• Title/Summary/Keyword: elemental analysis

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Characteristics of Laser-Induced Breakdown Spectroscopy (LIBS) at Space Environment for Space Resources Exploration (우주 자원 탐사를 위한 레이저 유도 플라즈마 분광분석법의 우주 환경에서의 특성 분석)

  • Choi, Soo-Jin;Yoh, Jai-Ick
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.40 no.4
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    • pp.346-353
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    • 2012
  • The Laser-Induced Breakdown Spectroscopy (LIBS) has great advantages as an analytical technique, namely real-time analysis without sample preparation, ideal for mobile chemical sensor for space exploration. The LIBS plasma characteristics are strongly dependent on the surrounding pressure. In this study, seven types of target (C, Ti, Ni, Cu, Sn, Al, Zn) were investigated for their elemental lifetime. The target was located in vacuum chamber which has the pressure range of 760 to $10^{-5}$ torr. As the pressure is decreased, the elemental lifetimes of carbon and titanium declined, while all other targets showed increased lifetimes until reaching 1 torr and declined with continued pressure decrease. The boiling point and electronegativity amongst the physicochemical properties of the samples are used to explain this peculiarity.

A Comparative Study on the REV, non-REV and Joint Network Methods for Analysis of Groundwater Flow in Jointed Rock Masses (절리암반내 지하수 유동해석을 위한 대표체적법, 비대표체적법 및 절리망 해석법의 비교 연구)

  • 문현구
    • Journal of the Korean Geotechnical Society
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    • v.15 no.5
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    • pp.217-228
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    • 1999
  • The three methods of analysis (i) REV(representative elemental volume), (ii) non-REV and (iii) joint network analysis are introduced in this paper to analyze the groundwater flow in jointed rock mass and the inflow into underground excavations. The results from those methods are compared one another to reveal their characteristics by varying the number of joints and the diameter of the opening. The pre-processor, the so-called sequential analysis, is introduced to predict the equivalent hydraulic conductivity of a jointed rock mass having a number of intersecting joints. Using the finite element mesh, joint map and sequential analysis, the equivalent hydraulic conductivities are calculated for all 445 elements. The hydraulic inhomogeneity and the determination of the representative properties of jointed rock masses are discussed. In the REV analysis where the entire rock mass is homogenized through the representative properties, the inflow is increased regularly and consistently by increasing the joint density, the opening size and the conductivity contrast value. Though the non-REV analysis showed irregular variation of the inflow due to the local inhomogeneity allowed to individual elements, the inflow approached the REV results as the characteristic length increases. The joint network analysis showed the most sensitive reaction to the joint density, the opening size and the presence of the network crossing the opening. The reliability of the network analysis depends on the geometric data of individual joints. In view of the limited field data on joint geometry and possible uncertainty the REV and non-REV methods are considered more practical and rational than the joint network analysis.

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PIXE Analysis of Aerosol Particles - Preparation of Standard Samples and Calibration Test - (PIXE 분석에 의한 대기에어로졸의 원소분석 -표준시료의 작성 및 정량화-)

  • 崔琴簒
    • Journal of Korean Society for Atmospheric Environment
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    • v.7 no.2
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    • pp.114-118
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    • 1991
  • Particle Induce X-Ray Emission (PIXE) analysis is one of the most useful methods which can determine the elemental concentration of aerosol particles in nano-gram range. The main purpose of this paper is to establish the measurement system and the procedure of PIXE analysis. The standard samples were prepared to calibrate the PIXE analysis by three different techniques. The linear relationships between the peak counts from PIXE spectra and the mass density from RBS spectra were obtained for each standardized element under the applied measurment geometry and conditions. The sensitivity curves for PIXE analysis were determined from these relationships.

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Oxidative Stabilization Behaviors of Petroleum-based Isotropic Pitch Fiber Spun by Melt-blown Method

  • Kim, Chan;Lee, Su-Hyun;Kim, Young-Min;Yang, Kap-Seung
    • Carbon letters
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    • v.2 no.3_4
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    • pp.170-175
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    • 2001
  • A petroleum-based isotropic pitch fiber spun by melt-blown method was oxidized in air flow at various conditions. The oxidized pitch fiber obtained was tested for its infusibility and its elemental composition during the process of stabilization. The structural changes were traced by using solvent solubility, FT-IR spectroscopy, and elemental analysis. The samples showed a gradual increase in weight with increasing the oxidization temperature. The weight gain of sample oxidized at $320^{\circ}C$ for 10 min was about 4.5%. The concentration of the pyridine and toluene soluble fraction decreased with an increase in stabilization temperatures. The oxygen uptaken in the stabilization process converted aliphatic side chains into the carbonyl groups. As stabilization proceeded, the more ether and carboxylic acid groups were formed through the oxidations of aldehyde and primary alcohol, and then the carboxylic acid was dehydrated to be aromatic anhydride.

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기획단계에서의 최적 개산견적산정의 방법론 고찰

  • Kim Chan-Joong
    • Proceedings of the Korean Institute Of Construction Engineering and Management
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    • autumn
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    • pp.120-125
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    • 2003
  • The estimated construction costs derived at the Planning stage of a project are utilized as important data determining the feasibility of overall project. Therefore the clients usually expect to have estimations of the construction cost as precise as possible and there has been extensive studies carried out by the cost specialists worldwide to satisfy this client's specific need whereas the local estimators still heavily rely on producing quantities and detail quotations only. This paper is to introduce a case study where elemental/functional area cost analysis is incorporated into a database system for the improved accuracy in cost estimations.

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Analysis of Image Visibility in Projection-type Integral Imaging System without Diffuser

  • Park, Soon-Gi;Song, Byoung-Sub;Min, Sung-Wook
    • Journal of the Optical Society of Korea
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    • v.14 no.2
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    • pp.121-126
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    • 2010
  • We analyze image visibility of a projection-type integral imaging system without diffuser, in terms of the fill factor, which is determined by the relationship between the exit pupil of the projection system and the size and the focal length of the elemental lens. High fill factor is a requirement for good visibility. Moreover, for psychological reasons, for the same fill factor, better visibility is accomplished using a relatively small elemental lens. In this paper, we study image visibility through basic experiments and results.

A Study on the Calibration Techniques for Thermopile Pyranometer (일사계 교정기법에 관한 연구)

  • Jo, Dok-Ki;Kang, Yong-Heack
    • 한국태양에너지학회:학술대회논문집
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    • 2008.11a
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    • pp.161-166
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    • 2008
  • The major purpose of this paper is to develop an uncertainty estimate for the calibration of thermopile instruments used to measure solar radiation parameters. We briefly describe the solar radiation parameters most often measured, instrumentation, reference standards, and calibration techniques. The bulk of the paper describes elemental sources of error and their magnitude. We then apply a standard error analysis methodology to combine these elemental error estimates into a statement of total uncertainty for the instrument calibration factor. Our results allow one to evaluate the accuracy of a radiometric measurement using thermopile instrumentation in the light of the application, such as engineering test evaluation or for validation of theoretical models.

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SIMS Investigation of Black Cr Solar Selective Coatings (Black Cr 태양 선택흡수막의 SIMS 연구)

  • Lee, Kil-Dong
    • Journal of the Korean Solar Energy Society
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    • v.34 no.4
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    • pp.39-44
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    • 2014
  • The elemental composition of electro-deposited black Cr solar selective coatings before and after heating in air by using secondary ion mass spectrometry (SIMS) was investigated for optical property analysis. In addition, black Cr selective coating exposed by solar radiation for 5 months was compared with heated sample. SIMS investigation shows that $OH^+$ bearing ions were related to a near surface region of CrOH and CrO compound. The optical degradation of this coating after heating at $500^{\circ}C$ reveals that diffusion of the Cu and Ni elements in substrate material, the chemical interactions adjacent to the interface, and the interface width broadening.

Closed-Die Forging Analysis of Clutch Teeth Using An Upper Bound Elemental Technique (상계요소법에 의한 클러치 치형의 밀폐단조해석)

  • 양정호;이상태;김용조
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1996.11a
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    • pp.134-138
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    • 1996
  • A simple kinematically admissible velocity field for closed-die forging of clutch teeth is analysed which takes account of the profiled teeth chosen kinematically by approximating these as straight taper teeth. The upper bound load and the deformed configurations are predicted by the velocity field at varying punch movements considering differing frictional factors. Experiments were carried out using a model material of plasticine at room temperature where talcum powder was used as a lubricant. The theoretical predictions of the forging load and the relative pressures are found to be in reasonably good agreement with the experimental results.

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Closed-Die Forging Analysis of Spling-LikeComponents (스플라인 기어류의 폐쇄단조 해석)

  • Lee, Seung-Dong;Kim, Won-Il;Kim, Yohng-Jo
    • Journal of the Korean Society of Industry Convergence
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    • v.2 no.2
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    • pp.187-194
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    • 1999
  • Closed-die forging of spline was analysed using the upper bound elemental technique, Two different forging methods, denoted here as side extrusion-forging and upset forging, were proposed, The kinematically admissible velocity fields for each of the forging methods, which could express trapezoidal, rectangular and serration tooth forms, were presented. Upper bounds to forging loads and deformed configurations were predicted using the velocity fields. Theoretical results were compared with experimental ones. Experiments with lead were carried out at room temperature where grease was used as a lubricant. The present investigation revealed that analytical forging loads were reduced by using the side extrusion-forging but the upset forging could improve configuration of the final forged splines.

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