these labeled compounds in rats showed intense uptake in the myocardium at 30 and 60 min. The results suggest that these ¹⁸F-labeled novel phosphonium cations would have potential as promising candidates for myocardial perfusion imaging.

• Journal of Environmental Impact Assessment
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• v.21 no.3
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• pp.353-365
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• 2012

This study is understanding characteristics and analyzing contributions of the odor causing compounds of complex-odor & major specified odor materials, and contribution analysis, caused pre-treatment facilities(input and storage) and post-treatment facilities(heating and drying). The target of this study is feeds-production-facilities, located in Seoul. The averaged complex-odor compounds on the boundary line is 21 times higher, and it is 15 times higher than emission standards. In cracking&collection(pre-treatment facilities), the concentration of compounds is 4,881 times, 2,080 times in drying, and 1,442 times in putting&storing facilities. Ammonia occupies the largest portion of the results of monitoring specified odor compounds in input&storage facilities, followed Acetaldehyde > Hydrogen sulfide > Methyl mercaptan. In cracking&collection, Ammonia also occupies most of odor compounds, followed Methyl mercaptan > Acetaldehyde > Dimethyl disulfide > Dimethyl sulfide > Hydrogen sulfide. Acetaldehyde > Methyl mercaptan in drying facilities. On the boundary line, however, the concentration of specified odor compounds stays below emission standards. The result of contribution analysis is that methyl mercaptan has the highest contribution in input & storage, as well as cracking&collection facilities, followed Acetaldehyde > Hydrogen sulfide > Dimethyl sulfide > Dimethyl disulfide. In the drying facilities, the contribution shows Methyl mercaptan > Acetaldehyde > i-Valeraldehyde and Butyraldehyde. Therefore, to decrease odor in foodwaste treatment facilities, proper prevention facilities need to be installed and operated, according to characteristics of individual odor compounds, based on monitored data.

• Journal of Korean Society on Water Environment
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• v.31 no.1
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• pp.29-34
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• 2015

The aim of this study is to understand the limitation of organic pollutant indexes ($BOD_5$, $COD_{Mn}$, $COD_{Cr}$) and estimate to set the TOC standard by comparing oxidation rates of $BOD_5$, $COD_{Mn}$, $COD_{Cr}$ and TOC based on the 487 organic compounds and 11 effluents from industrial wastewater containing various and unknown organic compounds. The range of ratio of theoretical oxygen demand (ThOD) to theoretical organic carbon (TOCt) was 0.00~5.33 and average ratio of classes of organic compounds was 2.68~3.70. According to classes of organic compounds, the average ratio of $O_2/C$ was 1.2 (range : 1.02~1.39). The order of oxidation rate for 15 organic compounds was TOC (90.7%) > $COD_{Cr}$ (88.8%) > $BOD_5$ (54.4%) > $COD_{Mn}$ (30.8%) indicating the lower oxidation rate of $BOD_5$ and COD compared with TOC. The ranking for average oxidation rate was $COD_{Cr}$ > $COD_{Mn}$ > $BOD_5$ indicating that $BOD_5$, $COD_{Mn}$ could be underestimated comparing with ThOD of organic compounds in case of industrial wastewater containing high concentration of refractory organic compounds. Most of the relationships between organic pollutant indexes and TOC were higher than 0.9. The ratio of TOC to organic compound indexes decreased in the order : $COD_{Cr}$ (3.4) > $COD_{Mn}$ > (1.9) > $BOD_5$ (0.7).

• Journal of the Korean Wood Science and Technology
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• v.37 no.1
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• pp.12-18
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• 2009

This study was attempted to investigate indoor air quality of a wooden house. Emission characteristics of carbonyl compounds from indoors whose interiors were finished using ecofriendly materials were detected. From the results of the examination, the carbonyl compounds mostly consisted of formaldehyde, acetaldehyde, and hexaldehyde. Especially, formaldehyde accounted for the largest portion of the compounds at 25.6~30.5%. All the rooms except for R2-2 contained formaldehyde less than criteria of indoor air quality of newly-constructed houses. In addition, all the rooms except for room R1-3, contained acetaldehyde more than the level of $48{\mu}g/m^3$ recommended by Japan's Ministry of Health, Labour and Welfare. As a results of the different wall covering, the room R1-1 of Hwangto emitted relatively higher levels of carbonyl compounds than the room R2-1 of phytoncide. In addition, the room R2-2 of the bamboo charcoal panels emitted more carbonyl compounds than the room R1-2. The living room R1-3 of Japanese cypress (Cryptomeria Japonica) emitted lower levels of carbonyl compounds than other rooms.

• Journal of Environmental Science International
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• v.24 no.2
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• pp.207-219
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• 2015

The purpose of this study is to show the geographical distribution and the temporal variation of the emission amount of biogenic volatile organic compounds(BVOCs) emanated from forests at Jeju Island. The total emission amount of BVOCs calculated by using the CORINAIR Methodology is $3612ton\;yr^{-1}$ at Jeju Island. More than half of BVOCs emissions is come from coniferous forest, and 45 per cent from broad leaved forest. The others is attributed to grassland. Of total emission of BVOCs, isoprene accounts for 28 per cent, monoterpene for 32 per cent, and other VOCs for about 40 percent, respectively. It can be shown that $3000{\sim}10000kg\;yr^{-1}$ of BVOCs is emitted at the zone with dense forest from an altitude of 500 m to the top of Mt. Halla, and less than $1500kg\;yr^{-1}$ at the zone an altitude of below 500 meters. The monoterpene emission is more than $1500kg\;yr^{-1}$ due to the existence of a colony of Abies koreana at the place with more than 1500 meters and a community of Pinus thunbergii and Cryptomeria japonica at the elevation of 500~700 m. In the case of isoprene emission, there is $1500{\sim}3000kg\;yr^{-1}$ at the zone of an elevation from 700 m to 1500 m due to dense broad leaved forest and very little of its emission at an elevation of more than 1500 meters because there is hardly broad leaved trees grown. In this study, emission of BVOCs according to the altitude above sea level is estimated under the situation of lack of the data for broad leaved tree. More detailed data and information for the distribution of broad leaved trees are needed in order to calculate more realistic BVOC emission.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.18 no.6
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• pp.468-476
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• 2006

The paper deals with the numerical analysis of contaminants emission from the material affected by temperature variation in floor heating system. Considering mass transfer and heat transfer theories, a computer program for the analysis of VOCs emission was made. To demonstrate the accuracy of the numerical solution, the prediction results and the measured data were compared. Using this program, emission rates of the materials in the bakeout space and the no bake-out space were compared to estimate the variation of emission rate.

• Bulletin of the Korean Chemical Society
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• v.25 no.1
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• pp.73-78
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• 2004

A highly sensitive detecting method has been developed for determining part per billion of sulfur in $H_2S$/Ar plasma. The method is based on the excitation of Ar/$H_2S\;or\;Ar/H_2S/O_2$ mixture in hollow cathode glow discharge sustained by radiofrequency (RF) or 60 Hz AC power and the spectroscopic measurement of the intensity of emission lines from electronically excited $S_2^*\;or\;SO_2^*$ species, respectively. The RF or AC power needed for the excitation did not exceed 30 W at a gas pressure maintained at several mbar. The emission intensity from the $SO_2^*$ species showed excellent linear response to the sulfur concentration ranging from 5 ppbv, which correspond to S/N = 5, to 500 ppbv. But the intensity from the $S_2^*$ species showed a linear response to the $H_2S$ only at low flow rate under 20 sccm (mL/min) of the sample gas. Separate experiments using $SO_2$ gas as the source of sulfur demonstrated that the presence of $O_2$ in the argon plasma is essential for obtaining prominent $SO_2^*$ emission lines.