• Title/Summary/Keyword: emission 파장

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Determination of L-Dopa by Spectrofluorimetry Using Co-fluorescence Enhancer (보조 형광증가제를 이용한 L-Dopa의 형광분광법적 정량)

  • Lee, Sang Hak;Ahn, Jung Mi
    • Journal of the Korean Chemical Society
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    • v.44 no.6
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    • pp.541-546
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    • 2000
  • Methods to determine L-dopa(L-3,4-dihydroxyphenylalanine) in aqueous solution by spectrofluorimetry based upon the ligand sensitized luminescence of Tb(III) ion L-dopa complex have been studied. Tb(III) ion and Lu(III) ion were used as ligand sensitized fluorescencer and co-fluorescence enhancer, respectively. The effects of excitation wavelength, pH, concentration of Tb(III) ion, concentration of Lu(III) ion and emission wavelength on the fluorescence intensity were investigated. The fluorescence intensity of the Tb(III) ion L-dopa complex was further increased with addition of Lu(III) ion. The calibration curve for L-dopa was linear over the range from 5.0 ${\times}$ $10^{-7}$ M to 1.0${\times}$ $10^{-4}$ M and the detection limit was 4.0 ${\times}$ $10^{-8}$ M under the optimal experimental conditions of 300 nm, 8.0, 1.0 ${\times}$ $10^{-4}$ M and 545 nm for excitation wavelength, pH, concentration of Tb(III) ion and emission wavelength, respectively. When Lu(III) ion was added to Tb(Ⅲ) ion L-dopa complex, the concentration range of linear response and detection limit were 1.0${\times}$$10^{-8}$ M to 2.0 ${\times}$ $10^{-4}$ M and 1.0 ${\times}$ $10^{-9}$ M, respectively under the optimal experimental conditions of 300 nm, 8.5, 1.0 ${\times}$ $10^{-5}$ M, 1.0 ${\times}$ $10^{-5}$ M, 545 nm for excitation wavelength, pH, concentration of Tb(III) ion, concentration of Lu(III) ion and emission wavelength, respectively.

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Nonlinearity of semiconductor optical amplifier and gain-clamping effects of Iaser-injected semiconductor optical amplifier in wavelength division mulitiplexing (파장 다중 광통신에서의 반도체 광증폭기의 비선형성과 연속파동 레이저가 입사된 반도체 광증폭기의 이득고정 효과)

  • 김동철;유건호;김형문;주흥로;한선규;주관종
    • Korean Journal of Optics and Photonics
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    • v.11 no.1
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    • pp.37-42
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    • 2000
  • We have numerically solved rate-equations of semiconductor optical amplifier (SOA) to understand the characteristics of SOA. The rate-equations we have used can describe injection carrier density, amplified spontaneous emission and signal photon density in spatial and time domain by dividing the cavity into multi-section. We have investigated injection carrier density, amplified spontaneous emission and signal photon density as a function of position and time in the case of single channel input in the form of square pulse. Also we have analyzed the non-linear phenomena of SOA in the case of injecting multi-channel wavelengths as in WDM. Intermodulation distortion (IMD) caused by beat among channels has significant effects on the signal distortion as the channel spacing becomes narrower, and channel crosstalk becomes larger as the power of signals increases. In the case of the injection of another CW laser whose wavelength is far enough from the signal wavelengths, the crosstalk and the output signal distortion can be significantly reduced. duced.

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Controlling the emission wavelength of self-assembled InAs quantum dots (자발형성 InAs 양자점의 발광파장 변조)

  • 김진수;이진홍;홍성의;곽호상;한원석;김종희;오대곤
    • Proceedings of the Optical Society of Korea Conference
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    • 2003.02a
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    • pp.152-153
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    • 2003
  • 최근 양자점 (Quantum Dot-QD)에 대한 관심이 기초 물리학뿐만 아니라 광전소자 응용 측면에서 많은 주목을 끌고 있다. 특히, 자발 형성방법으로 성장시킨 양자점 (Self-assembled QD)을 이용하여 Laser Diode와 같은 광소자에 응용한 결과가 발표되고 있다. 이러한 자발형성 방법으로 성장한 양자점을 광통신에 응용하기 위해서는 발광파장을 제어할 필요성이 있다. 따라서 본 연구에서는 단거리 광통신에 응용 될 수 있는 1.3 $\mu$m 영역과 장거리 광통신에 사용하는 1.55 $\mu$m 영역으로 InAs 양자점의 발광 파장을 변조한 결과에 대하여 분석하였다. (중략)

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Qualitative Analysis of the Component Materials of Nuclear Power Plant Using Time-Resolved Laser Induced Breakdown Spectroscopy (시간분해 레이저 유도 파열 분광분석에 의한 원자력발전소 계통재질의 성분 정성분석)

  • Chung, Kun-Ho;Cho, Yeong-Hyun;Lee, Wanno;Choi, Geun-Sik;Lee, Chang-Woo
    • Analytical Science and Technology
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    • v.17 no.5
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    • pp.416-422
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    • 2004
  • Time-resolved laser induced breakdown spectroscopy (TRELIBS) has been developed and applied to the qualitative analysis of the component materials of nuclear power plant. The alloy samples used in this work were carbon steels (A106 Gr. B; A336 P11; A335 P22), stainless steels (type 304; type 316) and inconel alloys (Inconel 600; Inconel 690; Inconel 800). Carbon steels can be individually distinguished by the intensity ratio of chromium to iron and molybdenum to iron emission lines observed at the wavelength raging from 485 to 575 nm. Type 316 stainless steel can be easily differentiated from type 304 by identification of the molybdenum emission lines at an emission wavelength ranging from 485 to 575 nm: type 304 does not give any molybdenum emission lines, but type 316 does. The inconel alloys can be individually distinguished by the intensity ratio of Cr/Fe and Ni/Fe emission lines at the wavelength raging from 420 to 510 nm. TRELIBS has been proved to be a powerful analytical technique for direct analysis of alloys due to its non-destructivity and simplicity.

Synthesis of long afterglow phosphor SrAl2O4 : Eu+2,Dy+3 by skull melting method (스컬용융법에 의한 SrAl2O4 : Eu+2,Dy+3 축광성 형광체 합성)

  • Ryu, Chang-Min;Seok, Jeong-Won
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.1
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    • pp.42-46
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    • 2017
  • $SrAl_2O_4$ : $Eu^{2+}$,$Dy^{3+}$ phosphorescent phosphors were synthesized by skull melting method. The molar ratio of oxides in the phosphors synthesized by the skull melting technique was $SrCO_3$ : $Al(OH)_3$ : $Eu_2O_3$ : $Dy_2O_3$= 1 : 2 : 0.015 : 0.02. Crystal structure and surface morphology were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis. Optical properties of the synthesized $SrAl_2O_4$ : $Eu^{2+}$,$Dy^{3+}$ were measured by photoluminescence (PL) spectrometer for in-depth study on the excitation, emission and afterglow properties. From the PL measurements, it was found that excitation occurred in the wavelength range from 300 to 420 nm with peak position at 360 nm. The emission spectrum showed a broad curve in the wavelength from 450 to 600 nm with peak position at 530 nm. $SrAl_2O_4$ : $Eu^{2+}$,$Dy^{3+}$ phosphors exhibited afterglow properties with emission that lasted for a long period.

Photoluminescence Properties of Novel $Mg_{2}SnO_{4}:Mn$ Phosphor (새로운 $Mg_{2}SnO_{4}:Mn$ 형광체의 광 발광 특성)

  • Kim, Kyung-Nam;Jung, Ha-Kyun;Park, Hee-Dong;Kim, Do-Jin
    • Journal of the Korean Ceramic Society
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    • v.38 no.9
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    • pp.817-821
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    • 2001
  • A new $Mg_{2-x}MN_xSnO_4$ phosphor with an inverse spinel structure was synthesized by the solid-state reaction technique. The photoluminescence properties of the $Mg_2SnO_4$:Mn phosphors were investigated under 147nm -vacuum ultraviolet ray excitation. The Mn-doped $Mg_2SnO_4$ phosphor exhibited high emission intensity with the spectrum centered at 500nm wavelength. It was explained that the green emission in $Mg_2SnO_4$:Mn phosphor has originated from energy transfer from $^4T_1$ to $^6A_1$ of $Mn^{2+}$ ion at tetrahedral site of the spinel structure. The $Mn^{2+}$ ion concentration exhibiting the maximum emission intensity under the excitation of 147nm-vacuum ultraviolet ray was 0.25mol%. And the decay time of the phosphor was shorter than 10ms.

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Measurement of Fluorescence Signal Strength of NO Particle Using ICCD (ICCD를 이용한 NO입자의 형광신호강도 측정)

  • 전용우;박원주;이광식;이홍식
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.15 no.4
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    • pp.23-30
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    • 2001
  • In this paper, the discharge image of NO particles wire-cylinder type electrode in the discharge reactor where AC dielectric barrier type corona discharge occurred and horizontal and vertical signal intensity at each flourescence emission during discharge and the horizontal and vertical signal strength of NO particles at flourescence emission wavelength band[236[nm], 247[nm]], were measured were measured by ICCD Camera. In addition discharge images and signal intensities in accordance with discharge time were measured to figure out the discharge mechanism. It was found that the strongest horizontal and vertical signal intensity of NO particles were observed at 247[nm] band, but no big difference in the horizontal and vertical signal intensity in accordance with discharge time was seen. In particular, the phenomenon image occuring inside the discharge reactor and wavelength ware able to be carried based on the measured data.

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Electrical and Optical Characteristics of Top-emission OLED (전면 발광 OLED의 전기 광학적 특성)

  • Shin, Eun-Chul;Ahn, Hui-Chul;Han, Won-Geun;Jang, Kyung-Uk;Choi, Seong-Jae;Lee, Ho-Sik;Song, Min-Jong;Kim, Tae-Wan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04b
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    • pp.22-23
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    • 2008
  • 본 연구에서는 전면 유기 발광소자(TE-OLED)를 제작하여 전기 광학적 특성을 연구하였다. 전면 발광 OLED의 투명 전극으로 사용된 Al과 Ag의 박막 두께에 따른 투과율과 면저항값은 다음과 같이 나타났다. 파장 520nm의 기준으로 Al 금속 박막의 두께가 10nm 이하여야 50% 투과율을 보였고, 반면 Ag는 25nm 이하로 나타났다. 면저항값은 박막두께 20nm 기준으로 Al은 약 $40\Omega/\square$, Ag는 $10\Omega/\square$이하로 나타났다. 전면발광 방식의 시야각에 따른 빛의 세기는 cos $60^{\circ}$ 일 때 0.1로, TE-OLED는 시야각이 증가하였을 때 현저히 감소되는 것을 볼 수 있다. TE-OLED의 시야각의 증가에 따른 EL-peak 또한 약 520nm의 파장대에서 약 500nm으로 변화하였다. 전면 발광 방식의 반폭치(FWHM)는 배면 발광 방식 보다 약 32nm정도 좁게 나타났다.

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